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Research Article | Open Access

Substitution of a fraction of zircon by cristobalite in nano hematite encapsulated pigment and examination of glaze application

Department of Inorganic Pigments and Glazes, Institute for Color Science and Technology (ICST), P.O. Box 1668814811, Tehran, Iran
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Abstract

Hematite pigment has a long history, but it cannot be used for ceramic application, because it must be thermally and chemically stable at high firing temperature when using a pigment in a glaze or ceramic body. Recently, through encapsulated systems, a new pigment with suitable thermal and chemical stability can be obtained by encapsulating hematite crystals into selected silica or zircon matrices. It means that nano-sized red hematite has been encapsulated into the protected phases. Transmission electron micrographs of hematite encapsulated into silica and zircon matrices by sol–gel method show spherical single crystals with diameter of about 5–10 nm. In order to optimize ceramic glaze formulations for application of the synthesized red inorganic nanocomposite inclusion pigment by sol–gel method, four different types of glazes (i.e., alkalis, borate, earth alkalis, and leaded glazes) have been tested. The results show that the substitution of a fraction of zircon by cristobalite in hematite-zircon pigment produces acceptable stability with red hue.

Keywords

nano hematiteinclusion pigmentzirconsilicaceramic glaze

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Journal of Advanced Ceramics
Volume 2 Issue 2,
June 2013
Pages 149-156
DOI: 10.1007/s40145-013-0054-0
Cite this article:
HOSSEINI-ZORI M. Substitution of a fraction of zircon by cristobalite in nano hematite encapsulated pigment and examination of glaze application. Journal of Advanced Ceramics, 2013, 2(2): 149-156. https://doi.org/10.1007/s40145-013-0054-0

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Received: 14 January 2013
Revised: 24 February 2013
Accepted: 14 March 2013
Published: 04 June 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
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