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The development and synthesis of cathode electrocatalysts with high activity and durable stability for metal-air batteries is an important challenge in the area of electrocatalysis. Herein, we introduce a novel in-situ nitriding and phosphating strategy for producing W3N4 and WP from phosphotungstic acid (HPW)-polyaniline-phytic acid-Fe3+ organic–inorganic hybrid material. The final material has a three-dimensional porous framework with W3N4-WP heterostructures embedded in the carbon matrix (W3N4-WP@NPC). As-made materials exhibit exceptional electrocatalytic performance for the oxygen reduction reaction (ORR), with a diffusion-limiting current density of 6.9 mA·cm−2 and a half-wave potential of 0.82 V. As a Zn-air primary cathode, the W3N4-WP@NPC assembled battery can provide a relatively high peak power density (194.2 mW·cm−2). As a Zn-air secondary air-cathode, it has great cycling stability over 500 h. This work provides a simple and efficient method for rationally designing high-performance air cathodes from copolymer-anchored polyoxometalates.
This work was supported by the Hubei Provincial Natural Science Foundation and Huangshi of China (No. 2022CFD039), the National Natural Science Foundation of China (No. 22008058), the Natural Science Foundation of Jiangsu Province (No. BK20220912), and the China Postdoctoral Science Foundation (No. 2022M711607).