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Nano Research 2024, 17(4): 2646-2654 https://doi.org/10.1007/s12274-023-6059-2
Research Article | Issue | Published: 31 August 2023

Adjusting oxygen vacancy of VO2·xH2O nanoarray architectures for efficient NH4+ storage

Show Author's Information Jia’ni Gong1,  Pengfei Bai2,  Jingjing Sun1,  Yanyan Liu1,  Xueying Dong1,  Tao Hu1( ),  Changgong Meng1,3,  Yifu Zhang1( )
School of Chemistry, Dalian University of Technology, Dalian 116024, China
School of Chemistry and Materials Sciences, CAS Key Laboratory of Materials for Energy Conversion, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230026, China
College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China
Keywords:
anode material, oxygen defects, ammonium-ion battery, hydrate vanadium dioxide
Topics:
Ion batteries
Cite this article:
Gong J, Bai P, Sun J, et al. Adjusting oxygen vacancy of VO2·xH2O nanoarray architectures for efficient NH4+ storage. Nano Research, 2024, 17(4): 2646-2654. https://doi.org/10.1007/s12274-023-6059-2
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Abstract Full text Electronic supplementary material About this article

Aqueous rechargeable batteries are the promising energy storge technology due to their safety, low cost, and environmental friendliness. Ammonium ion (NH4+) is an ideal charge carrier for such batteries because of its small hydration radius and low molar mass. In this study, VO2·xH2O with rich oxygen defects (d-HVO) is designed and synthesized, and it exhibits unique nanoarray structure and good electrochemical performances for NH4+ storge. Experimental and calculation results indicate that oxygen defects in d-HVO can enhance the conductivity and diffusion rate of NH4+, leading to improved electrochemical performances. The most significant improvement is observed in d-HVO with 2 mmol thiourea (d-HVO-2) (220 mAh·g−1 at 0.1 A·g−1), which has a moderate defect content. A full cell is assembled using d-HVO-2 as the anode and polyaniline (PANI) as the cathode, which shows excellent cycling stability with a capacity retention rate of 80% after 1000 cycles and outstanding power density up to 4540 W·kg−1. Moreover, the flexible d-HVO-2||PANI battery, based on quasi-solid electrolyte, shows excellent flexibility under different bending conditions. This study provides a new approach for designing and developing high-performance NH4+ storage electrode materials.


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Abstract
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Electronic supplementary material
About this article

Adjusting oxygen vacancy of VO2·xH2O nanoarray architectures for efficient NH4+ storage

Show Author's information Jia’ni Gong1, Pengfei Bai2, Jingjing Sun1, Yanyan Liu1, Xueying Dong1, Tao Hu1( ), Changgong Meng1,3, Yifu Zhang1( )
School of Chemistry, Dalian University of Technology, Dalian 116024, China
School of Chemistry and Materials Sciences, CAS Key Laboratory of Materials for Energy Conversion, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230026, China
College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China

Abstract

Aqueous rechargeable batteries are the promising energy storge technology due to their safety, low cost, and environmental friendliness. Ammonium ion (NH4+) is an ideal charge carrier for such batteries because of its small hydration radius and low molar mass. In this study, VO2·xH2O with rich oxygen defects (d-HVO) is designed and synthesized, and it exhibits unique nanoarray structure and good electrochemical performances for NH4+ storge. Experimental and calculation results indicate that oxygen defects in d-HVO can enhance the conductivity and diffusion rate of NH4+, leading to improved electrochemical performances. The most significant improvement is observed in d-HVO with 2 mmol thiourea (d-HVO-2) (220 mAh·g−1 at 0.1 A·g−1), which has a moderate defect content. A full cell is assembled using d-HVO-2 as the anode and polyaniline (PANI) as the cathode, which shows excellent cycling stability with a capacity retention rate of 80% after 1000 cycles and outstanding power density up to 4540 W·kg−1. Moreover, the flexible d-HVO-2||PANI battery, based on quasi-solid electrolyte, shows excellent flexibility under different bending conditions. This study provides a new approach for designing and developing high-performance NH4+ storage electrode materials.

