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Nano Research 2024, 17(6): 5261-5269 https://doi.org/10.1007/s12274-024-6507-7
Research Article | Issue | Published: 22 February 2024

Anchoring Ru clusters to highly defective N-doped carbon nanotubes via a thermal-shock strategy for stable industrial hydrogen evolution

Show Author's Information Zhiming Li1,2,§,  Xinyu Li2,§,  Haiqing Ma1,  Chenliang Ye3,  Hongan Yu1,  Long Nie1,  Meng Zheng1,  Jin Wang1,2( )
College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China
School of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, China
Department of Power Engineering, North China Electric Power University, Baoding 071003, China

§ Zhiming Li and Xinyu Li contributed equally to this work.

Keywords:
hydrogen evolution reaction, thermal-shock method, large-current-density, Ru cluster
Topics:
Hydrogen fuels
Cite this article:
Li Z, Li X, Ma H, et al. Anchoring Ru clusters to highly defective N-doped carbon nanotubes via a thermal-shock strategy for stable industrial hydrogen evolution. Nano Research, 2024, 17(6): 5261-5269. https://doi.org/10.1007/s12274-024-6507-7
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Abstract Full text Electronic supplementary material About this article

Non-Pt or low-Pt catalysts capable for stable generation of hydrogen via water electrolysis at an industrial level of current density are highly demanded. Construction of strong metal–support connection is beneficial to improve the performance stability of electrocatalysts. Here we employed highly defective N-doped carbon nanotubes (d-N-CNT) as the support to achieve uniform and firm anchoring of Ru clusters (~ 1.9 nm) via a thermal-shock strategy. The as-prepared Ru/d-N-CNT catalyst shows excellent catalytic activity for hydrogen evolution reaction (HER) in alkaline media and requires an overpotential (ƞ) of 12 mV at 10 mA·cm−2 and 116 mV at 200 mA·cm−2 with a Ru loading of 0.025 mg·cm−2. Impressively, Ru/d-N-CNT presents robust stability for HER at both low current density (stable for at least 1000 h at 10 mA·cm−2) and the industrial level of current density (stable for at least 100 h at 1000 mA·cm−2), remarkably outperforming commercial Pt/C and Ru/C. The highly defective nature of the N-CNT support endowed the as-prepared Ru/d-N-CNT catalyst with strong metal–support adhesion that efficiently suppressed agglomeration as well as obscission of Ru clusters. Meanwhile, the rich defects increased the surface energy of the N-CNT support and resulted in improved hydrophilicity as evidenced by the liquid contact angle measurement and the bubble evolution process, which also played an important role in stabilizing the HER performance especially at large current density.


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About this article

Anchoring Ru clusters to highly defective N-doped carbon nanotubes via a thermal-shock strategy for stable industrial hydrogen evolution

Show Author's information Zhiming Li1,2,§, Xinyu Li2,§, Haiqing Ma1, Chenliang Ye3, Hongan Yu1, Long Nie1, Meng Zheng1, Jin Wang1,2( )
College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China
School of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, China
Department of Power Engineering, North China Electric Power University, Baoding 071003, China

§ Zhiming Li and Xinyu Li contributed equally to this work.

Abstract

Non-Pt or low-Pt catalysts capable for stable generation of hydrogen via water electrolysis at an industrial level of current density are highly demanded. Construction of strong metal–support connection is beneficial to improve the performance stability of electrocatalysts. Here we employed highly defective N-doped carbon nanotubes (d-N-CNT) as the support to achieve uniform and firm anchoring of Ru clusters (~ 1.9 nm) via a thermal-shock strategy. The as-prepared Ru/d-N-CNT catalyst shows excellent catalytic activity for hydrogen evolution reaction (HER) in alkaline media and requires an overpotential (ƞ) of 12 mV at 10 mA·cm−2 and 116 mV at 200 mA·cm−2 with a Ru loading of 0.025 mg·cm−2. Impressively, Ru/d-N-CNT presents robust stability for HER at both low current density (stable for at least 1000 h at 10 mA·cm−2) and the industrial level of current density (stable for at least 100 h at 1000 mA·cm−2), remarkably outperforming commercial Pt/C and Ru/C. The highly defective nature of the N-CNT support endowed the as-prepared Ru/d-N-CNT catalyst with strong metal–support adhesion that efficiently suppressed agglomeration as well as obscission of Ru clusters. Meanwhile, the rich defects increased the surface energy of the N-CNT support and resulted in improved hydrophilicity as evidenced by the liquid contact angle measurement and the bubble evolution process, which also played an important role in stabilizing the HER performance especially at large current density.

Keywords: hydrogen evolution reaction, thermal-shock method, large-current-density, Ru cluster

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Acknowledgements

Publication history

Received: 25 December 2023
Revised: 17 January 2024
Accepted: 18 January 2024
Published: 22 February 2024
Issue date: June 2024

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© Tsinghua University Press 2024

Acknowledgements

Acknowledgements

This work was financially supported by the National Key Research and Development Program of China (No. 2021YFA1600800) and the National Natural Science Foundation of China (No. 22022508).

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