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Research Article

High-precision nondestructive evaluation of a thermal barrier coating based on perovskite quantum dot anion exchange

Tao Han1( )Shufang Ding1Zifan Wang2Sirong Jiang1Pengjiang Jing1Tianshang Yi1Yaqi Chen1Chunzhi Jiang1Xiaofeng Zhang2( )
Microelectronics and Optoelectronics Technology Key Laboratory of Hunan Higher Education, School of Physics and Electronic Electrical Engineering, Xiangnan University, Chenzhou 423000, China
National Engineering Laboratory for Modern Materials Surface Engineering Technology & The Key Lab of Guangdong for Modern Surface Engineering Technology, Guangdong Institute of New Materials, Guangdong Academy of Sciences, Guangzhou 510650, China
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Graphical Abstract

We have reported a new nondestructive evaluation (NDE) technique of thermal barrier coatings based on quantum dot (QD) anion exchange. The resultant NDE technique shows that the colour of the thermal barrier coatings (TBCs) obviously changes from green to blue, accompanied by a large photoluminescence (PL) blueshift (~ 100 nm).

Abstract

Thermal barrier coatings (TBCs) in gas turbine engines are used in expressly harsh environments; thus, assessing TBC integrity status is critical for safety and reliability. However, traditional periodic maintenance involves visual inspections of the TBCs, requiring the gas turbine to be decommissioned and partially dismantled. Most importantly, tiny defects or internal damages that easily cause coating failure cannot be identified. In this work, a new nondestructive evaluation (NDE) technique of TBCs based on quantum dot (QD) anion exchange is first explored internationally. By exchanging anions between the Cl ions and the CsPbBr3 QDs, the degrees of salt corrosion of the TBCs are evaluated. The resultant NDE technique shows that the colour of the TBCs obviously changes from green to blue, accompanied by a large blueshift (~ 100 nm) of the photoluminescence (PL) peak position. In addition, the relationship between the PL peak position and coating thermophysical properties indicates that the precision of this NDE technique may easily identify the μm-level of the thermal growth oxide (TGO) changes inside the TBCs.

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Nano Research
Pages 4582-4592
Cite this article:
Han T, Ding S, Wang Z, et al. High-precision nondestructive evaluation of a thermal barrier coating based on perovskite quantum dot anion exchange. Nano Research, 2024, 17(5): 4582-4592. https://doi.org/10.1007/s12274-023-6355-x
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Received: 30 August 2023
Revised: 12 November 2023
Accepted: 21 November 2023
Published: 12 January 2024
© Tsinghua University Press 2023
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