Keywords: anode material, oxygen defects, ammonium-ion battery, hydrate vanadium dioxide

References(66)

[1]

Cao, J.; Zhang, D. D.; Zhang, X. Y.; Sawangphruk, M.; Qin, J. Q.; Liu, R. P. A universal and facile approach to suppress dendrite formation for a Zn and Li metal anode. J. Mater. Chem. A 2020, 8, 9331–9344.
DOI Google Scholar
[2]

Liu, C.; Li, F.; Ma, L. P.; Cheng, H. M. Advanced materials for energy storage. Adv. Mater. 2010, 22, E28–E62.
DOI Google Scholar
[3]

Huang, Y.; Zhu, M. S.; Huang, Y.; Pei, Z. X.; Li, H. F.; Wang, Z. F.; Xue, Q.; Zhi, C. Y. Multifunctional energy storage and conversion devices. Adv. Mater. 2016, 28, 8344–8364.
DOI Google Scholar
[4]

Yang, Z. G.; Zhang, J. L.; Kintner-Meyer, M. C. W.; Lu, X. C.; Choi, D.; Lemmon, J. P.; Liu, J. Electrochemical energy storage for green grid. Chem. Rev. 2011, 111, 3577–3613.
DOI Google Scholar
[5]

Pasta, M.; Wessells, C. D.; Huggins, R. A.; Cui, Y. A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage. Nat. Commun. 2012, 3, 1149.
DOI Google Scholar
[6]

Jiang, H. M.; Zhang, Y. F.; Waqar, M.; Yang, J.; Liu, Y. Y.; Sun, J. J.; Feng, Z. Y.; Sun, J. G.; Pan, Z. H.; Meng, C. G. et al. Anomalous Zn2+ storage behavior in dual-ion-in-sequence reconstructed vanadium oxides. Adv. Funct. Mater. 2023, 33, 2213127.
DOI Google Scholar
[7]

Wu, X. Y.; Hong, J. J.; Shin, W.; Ma, L.; Liu, T. C.; Bi, X. X.; Yuan, Y. F.; Qi, Y. T.; Surta, T. W.; Huang, W. X. et al. Diffusion-free grotthuss topochemistry for high-rate and long-life proton batteries. Nat. Energy 2019, 4, 123–130.
DOI Google Scholar
[8]

Jiang, H.; Hong, J. J.; Wu, X. Y.; Surta, T. W.; Qi, Y. T.; Dong, S. Y.; Li, Z. F.; Leonard, D. P.; Holoubek, J. J.; Wong, J. C. et al. Insights on the proton insertion mechanism in the electrode of hexagonal tungsten oxide hydrate. J. Am. Chem. Soc. 2018, 140, 11556–11559.
DOI Google Scholar
[9]

Li, J.; Yan, H. H.; Xu, C. W.; Liu, Y. W.; Zhang, X. K.; Xia, M. T.; Zhang, L. Y.; Shu, J. Insights into host materials for aqueous proton batteries: Structure, mechanism and prospect. Nano Energy 2021, 89, 106400.
DOI Google Scholar
[10]

Wu, Y. L.; Dong, S. Y.; Lv, N.; Xu, Z. K.; Ren, R. Q.; Zhu, G. Y.; Huang, B. L.; Zhang, Y. Z.; Dong, X. C. Unlocking the high capacity ammonium-ion storage in defective vanadium dioxide. Small 2022, 18, 2204888.
DOI Google Scholar
[11]

Chao, D. L.; Fan, H. J. Intercalation pseudocapacitive behavior powers aqueous batteries. Chem 2019, 5, 1359–1361.
DOI Google Scholar
[12]

Zheng, R. T.; Li, Y. H.; Yu, H. X.; Zhang, X. K.; Yang, D.; Yan, L.; Li, Y.; Shu, J.; Su, B. L. Ammonium ion batteries: Material, electrochemistry and strategy. Angew. Chem., Int. Ed. 2023, 62, e202301629.
DOI Google Scholar
[13]

