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Nano Research 2024, 17(5): 3988-3996 https://doi.org/10.1007/s12274-023-6324-4
Communication | Issue | Published: 13 December 2023

Fabrication of highly effective electrodes for iron chromium redox flow battery

Show Author's Information Yingchun Niu,§,  Chao Guo,§,  Yinping Liu,  Guangfu Wu,  Tianhang Zhou,  Fangang Qu,  Ziji Yang,  Ali Heydari,  Chunming Xu,  Quan Xu( )
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China

§ Yingchun Niu and Chao Guo contributed equally to this work.

Keywords:
density functional theory (DFT) calculation, carbon cloth, electron, redox flow battery, defect site, iron chromium
Topics:
Electric energy storage
Cite this article:
Niu Y, Guo C, Liu Y, et al. Fabrication of highly effective electrodes for iron chromium redox flow battery. Nano Research, 2024, 17(5): 3988-3996. https://doi.org/10.1007/s12274-023-6324-4
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Abstract Full text Electronic supplementary material About this article

Iron-chromium redox flow batteries (ICRFBs) have emerged as promising energy storage devices due to their safety, environmental protection, and reliable performance. The carbon cloth (CC), often used in ICRFBs as the electrode, provides a suitable platform for electrochemical processes owing to its high surface area and interconnected porous structure. However, the CC electrodes have issues, such as, insufficient electron transfer performance, which limits their industrial application. Here, we employed silicic acid etching to carve dense nano-porous structures on the surface of CC electrodes based on the favorable design of ICRFBs and the fundamental principles of electrode polarization losses. As a result, we developed a multifunctional carbon cloth electrode with abundant vacancies, notably enhancing the performance of the battery. The fabricated electrode showcased a wealth of defect sites and superior electronic transport properties, offering an extensive and effective reaction area for rapidly flowing electrolytes. With an electrode compression ratio of 40% and the highest current density in ICRFBs so far (140 mA·cm−2), the battery achieved the average energy efficiency of 81.3%, 11.24% enhancement over the previously published work. Furthermore, throughout 100 charge–discharge cycles, the average energy efficiency degradation was negligible (~ 0.04%), which has the potential to become the most promising candidate for large-scale and long-term electrochemical energy storage applications.


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Abstract
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Electronic supplementary material
About this article

Fabrication of highly effective electrodes for iron chromium redox flow battery

Show Author's information Yingchun Niu,§, Chao Guo,§, Yinping Liu, Guangfu Wu, Tianhang Zhou, Fangang Qu, Ziji Yang, Ali Heydari, Chunming Xu, Quan Xu( )
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China

§ Yingchun Niu and Chao Guo contributed equally to this work.

Abstract

Iron-chromium redox flow batteries (ICRFBs) have emerged as promising energy storage devices due to their safety, environmental protection, and reliable performance. The carbon cloth (CC), often used in ICRFBs as the electrode, provides a suitable platform for electrochemical processes owing to its high surface area and interconnected porous structure. However, the CC electrodes have issues, such as, insufficient electron transfer performance, which limits their industrial application. Here, we employed silicic acid etching to carve dense nano-porous structures on the surface of CC electrodes based on the favorable design of ICRFBs and the fundamental principles of electrode polarization losses. As a result, we developed a multifunctional carbon cloth electrode with abundant vacancies, notably enhancing the performance of the battery. The fabricated electrode showcased a wealth of defect sites and superior electronic transport properties, offering an extensive and effective reaction area for rapidly flowing electrolytes. With an electrode compression ratio of 40% and the highest current density in ICRFBs so far (140 mA·cm−2), the battery achieved the average energy efficiency of 81.3%, 11.24% enhancement over the previously published work. Furthermore, throughout 100 charge–discharge cycles, the average energy efficiency degradation was negligible (~ 0.04%), which has the potential to become the most promising candidate for large-scale and long-term electrochemical energy storage applications.

Keywords: density functional theory (DFT) calculation, carbon cloth, electron, redox flow battery, defect site, iron chromium

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Publication history
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Acknowledgements

Publication history

Received: 03 October 2023
Revised: 26 October 2023
Accepted: 06 November 2023
Published: 13 December 2023
Issue date: May 2024

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This research was funded by the National Natural Science Foundation of China (Nos. 22308378, 22308380, and 52211530034).

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