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Nano Research 2024, 17(6): 5179-5187 https://doi.org/10.1007/s12274-024-6442-7
Research Article | Issue | Published: 25 January 2024

Manipulating fast Li2S redox via carbon confinement and oxygen defect engineering of In2O3 for lithium–sulfur batteries

Show Author's Information Jinlei Qin,  Rui Wang,  Zilong Yuan,  Pei Xiao,  Deli Wang( )
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Keywords:
oxygen vacancies, Li–S batteries, nitrogen-doped carbon confinement, bidirectional Li2S redox
Topics:
Lithium sulfur batteries
Cite this article:
Qin J, Wang R, Yuan Z, et al. Manipulating fast Li2S redox via carbon confinement and oxygen defect engineering of In2O3 for lithium–sulfur batteries. Nano Research, 2024, 17(6): 5179-5187. https://doi.org/10.1007/s12274-024-6442-7
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Abstract Full text Electronic supplementary material About this article

Lithium–sulfur (Li–S) batteries have been considered as promising energy storage systems due to the merits of high energy density and low cost. However, the lithium polysulfides (LiPSs) diffusion and sluggish redox kinetics hamper the battery performance. In this work, low-bandgap indium oxide (In2O3) with dense oxygen vacancies (In2O3−x, 0 < x < 3) confined in nitrogen-doped carbon column (NC) is developed as a desirable LiPSs immobilizer and promoter to address these intractable problems. The NC confined In2O3−x with rich O vacancies (In2O3−x@NC) lowers the bandgap of 1.78 eV, strengthens the chemical adsorbability to LiPSs, and catalyzes the bidirectional Li2S redox. Attributed to the structural and chemical cooperativities, the obtained sulfur electrodes exhibit a stable cycling over 550 cycles at 1.0 C and splendid rate capability up to 4.0 C. More significantly, when the sulfur-loading reaches as high as 5.5 mg·cm−2, the cathodes achieve an areal capacity of 5.12 mAh·cm−2 at 0.1 C. The strategy of NC confined catalyst with rich defects engineering demonstrates great promise in the development of practical Li–S batteries.


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Electronic supplementary material
About this article

Manipulating fast Li2S redox via carbon confinement and oxygen defect engineering of In2O3 for lithium–sulfur batteries

Show Author's information Jinlei Qin, Rui Wang, Zilong Yuan, Pei Xiao, Deli Wang( )
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Abstract

Lithium–sulfur (Li–S) batteries have been considered as promising energy storage systems due to the merits of high energy density and low cost. However, the lithium polysulfides (LiPSs) diffusion and sluggish redox kinetics hamper the battery performance. In this work, low-bandgap indium oxide (In2O3) with dense oxygen vacancies (In2O3−x, 0 < x < 3) confined in nitrogen-doped carbon column (NC) is developed as a desirable LiPSs immobilizer and promoter to address these intractable problems. The NC confined In2O3−x with rich O vacancies (In2O3−x@NC) lowers the bandgap of 1.78 eV, strengthens the chemical adsorbability to LiPSs, and catalyzes the bidirectional Li2S redox. Attributed to the structural and chemical cooperativities, the obtained sulfur electrodes exhibit a stable cycling over 550 cycles at 1.0 C and splendid rate capability up to 4.0 C. More significantly, when the sulfur-loading reaches as high as 5.5 mg·cm−2, the cathodes achieve an areal capacity of 5.12 mAh·cm−2 at 0.1 C. The strategy of NC confined catalyst with rich defects engineering demonstrates great promise in the development of practical Li–S batteries.

Keywords: oxygen vacancies, Li–S batteries, nitrogen-doped carbon confinement, bidirectional Li2S redox

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Publication history
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Acknowledgements

Publication history

Received: 24 September 2023
Revised: 15 December 2023
Accepted: 22 December 2023
Published: 25 January 2024
Issue date: June 2024

Copyright

© Tsinghua University Press 2024

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 22279036) and the Innovation and Talent Recruitment Base of New Energy Chemistry and Device (No. B21003). The authors thank the Analytical and Testing Center of Huazhong University of Science and Technology (HUST) for allowing use of its facilities.

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