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Nano Research 2024, 17(5): 3872-3878 https://doi.org/10.1007/s12274-023-6371-x
Research Article | Issue | Published: 28 December 2023

Direct synthesis of a disinfectant with fresh scent of green plants by semi-hydrogenation of alkynol on Pd single-atom catalysts

Show Author's Information Yan Jiang1,§,  Xuetong Yu1,§,  Yuxia Ji1,  Xunzhu Jiang3,  Yalin Guo3,  Tianbo Li5,  Liang Gao1,2,  Rui Lang1,2,4( ),  Yanxiong Fang1,2,4,  Botao Qiao3( ),  Jinxiang Dong1( )
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang 515200, China
CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116024, China
Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangzhou 510006, China
School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, China

§ Yan Jiang and Xuetong Yu contributed equally to this work.

Keywords:
coronavirus disease 2019 (COVID-19), hydrogenation, single-atom catalysis, fragrance, household product
Topics:
Catalysis Selective catalytic reduction
Cite this article:
Jiang Y, Yu X, Ji Y, et al. Direct synthesis of a disinfectant with fresh scent of green plants by semi-hydrogenation of alkynol on Pd single-atom catalysts. Nano Research, 2024, 17(5): 3872-3878. https://doi.org/10.1007/s12274-023-6371-x
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Abstract Full text Electronic supplementary material About this article

Alcohol-based disinfectants have protected people in the coronavirus disease 2019 (COVID-19) pandemic, but olfactory stimuli of ethanol may evoke unpleasant memories associated with stressful situations in the devastating infectious disease. The smell of ethanol in household cleaning and disinfectant products can be covered up by the fragrance additives, and 3-hexenol is especially appreciated for the characteristic, strong odor of green plants. Industrial production of 3-hexenol relies on the selective hydrogenation of 3-hexyn-1-ol, where Lindlar catalyst is normally used for the superior selectivity. Although achieving such catalytic transformation in ethanol solution seems as a direct way to produce a disinfectant with green aroma, a popular consumer product in the post-COVID era, severe leaching of toxic Pb hinders Lindlar catalyst as a promising candidate. We find that the Fe2O3 supported Pd single-atom catalyst is highly selective to fulfill semi-hydrogenation of 3-hexyn-1-ol in 75% ethanol, and the aforementioned household product is readily generated after filtrating the stable, solid catalyst out of reaction solution. Single-atom catalysts have been frequently utilized for fine-chemical synthesis, while in this work they make stunning debut in practical manufacture of daily used products.


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About this article

Direct synthesis of a disinfectant with fresh scent of green plants by semi-hydrogenation of alkynol on Pd single-atom catalysts

Show Author's information Yan Jiang1,§, Xuetong Yu1,§, Yuxia Ji1, Xunzhu Jiang3, Yalin Guo3, Tianbo Li5, Liang Gao1,2, Rui Lang1,2,4( ), Yanxiong Fang1,2,4, Botao Qiao3( ), Jinxiang Dong1( )
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang 515200, China
CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116024, China
Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangzhou 510006, China
School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, China

§ Yan Jiang and Xuetong Yu contributed equally to this work.

Abstract

Alcohol-based disinfectants have protected people in the coronavirus disease 2019 (COVID-19) pandemic, but olfactory stimuli of ethanol may evoke unpleasant memories associated with stressful situations in the devastating infectious disease. The smell of ethanol in household cleaning and disinfectant products can be covered up by the fragrance additives, and 3-hexenol is especially appreciated for the characteristic, strong odor of green plants. Industrial production of 3-hexenol relies on the selective hydrogenation of 3-hexyn-1-ol, where Lindlar catalyst is normally used for the superior selectivity. Although achieving such catalytic transformation in ethanol solution seems as a direct way to produce a disinfectant with green aroma, a popular consumer product in the post-COVID era, severe leaching of toxic Pb hinders Lindlar catalyst as a promising candidate. We find that the Fe2O3 supported Pd single-atom catalyst is highly selective to fulfill semi-hydrogenation of 3-hexyn-1-ol in 75% ethanol, and the aforementioned household product is readily generated after filtrating the stable, solid catalyst out of reaction solution. Single-atom catalysts have been frequently utilized for fine-chemical synthesis, while in this work they make stunning debut in practical manufacture of daily used products.

Keywords: coronavirus disease 2019 (COVID-19), hydrogenation, single-atom catalysis, fragrance, household product

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Publication history
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Acknowledgements

Publication history

Received: 27 September 2023
Revised: 12 November 2023
Accepted: 27 November 2023
Published: 28 December 2023
Issue date: May 2024

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (Nos. 22378079 and 22102210), Guangzhou Projects for Fundamental Research (No. 202102020202), the Guangdong Provincial Key Laboratory of Plant Resources Biorefinery (No. 2021GDKLPRB10) and the start-up funding of Guangdong University of Technology.

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