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Research Article | Open Access

Microstructure and corrosion resistance of ultrasonic micro-arc oxidation biocoatings on magnesium alloy

Lijie QUa,bMuqin LIa,b,*( )Miao LIUcErlin ZHANGbChen MAb
State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, China
Department of Stomatology, Jiamusi University, Jiamusi 154007, China
Department of Materials Science and Engineering, Jiamusi University, Jiamusi 154007, China
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Abstract

The ultrasonic micro-arc oxidation (UMAO) was used to fabricate ceramic coatings on magnesium alloy. UMAO coatings were produced at 60 W input ultrasonic. The effects of the ultrasound on the microstructure, phase composition, elemental distribution and corrosion resistance of the coatings were extensively investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy-dispersive X-ray spectrometry (EDX) and electrochemical workstation. The results showed that ultrasound improved the homogeneous distribution of micro-porous structure. The coatings were mainly composed of MgO ceramic and small amount of calcium and phosphorus with porous structure. The Ca/P ratio of the coatings increased when 60 W ultrasonic was used. The corrosion potential in simulated body fluid (SBF) changed from -1.583 V of bare magnesium alloy to -0.353 V of magnesium alloy coated under 60 W ultrasonic. The corrosion resistance of UMAO coatings was better than that of MAO coatings.

