AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
PDF (1.4 MB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Structural, magnetic and dielectric properties of nano-crystallineNi-doped BiFeO3 ceramics formulated by self-propagating high-temperature synthesis

Yogesh A. CHAUDHARIa,bChandrashekhar M. MAHAJANcPrashant P. JAGTAPaSubhash T. BENDREa,*( )
Department of Physics, School of Physical Sciences, North Maharashtra University, Jalgaon 425001, India
Department of Engineering Sciences and Humanities (DESH), SRTTC-FOE, Kamshet, Pune 410405, India
Department of Engineering Sciences and Humanities (DESH), Vishwakarma Institute of Technology (VIT), Pune 411037, India
Show Author Information

Abstract

Ni-doped BiFeO3 powders with the composition BiFe1-xNixO3 (x = 0.05, 0.1 and 0.15) were prepared by a self-propagating high-temperature synthesis (SHS), using metal nitrates as oxidizers and glycine as fuel. The X-ray diffraction (XRD) patterns depict that Ni-doped BiFeO3 ceramics crystallize in a rhombhohedral phase. The scanning electron micrographs of Ni-doped BiFeO3 ceramics show a dense morphology with interconnected structure. It is found that, the room-temperature magnetization measurements in Ni-incorporated BiFeO3 ceramics give rise to nonzero magnetization. The magnetization of Ni-doped BiFeO3 ceramics is significantly enhanced when Ni doping concentration reaches to x = 0.1 at 5 K. The variations of dielectric constant with temperature in BiFe0.95Ni0.05O3, BiFe0.9Ni0.1O3 and BiFe0.85Ni0.15O3 samples exhibit clear dielectric anomalies approximately around 450 ℃, 425 ℃ and 410 ℃ respectively, which correspond to antiferromagnetic to paramagnetic phase transition of the parent compound BiFeO3.

