AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
PDF (8.1 MB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Preparation of SiC powders by carbothermal reduction with bamboo charcoal as renewable carbon source

Xingzhong GUOLin ZHUWenyan LIHui YANG*( )
Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Show Author Information

Abstract

Bamboo charcoal was expected to be a renewable carbon source for carbide materials in carbothermal reduction because of its superior characteristics. SiC powders with characteristic shapes were fabricated by carbothermal reduction with industrial silica sol and bamboo charcoal particles as silicon and carbon sources respectively, and the effects of reacting temperature and time on shape evolutions and properties of the as-prepared SiC powders were investigated. The silica sol/bamboo charcoal system was firstly transformed into SiO2/C system by the transition of silica sol and graphitization of bamboo charcoal, and the carbothermal reduction between SiO2 and C occurred at/above 1600 ℃. The characteristic shapes of SiC particles were transformed from string-beads-like to dumbbell-like and rod-like with the increase of reacting temperature. The prepared SiC powders are expected to become new raw material for silicon carbide ceramic composites.

References

[1]
Riley FL. Structural Ceramics: Fundamentals and Case Studies. Cambridge University Press, 2009.
[2]
Basu B, Balani K. Advanced Structural Ceramics. John Wiley & Sons, 2011.
[3]
Singh D, Zhu DM, Zhou YC, et al. Eds. Design, Development, and Applications of Engineering Ceramics and Composites: Ceramic Transactions. John Wiley & Sons, 2010.
[4]
Narisawa M, Yasuda H, Mori R, et al. Silicon carbide particle formation from carbon black—Polymethylsilsesquioxane mixtures with melt pressing. J Ceram Soc Jpn 2008, 116: 121–125.
[5]
Cui XL, Wang YH, Wang L, et al. Synthesis of nanometer-sized TiC and SiC from petroleum coke by reactive milling. Pet Sci Technol 2011, 19: 971–978.
[6]
Sulardjaka , Jamasri , Wildan MW, et al. Method for increasing β-SiC yield on solid state reaction of coal fly ash and activated carbon powder. Bull Mater Sci 2011, 34: 1013–1016.
[7]
Wang L, Hu XB, Xu XG, et al. Synthesis of high purity SiC powder for high-resistivity SiC single crystals growth. J Mater Sci Technol 2007, 23: 118–122.
[8]
Asada T, Ishihara S, Yamane T, et al. Science of bamboo charcoal: Study on carbonizing temperature of bamboo charcoal and removal capability of harmful gases. J Health Sci 2002, 48: 473–479.
[9]
Dai JL, Guo XZ, Yang H, et al. Study on the microstructure of bamboo charcoal. J Mater Sci Eng 2007, 25: 743–745 (in Chinese).
[10]
Guo XZ, Zhu L, Yang H, et al. Effects of additives on the microstructure of synthesized SiC particles by using silica sol/bamboo charcoal system. Mater Lett 2012, 73: 133–135.
[11]
Guo XZ, Zhang LJ, Yan LQ, et al. Preparation of silicon carbide using bamboo charcoal as carbon source. Mater Lett 2010, 64: 331–333.
[12]
Burda C, Chen XB, Narayanan R, et al. Chemistry and properties of nanocrystals of different shapes. Chem Rev 2005, 105: 1025–1102.
[13]
Yang GY, Wu RB, Pan Y, et al. Direct observation of the growth process of silicon carbide nanowhiskers by vapor–solid process. Physica E 2007, 39: 171–174.
[14]
Wu RB, Yang GY, Pan Y, et al. Prism-shaped SiC nanowhiskers. J Alloys Compd 2008, 453: 241–246.
[15]
Dhage S, Lee HC, Hassan MS, et al. Formation of SiC nanowhiskers by carbothermic reduction of silica with activated carbon. Mater Lett 2009, 63: 174–176.
[16]
Dhiman R, Johnson E, Morgen P. Growth of SiC nanowhiskers from wooden precursors, separation, and characterization. Ceram Int 2011, 37: 3759–3764.
[17]
Sōmiya S, Inomata Y, Eds. Silicon Carbide Ceramics: Fundamental and Solid Reaction. London: Elsevier Applied Science, 1991.
Journal of Advanced Ceramics
Pages 128-134
Cite this article:
GUO X, ZHU L, LI W, et al. Preparation of SiC powders by carbothermal reduction with bamboo charcoal as renewable carbon source. Journal of Advanced Ceramics, 2013, 2(2): 128-134. https://doi.org/10.1007/s40145-013-0050-4

833

Views

29

Downloads

29

Crossref

N/A

Web of Science

32

Scopus

0

CSCD

Altmetrics

Received: 23 January 2013
Revised: 24 February 2013
Accepted: 27 February 2013
Published: 04 June 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.

Return