References

[1]
Witte F. The history of biodegradable magnesium implants: A review. Acta Biomater 2010, 6: 1680-1692.
[2]
Hermawan H, Dubé D, Mantovani D. Developments in metallic biodegradable stents. Acta Biomater 2010, 6: 1693-1697.
[3]
Alvarez-Lopez M, Pereda MD, del Valle JA, et al. Corrosion behaviour of AZ31 magnesium alloy with different grain sizes in simulated biological fluids. Acta Biomater 2010, 6: 1763-1771.
[4]
Li JN, Cao P, Zhang XN, et al. In vitro degradation and cell attachment of a PLGA coated biodegradable Mg–6Zn based alloy. J Mater Sci 2010, 45: 6038-6045.
[5]
Mandelli A, Bestetti M, Da Forno A, et al. A composite coating for corrosion protection of AM60B magnesium alloy. Surf Coat Technol 2011, 205: 4459-4465.
[6]
Chen H, Lv GH, Zhang GL, et al. Corrosion performance of plasma electrolytic oxidized AZ31 magnesium alloy in silicate solutions with different additives. Surf Coat Technol 2010, 205: S32-S35.
[7]
Cai J, Cao F, Chang L, et al. The preparation and corrosion behaviors of MAO coating on AZ91D with rare earth conversion precursor film. Appl Surf Sci 2011, 257: 3804-3811.
[8]
Yang Y, Wu H. Effects of current frequency on the microstructure and wear resistance of ceramic coatings embedded with SiC nano-particles produced by micro-arc oxidation on AZ91D magnesium alloy. J Mater Sci Technol 2010, 26: 865-871.
[9]
Guo HF, An MZ. Growth of ceramic coatings on AZ91D magnesium alloys by micro-arc oxidation in aluminate–fluoride solutions and evaluation of corrosion resistance. Appl Surf Sci 2005, 246: 229-238.
[10]
Gu XN, Li N, Zhou WR, et al. Corrosion resistance and surface biocompatibility of a microarc oxidation coating on a Mg–Ca alloy. Acta Biomater 2011, 7: 1880-1889.
[11]
Liang J, Hu L, Hao J. Characterization of microarc oxidation coatings formed on AM60B magnesium alloy in silicate and phosphate electrolytes. Appl Surf Sci 2007, 253: 4490-4496.
[12]
Shi L, Xu Y, Li K, et al. Effect of additives on structure and corrosion resistance of ceramic coatings on Mg–Li alloy by micro-arc oxidation. Curr Appl Phys 2010, 10: 719-723.
[13]
Lin P, Zhou H, Li W, et al. Interactive effect of cerium and aluminum on the ignition point and the oxidation resistance of magnesium alloy. Corros Sci 2008, 50: 2669-2675.
[14]
Liang J, Guo B, Tian J, et al. Effects of NaAlO2 on structure and corrosion resistance of microarc oxidation coatings formed on AM60B magnesium alloy in phosphate–KOH electrolyte. Surf Coat Technol 2005, 199: 121-126.
[15]
Chen J, Zeng R, Huang W, et al. Characterization and wear resistance of micro-arc oxidation coating on magnesium alloy AZ91 in simulated body fluids. Trans Nonferrous Met Soc China 2008, 18: s361-s364.
[16]
Zhong L, Cao F. Shi Y, et al. Preparation and corrosion resistance of cerium-based chemical conversion coating on AZ91 magnesium alloy. Acta Metall Sin 2008, 44: 979-985 (in Chinese).
[17]
Wu CS, Zhang Z, Cao FH, et al. Study on the anodizing of AZ31 magnesium alloys in alkaline borate solutions. Appl Surf Sci 2007, 253: 3893-3898.
[18]
Chang L, Cao F, Cai J, et al. Formation and transformation of Mg(OH)2 in anodic coating using FTIR mapping. Electrochem Commun 2009, 11: 2245-2248.
[19]
Khaselev O, Yahalom J. The anodic behavior of binary Mg–Al alloys in KOH–aluminate solutions. Corros Sci 1998, 40: 1149-1160.
[20]
Srinivasan PB, Liang J, Blawert C. Characterization of calcium containing plasma electrolytic oxidation coatings on AM50 magnesium alloy. Appl Surf Sci 2010, 256: 4017-4022.
[21]
Xu L, Pan F, Yu G, et al. In vitro and in vivo evaluation of the surface bioactivity of a calcium phosphate coated magnesium alloy. Biomaterials 2009, 30: 1512-1523.
[22]
Liu GY, Hu J, Ding ZK, et al. Bioactive calcium phosphate coating formed on micro-arc oxidized magnesium by chemical deposition. Appl Surf Sci 2011, 257: 2051-2057.
[23]
Yang S, Qi M, Chen Y, et al. MAO–DCPD composite coating on Mg alloy for degradable implant applications. Mater Lett 2011, 65: 2201-2204.
[24]
Zhang Y, Lin SY, Fang Y. New developments in sonochemistry—Preparation of nanomaterials by ultrasound. Physics 2002, 31: 80-83 (in Chinese).
[25]
Mo RY, Lin SY, Wang CH. Methods of study on sound cavitation. Appl Acoust 2009, 28: 389-400 (in Chinese).
[26]
Cravotto G, Tagliapietra S, Robaldo B, et al. Chemical modification of chitosan under high-intensity ultrasound. Ultrason Sonochem 2005, 12: 95-98.
[27]
Aurousseau M, Pham NT, Ozil P. Effects of ultrasound on the electrochemical cementation of cadmium by zinc powder. Ultrason Sonochem 2004, 11: 23-26.
[28]
Morison SR. Wu HH, translator. Electrochemistry of Semiconductor and Metal Oxide Film. Beijing: Science Press, 1988: 95-96 (in Chinese).
[29]
Wu HH. Electrochemistry. Beijing: Chemical Industry Press, 2004: 218 (in Chinese).
[30]
Pandey AK, Kalsi PC, Iyer RH. Effects of high intensity ultrasound in chemical etching of particleyer tracks in solid state nuclear track detectors. Nucl Instrum Meth B 1998, 134: 393-399.
[31]
Wang XM, Zhu LQ, Liu HC, et al. Influence of surface pretreatment on the anodizing film of Mg alloy and the mechanism of the ultrasound during the pretreatment. Surf Coat Technol 2008, 202: 4210-4217.
[32]
Abbasi S, Bayati MR, Golestani-Fard F, et al. Micro arc oxidized HAp–TiO2 nanostructured hybrid layers-part I: Effect of voltage and growth time. Appl Surf Sci 2011, 257: 5944-5949.
Journal of Advanced Ceramics
Pages 227-234
Cite this article:
QU L, LI M, LIU M, et al. Microstructure and corrosion resistance of ultrasonic micro-arc oxidation biocoatings on magnesium alloy. Journal of Advanced Ceramics, 2013, 2(3): 227-234. https://doi.org/10.1007/s40145-013-0064-y

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Received: 01 February 2013
Revised: 12 April 2013
Accepted: 15 April 2013
Published: 07 September 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.

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