Xia, M. T.; Zhang, X. K.; Yu, H. X.; Yang, Z. W.; Chen, S.; Zhang, L. Y.; Shui, M.; Xie, Y.; Shu, J. Hydrogen bond chemistry in Fe4[Fe(CN)6]3 host for aqueous NH4+ batteries. Chem. Eng. J. 2021, 421, 127759.
DOI Google Scholar
[14]

Wu, Y. L.; Xu, Z. K.; Ren, R. Q.; Lv, N.; Yang, J. Y.; Zhang, J. Y.; Ren, H.; Dong, S. Y.; Dong, X. C. Flexible ammonium-ion pouch cells based on a tunneled manganese dioxide cathode. ACS Appl. Mater. Interfaces 2023, 15, 12434–12442.
DOI Google Scholar
[15]

Dong, S. Y.; Shin, W.; Jiang, H.; Wu, X. Y.; Li, Z. F.; Holoubek, J.; Stickle, W. F.; Key, B.; Liu, C.; Lu, J. et al. Ultra-fast NH4+ storage: Strong H bonding between NH4+ and Bi-layered V2O5. Chem 2019, 5, 1537–1551.
DOI Google Scholar
[16]

Wang, P.; Zhang, Y. F.; Feng, Z. Y.; Liu, Y. Y.; Meng, C. G. A dual-polymer strategy boosts hydrated vanadium oxide for ammonium-ion storage. J. Colloid Interface Sci. 2022, 606, 1322–1332.
DOI Google Scholar
[17]

Wang, P.; Zhang, Y. F.; Jiang, H. M.; Dong, X. Y.; Meng, C. G. Ammonium vanadium oxide framework with stable NH4+ aqueous storage for flexible quasi-solid-state supercapacitor. Chem. Eng. J. 2022, 427, 131548.
DOI Google Scholar
[18]

Zhang, X. K.; Xia, M. T.; Yu, H. X.; Zhang, J. W.; Yang, Z. W.; Zhang, L. Y.; Shu, J. Hydrogen bond-assisted ultra-stable and fast aqueous NH4+ storage. Nano-Micro Lett. 2021, 13, 139.
DOI Google Scholar
[19]

Zhang, X. K.; Xia, M. T.; Liu, T. T.; Peng, N.; Yu, H. X.; Zheng, R. T.; Zhang, L. Y.; Shui, M.; Shu, J. Copper hexacyanoferrate as ultra-high rate host for aqueous ammonium ion storage. Chem. Eng. J. 2021, 421, 127767.
DOI Google Scholar
[20]

Chen, X. Y.; Wang, P.; Feng, Z. Y.; Meng, C. G.; Zhang, Y. F. Conductive polymer intercalated vanadium oxide on carbon cloth for fast ammonium-ion storage in supercapacitor applications. Chem. Eng. J. 2022, 445, 136747.
DOI Google Scholar
[21]

Chen, X. Y.; Wang, P.; Feng, Z. Y.; Liu, Y. Y.; Cui, M.; Meng, C. G.; Zhang, Y. F. Structural regulation of vanadium oxide by poly(3,4-ethylenedioxithiophene) intercalation for ammonium-ion supercapacitors. Adv. Sens. Energy Mater. 2022, 1, 100013.
DOI Google Scholar
[22]

Ma, Y.; Sun, T. J.; Nian, Q. S.; Zheng, S. B.; Ma, T.; Wang, Q. R.; Du, H. H.; Tao, Z. L. Alloxazine as anode material for high-performance aqueous ammonium-ion battery. Nano Res. 2022, 15, 2047–2051.
DOI Google Scholar
[23]

Liang, G. J.; Wang, Y. L.; Huang, Z. D.; Mo, F. N.; Li, X. L.; Yang, Q.; Wang, D. H.; Li, H. F.; Chen, S. M.; Zhi, C. Y. Initiating hexagonal MoO3 for superb-stable and fast NH4+ storage based on hydrogen bond chemistry. Adv. Mater. 2020, 32, 1907802.
DOI Google Scholar
[24]

