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Review Article

Recent advances in metal-organic frameworks for electrochemical performance of batteries

Haoyang Xu1Pengbiao Geng2Wanchang Feng1Meng Du1Dae Joon Kang3Huan Pang1 ( )
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China
Department of Physics, Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 16419, Republic of Korea
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Abstract

Energy shortage hinders the rapid development of today’s society, and the emergence of electronic travel equipment alleviates this phenomenon to a certain extent. The batteries are the energy storage part of electric equipment. Metal-organic frameworks (MOFs) are a fresh sort of porous crystal materials with controllable structure, large specific surface area, and adjustable pore size. MOFs are good electrode materials, which are used to make a variety of friendly environment, long cycling life and superior energy density of new batteries. Furthermore, MOFs are also used in separators and electrolytes, which have a lot of application space in batteries. In this review, the up-to-date research advance of MOF materials in various kinds of batteries (lithium-ion batteries, lithium oxygen batteries, lithium sulfur batteries, zinc-ion batteries, potassium-ion batteries, etc.) is reviewed. Moreover, concisely introduced several conventional synthesis approaches of MOFs. Finally, Perspectives and directions on the future improvement of MOF in energy storage devices are proposed for meeting the requirement of practical applications.

Graphical Abstract

With the increasing demand for energy, metal-organic frameworks (MOFs) have been widely studied in the field of battery electrochemistry, including lithium-ion batteries, lithium-sulfur batteries, potassium-ion batteries, zinc-ion batteries, and so on. In this review, we have reviewed and evaluated the simple synthesis method, modulated morphology and electrochemical performance of MOFs in various new types of batteries.

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Nano Research
Pages 3472-3492

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Cite this article:
Xu H, Geng P, Feng W, et al. Recent advances in metal-organic frameworks for electrochemical performance of batteries. Nano Research, 2024, 17(5): 3472-3492. https://doi.org/10.1007/s12274-023-6251-4
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Received: 05 September 2023
Revised: 06 October 2023
Accepted: 08 October 2023
Published: 28 November 2023
© Tsinghua University Press 2023