References

[1]
Cheong SW, Mostovoy M. Multiferroics: A magnetic twist for ferroelectricity. Nat Mater 2007, 6: 1320.
[2]
Kumar N, Panwar N, Gahtori B, et al. Structural, dielectric and magnetic properties of Pr substituted Bi1-xPrxFeO3 (0≤ x ≤0.15) multiferroic compounds. J Alloys Compd 2010, 501: L29L32.
[3]
Chaudhari YA, Singh A, Abuassaj EM, et al. Multiferroic properties in BiFe1-xZnxO3 (= 0.1–0.2) ceramics by solution combustion method (SCM). J Alloys Compd 2012, 518: 5157.10.1016/j.jallcom.2011.12.122
[4]
Qin W, Guo YP, Guo B, et al. Dielectric and optical properties of BiFeO3–(Na0.5Bi0.5)TiO3 thin films deposited on Si substrate using LaNiO3 as buffer layer for photovoltaic devices. J Alloys Compd 2012, 513: 154158.
[5]
Farhadi S, Rashidi N. Microwave-induced solid-state decomposition of the Bi[Fe(CN)6]·5H2O precursor: A novel route for the rapid and facile synthesis of pure and single-phase BiFeO3 nanopowder. J Alloys Compd 2010, 503: 439444.
[6]
Shami MY, Awan MS, Anis-ur-Rehman M. Phase pure synthesis of BiFeO3 nanopowders using diverse precursor via co-precipitation method. J Alloys Compd 2011, 509: 1013910144.
[7]
Garcia FG, Riccardi CS, Simões AZ. Lanthanum doped BiFeO3 powders: Syntheses and characterization. J Alloys Compd 2010, 501: 2529.
[8]
Wang YY. A giant polarization value in bismuth ferrite thin films. J Alloys Compd 2011, 509: L362L364.
[9]
Azam A, Jawad A, Ahmed AS, et al. Structural, optical and transport properties of Al3+ doped BiFeO3 nanopowder synthesized by solution combustion method. J Alloys Compd 2011, 509: 29092913.
[10]
Minh NV, Quan NG. Structural, optical and electromagnetic properties of Bi1-xHoxFeO3 multiferroic materials. J Alloys Compd 2011, 509: 26632666.
[11]
Kothari D, Reddy VR, Gupta A, et al. Eu doping in multiferroic BiFeO3 ceramics studied by Mossbauer and EXAFS spectroscopy. J Phys: Condens Mat 2010, 22: 356001.
[12]
Dho J, Qi X, Kim H, et al. Large electric polarization and exchange bias in multiferroic BiFeO3. Adv Mater 2006, 18: 14451448.
[13]
Qi XD, Dho J, Tomov R, et al. Greatly reduced leakage current and conduction mechanism in aliovalent-ion-doped BiFeO3. Appl Phys Lett 2005, 86: 062903.
[14]
Wang C, Takahashi M, Fujino H, et al. Leakage current of multiferroic (Bi0.6Tb0.3La0.1)FeO3 thin films grown at various oxygen pressures by pulsed laser deposition and annealing effect. J Appl Phys 2006, 99: 054104.
[15]
Xiao XH, Zhu J, Li YR, et al. Greatly reduced leakage current in BiFeO3 thin film by oxygen ion implantation. J Phys D: Appl Phys 2007, 40: 57755778.
[16]
Pabst GW, Martin LW, Chu YH, et al. Leakage mechanisms in BiFeO3 thin films. Appl Phys Lett 2007, 90: 072902.
[17]
Jiang QH, Nan CW, Shen ZJ. Synthesis and properties of multiferroic La-modified BiFeO3 ceramics. J Am Ceram Soc 2006, 89: 21232127.
[18]
Kumar M, Yadav KL. Rapid liquid phase sintered Mn doped BiFeO3 ceramics with enhanced polarization and weak magnetization. Appl Phys Lett 2007, 91: 242901.
[19]
Nalwa KS, Garg A, Upadhyaya A. Effect of samarium doping on the properties of solid-state synthesized multiferroic bismuth ferrite. Mater Lett 2008, 62: 878881.
[20]
Kumar M, Yadav KL. Study of room temperature magnetoelectric coupling in Ti substituted bismuth ferrite system. J Appl Phys 2006, 100: 074111.
[21]
Xu QY, Zai HF, Wu D, et al. The magnetic properties of BiFeO3 and Bi(Fe0.95Zn0.05)O3. J Alloys Compd 2009, 485: 1316.
[22]
Chen SY, Wang LY, Xuan HC, et al. Multiferroic properties and converse magnetoelectric effect in Bi1-xCaxFeO3 ceramics. J Alloys Compd 2010, 506: 537540.
[23]
Wang Y, Xu G, Yang L, et al. Enhancement of ferromagnetic properties in Ni-doped BiFeO3. Mater Sci-Poland 2009, 27: 219224.
[24]
Saha S, Ghanawat SJ, Purohit RD. Solution combustion synthesis of nano particle La0.9Sr0.1MnO3 powder by a unique oxidant–fuel combination and its characterization. J Mater Sci 2006, 41: 19391943.
[25]
Dutta DP, Jayakumar OD, Tyagi AK, et al. Effect of doping on the morphology and multiferroic properties of BiFeO3 nanorods. Nanoscale 2010, 2: 11491154.
[26]
Jia DC, Xu JH, Ke H, et al. Structure and multiferroic properties of BiFeO3 powders. J Eur Ceram Soc 2009, 29: 30993103.
Journal of Advanced Ceramics
Pages 135-140
Cite this article:
CHAUDHARI YA, MAHAJAN CM, JAGTAP PP, et al. Structural, magnetic and dielectric properties of nano-crystallineNi-doped BiFeO3 ceramics formulated by self-propagating high-temperature synthesis. Journal of Advanced Ceramics, 2013, 2(2): 135-140. https://doi.org/10.1007/s40145-013-0051-3

1022

Views

35

Downloads

20

Crossref

N/A

Web of Science

22

Scopus

0

CSCD

Altmetrics

Received: 18 August 2012
Revised: 02 March 2013
Accepted: 02 March 2013
Published: 04 June 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.

Return