Zhang, Y. Z.; Liang, J.; Huang, Z. H.; Wang, Q.; Zhu, G. Y.; Dong, S. Y.; Liang, H. F.; Dong, X. C. Ionically conductive tunnels in h-WO3 enable high-rate NH4+ storage. Adv. Sci. 2022, 9, 2105158.
DOI Google Scholar
[25]

Wang, P. J.; Shi, X. D.; Wu, Z. X.; Guo, S.; Zhou, J.; Liang, S. Q. Layered hydrated vanadium oxide as highly reversible intercalation cathode for aqueous Zn-ion batteries. Carbon Energy 2020, 2, 294–301.
DOI Google Scholar
[26]
Wang, S. W.; Zhang, H.; Zhao, K.; Liu, W. Q.; Luo, N. R.; Zhao, J. N.; Wu, S. D.; Ding, J. W.; Fang, S. M.; Cheng, F. Y. Designing interstitial boron-doped tunnel-type vanadium dioxide cathode for enhancing zinc ion storage capability. Carbon Energy, in press, https://doi.org/10.1002/cey2.330.
[27]

Arnon, D. I.; Tsujimoto, H. Y.; Tang, G. M. S. Proton transport in photooxidation of water: A new perspective on photosynthesis. Proc. Natl. Acad. Sci. USA 1981, 78, 2942–2946.
DOI Google Scholar
[28]

Xiao, B. W. Intercalated water in aqueous batteries. Carbon Energy 2020, 2, 251–264.
DOI Google Scholar
[29]

Kim, H. S.; Cook, J. B.; Lin, H.; Ko, J. S.; Tolbert, S. H.; Ozolins, V.; Dunn, B. Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x. Nat. Mater. 2017, 16, 454–460.
DOI Google Scholar
[30]

Cao, J.; Zhang, D. D.; Yue, Y. L.; Wang, X.; Pakornchote, T.; Bovornratanaraks, T.; Zhang, X. Y.; Wu, Z. S.; Qin, J. Q. Oxygen defect enriched (NH4)2V10O25·8H2O nanosheets for superior aqueous zinc-ion batteries. Nano Energy 2021, 84, 105876.
DOI Google Scholar
[31]

Sundriyal, S. K.; Sharma, Y. Controlled generation and tuning the oxygen defects in nanofibers of Ca2Fe2O5 toward high and stable Li-ion battery anode. Appl. Surf. Sci. 2021, 560, 150055.
DOI Google Scholar
[32]

Yao, Z. J.; Xia, X. H.; Zhang, S. Z.; Zhou, C. A.; Pan, G. X.; Xiong, Q. Q.; Wang, Y. D.; Wang, X. L.; Tu, J. P. Oxygen defect boosted N-doped Ti2Nb10O29 anchored on core-branch carbon skeleton for both high-rate liquid & solid-state lithium ion batteries. Energy Storage Mater. 2020, 25, 555–562.
DOI Google Scholar
[33]

Liang, X. Y.; Yan, L. J.; Li, W. P.; Bai, Y. C.; Zhu, C.; Qiang, Y. J.; Xiong, B. X.; Xiang, B.; Zou, X. F. Flexible high-energy and stable rechargeable vanadium-zinc battery based on oxygen defect modulated V2O5 cathode. Nano Energy 2021, 87, 106164.
DOI Google Scholar
[34]

Nguyen, V. P.; Park, J. S.; Yuk, J. M.; Oh, M.; Kim, J. H.; Lee, S. M. Boosted Zn2+ storage performance of hydrated vanadium oxide by defect and heterostructure. J. Mater. Chem. A 2022, 10, 13428–13438.
DOI Google Scholar
[35]
Liu, Y. Y.; Feng, Z. Y.; Jiang, H. M.; Dong, X. Y.; Meng, C. G.; Zhang, Y. F. Tailoring NH4+ storage by regulating oxygen defect in ammonium vanadate. Green Energy Environ., in press, https://doi.org/10.1016/j.gee.2023.02.001.
[36]

Kuchena, S. F.; Wang, Y. Superior polyaniline cathode material with enhanced capacity for ammonium ion storage. ACS Appl. Energy Mater. 2020, 3, 11690–11698.
DOI Google Scholar
[37]

Li, Z. Q.; Ren, Y. K.; Mo, L.; Liu, C. F.; Hsu, K.; Ding, Y. C.; Zhang, X. X.; Li, X. L.; Hu, L. H.; Ji, D. H. et al. Impacts of oxygen vacancies on zinc ion intercalation in VO2. ACS Nano 2020, 14, 5581–5589.
DOI Google Scholar
[38]

Chang, X.; Yang, X. F.; Qiao, Y.; Wang, S.; Zhang, M. H.; Xu, J.; Wang, D. H.; Bu, X. H. Confined heteropoly blues in defected Zr-MOF (bottle around ship) for high-efficiency oxidative desulfurization. Small 2020, 16, 1906432.
DOI Google Scholar
[39]

Liu, R. Q.; Liu, W. H.; Bu, Y. L.; Yang, W. W.; Wang, C.; Priest, C.; Liu, Z. W.; Wang, Y. Z.; Chen, J. Y.; Wang, Y. H. et al. Conductive porous laminated vanadium nitride as carbon-free hosts for high-loading sulfur cathodes in lithium-sulfur batteries. ACS Nano 2020, 14, 17308–17320.
DOI Google Scholar
[40]

Fang, G. Z.; Zhu, C. Y.; Chen, M. H.; Zhou, J.; Tang, B. Y.; Cao, X. X.; Zheng, X. S.; Pan, A. Q.; Liang, S. Q. Suppressing manganese dissolution in potassium manganate with rich oxygen defects engaged high-energy-density and durable aqueous zinc-ion battery. Adv. Funct. Mater. 2019, 29, 1808375.
DOI Google Scholar
[41]

Zeng, Y. X.; Lai, Z. Z.; Han, Y.; Zhang, H. Z.; Xie, S. L.; Lu, X. H. Oxygen-vacancy and surface modulation of ultrathin nickel cobaltite nanosheets as a high-energy cathode for advanced Zn-ion batteries. Adv. Mater. 2018, 30, 1802396.
DOI Google Scholar
[42]

Meng, T.; Li, B.; Hu, L.; Yang, H.; Fan, W. J.; Zhang, S. Q.; Liu, P.; Li, M. Y.; Gu, F. L.; Tong, Y. X. Engineering of oxygen vacancy and electric-field effect by encapsulating lithium titanate in reduced graphene oxide for superior lithium ion storage. Small Methods 2019, 3, 1900185.
DOI Google Scholar
[43]

He, H. N.; Huang, D.; Gan, Q. M.; Hao, J. N.; Liu, S. L.; Wu, Z. B.; Pang, W. K.; Johannessen, B.; Tang, Y. G.; Luo, J. L. et al. Anion vacancies regulating endows MoSSe with fast and stable potassium ion storage. ACS Nano 2019, 13, 11843–11852.
DOI Google Scholar
[44]

Tang, B. Y.; Fang, G. Z.; Zhou, J.; Wang, L. B.; Lei, Y. P.; Wang, C.; Lin, T. Q.; Tang, Y.; Liang, S. Q. Potassium vanadates with stable structure and fast ion diffusion channel as cathode for rechargeable aqueous zinc-ion batteries. Nano Energy 2018, 51, 579–587.
DOI Google Scholar
[45]

Liu, N. N.; Wu, X.; Yin, Y. Y.; Chen, A. S.; Zhao, C. Y.; Guo, Z. K.; Fan, L. S.; Zhang, N. Q. Constructing the efficient ion diffusion pathway by introducing oxygen defects in Mn2O3 for high-performance aqueous zinc-ion batteries. ACS Appl. Mater. Interfaces 2020, 12, 28199–28205.
DOI Google Scholar
[46]

Guo, R. T.; Liu, X.; Xia, F. J.; Jiang, Y. L.; Zhang, H. Z.; Huang, M.; Niu, C. J.; Wu, J. S.; Zhao, Y.; Wang, X. P. et al. Large-scale integration of a zinc metasilicate interface layer guiding well-regulated Zn deposition. Adv. Mater. 2022, 34, 2202188.
DOI Google Scholar
[47]

Holoubek, J. J.; Jiang, H.; Leonard, D.; Qi, Y. T.; Bustamante, G. C.; Ji, X. L. Amorphous titanic acid electrode: Its electrochemical storage of ammonium in a new water-in-salt electrolyte. Chem. Commun. 2018, 54, 9805–9808.
DOI Google Scholar
[48]

Wu, T. Q.; Zhao, Z. D.; Zhang, J. J.; Zhang, C.; Guo, Y. X.; Cao, Y. J.; Pan, S. X.; Liu, Y. C.; Liu, P. Y.; Ge, Y. H. et al. Thick electrode with thickness-independent capacity enabled by assembled two-dimensional porous nanosheets. Energy Storage Mater. 2021, 36, 265–271.
DOI Google Scholar
[49]

Kuang, Y. D.; Chen, C. J.; Kirsch, D.; Hu, L. B. Thick electrode batteries: Principles, opportunities, and challenges. Adv. Energy Maer. 2019, 9, 1901457.
DOI Google Scholar
[50]

Zhang, X.; Ju, Z. Y.; Zhu, Y.; Takeuchi, K. J.; Takeuchi, E. S.; Marschilok, A. C.; Yu, G. H. Multiscale understanding and architecture design of high energy/power lithium-ion battery electrodes. tAdv. Energy Mater. 2021, 11, 2000808.
DOI Google Scholar
[51]

Lv, Z. Q.; Yue, M.; Ling, M. X.; Zhang, H. M.; Yan, J. W.; Zheng, Q.; Li, X. F. Controllable design coupled with finite element analysis of low-tortuosity electrode architecture for advanced sodium-ion batteries with ultra-high mass loading. Adv. Energy Mater. 2021, 11, 2003725.
DOI Google Scholar
[52]

Gong, J. N.; Bai, P. F.; Zhang, Y. F.; Wang, Q. S.; Sun, J. J.; Liu, Y. Y.; Jiang, H. M.; Feng, Z. Y.; Hu, T.; Meng, C. G. Vanadate ion promoting the transformation of α-phase molybdenum trioxide (α-MoO3) to h-phase MoO3 (h-MoO3) for boosted Zn-ion storage. J. Colloid Interface Sci. 2023, 647, 115–123.
DOI Google Scholar
[53]

Zhang, D. D.; Cao, J.; Zhang, X. Y.; Insin, N.; Wang, S. M.; Han, J. T.; Zhao, Y. S.; Qin, J. Q.; Huang, Y. H. Inhibition of manganese dissolution in Mn2O3 cathode with controllable Ni2+ incorporation for high-performance zinc ion battery. Adv. Funct. Mater. 2021, 31, 2009412.
DOI Google Scholar
[54]

Ma, S. Y.; Jiang, T.; Deng, J. B.; Zhang, Q.; Ou, Y. J.; Liu, X. H.; Lin, C. F.; Wang, K. K.; Zhao, X. S. VPO5: An all-climate lithium-storage material. Energy Storage Mater. 2022, 46, 366–373.
DOI Google Scholar
[55]

Walker, M. J.; Jarry, A.; Pronin, N.; Ballard, J.; Rubloff, G. W.; Brillson, L. J. Nanoscale depth and lithiation dependence of V2O5 band structure by cathodoluminescence spectroscopy. J. Mater. Chem. A 2020, 8, 11800–11810.
DOI Google Scholar
[56]

Yan, M. Y.; He, P.; Chen, Y.; Wang, S. Y.; Wei, Q. L.; Zhao, K. N.; Xu, X.; An, Q. Y.; Shuang, Y.; Shao, Y. Y. et al. Water-lubricated intercalation in V2O5·nH2O for high-capacity and high-rate aqueous rechargeable zinc batteries. Adv. Mater. 2018, 30, 1703725.
DOI Google Scholar
[57]

Yang, J.; Zhang, Q. C.; Wang, Z. X.; Wang, Z.; Kang, L. X.; Qi, M.; Chen, M. X.; Liu, W.; Gong, W. B.; Lu, W. B. et al. Rational construction of self-standing sulfur-doped Fe2O3 anodes with promoted energy storage capability for wearable aqueous rechargeable NiCo-Fe batteries. Adv. Energy Mater. 2020, 10, 2001064.
DOI Google Scholar
[58]

Ma, Z. Y.; Rui, K.; Zhang, Y.; Li, D. S.; Wang, Q. Q.; Zhang, Q.; Du, M.; Yan, J. X.; Zhang, C.; Huang, X. et al. Nitrogen boosts defective vanadium oxide from semiconducting to metallic merit. Small 2019, 15, 1900583.
DOI Google Scholar
[59]

Yang, K.; Hu, Y. Y.; Li, L. Y.; Cui, L. L.; He, L.; Wang, S. J.; Zhao, J. W.; Song, Y. F. First high-nuclearity mixed-valence polyoxometalate with hierarchical interconnected Zn2+ migration channels as an advanced cathode material in aqueous zinc-ion battery. Nano Energy 2020, 74, 104851.
DOI Google Scholar
[60]

Liu, Y. Y.; Zhang, Y. F.; Jiang, H. M.; Sun, J. J.; Feng, Z. Y.; Hu, T.; Meng, C. G.; Pan, Z. H. Synergistic engineering of oxygen-defect and heterojunction boosts Zn2+ (de)intercalation kinetics in vanadium oxide for high-performance zinc-ion batteries. Chem. Eng. J. 2022, 435, 134949.
DOI Google Scholar
[61]

Zhang, Z. C. Y.; Xi, B. J.; Wang, X.; Ma, X. J.; Chen, W. H.; Feng, J. K.; Xiong, S. L. Oxygen defects engineering of VO2·xH2O nanosheets via in situ polypyrrole polymerization for efficient aqueous zinc ion storage. Adv. Funct. Mater. 2021, 31, 2103070.
DOI Google Scholar
[62]

Lu, W.; Yan, L.; Ye, W. Q.; Ning, J. Q.; Zhong, Y. J.; Hu, Y. Defect engineering of electrode materials towards superior reaction kinetics for high-performance supercapacitors. J. Mater. Chem. A 2022, 10, 15267–15296.
DOI Google Scholar
[63]

Yao, Y.; Zhu, Y. H.; Pan, C. Q.; Wang, C. Y.; Hu, S. Y.; Xiao, W.; Chi, X.; Fang, Y. R.; Yang, J.; Deng, H. T. et al. Interfacial sp C-O-Mo hybridization originated high-current density hydrogen evolution. J. Am. Chem. Soc. 2021, 143, 8720–8730.
DOI Google Scholar
[64]

Yang, W.; Dong, L. B.; Yang, W.; Xu, C. J.; Shao, G. J.; Wang, G. X. 3D oxygen-defective potassium vanadate/carbon nanoribbon networks as high-performance cathodes for aqueous zinc-ion batteries. Small Methods 2020, 4, 1900670.
DOI Google Scholar
[65]

Liao, M.; Wang, J. W.; Ye, L.; Sun, H.; Wen, Y. Z.; Wang, C.; Sun, X. M.; Wang, B. J.; Peng, H. S. A deep-cycle aqueous zinc-ion battery containing an oxygen-deficient vanadium oxide cathode. Angew. Chem., Int. Ed. 2020, 59, 2273–2278.
DOI Google Scholar
[66]

Padmapriya, S.; Harinipriya, S.; Jaidev, K.; Sudha, V.; Kumar, D.; Pal, S. Storage and evolution of hydrogen in acidic medium by polyaniline. Int. J. Energy Res. 2018, 42, 1196–1209.
DOI Google Scholar
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Publication history
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Acknowledgements

Publication history

Received: 16 June 2023
Revised: 26 July 2023
Accepted: 29 July 2023
Published: 31 August 2023
Issue date: April 2024

Copyright

© Tsinghua University Press 2023

Acknowledgements

We thank the Natural Science Foundation of Liaoning Province (No. 2023-MS-115) and the Large Instrument and Equipment Open Foundation of Dalian University of Technology to support this work.

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