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Research Article

Multiresponsive, easy-reversible, and dual-visual Pt(II) salt nanostructures for advanced anti-counterfeiting application

Zhen Su,§, Depeng Li,§, Lixin Zhang, Si Tian, Yuhong Su, Xiaoyun Hu( ), Duan Xiong, Qingqing Guan( )
Key Laboratory of Oil and Gas Fine Chemicals Ministry of Education, College of Chemical Engineering, Xinjiang University, Urumqi 830017, China

§ Zhen Su and Depeng Li contributed equally to this work.

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Graphical Abstract

We propose a multiresponsive, easily reversible and dual-visual perchlorate Pt(II) salt for advanced anticounterfeiting, by adopting two comparable weak interactions that are hydrogen bond and ion dipole interaction to selectively combine H2O or HCHO molecules. The present study provides a valuable strategy for designing smart optical system with multi-stimuli response and controllable reversibility, which would significantly promote its high-security-level anticounterfeiting applications.

Abstract

Smart materials that integrate multi-stimuli response, full reversibility, and dual-visual read-out channel are highly desired for anti-counterfeiting and information encryption applications. Herein, we developed a multiresponsive perchlorate terpyridyl Pt(II) nano complex which could undergo fully reversible conversion between three forms stimulated by water or formaldehyde molecule due to the extent of Pt–Pt interaction. Meanwhile, a dual-visual channel, i.e., the colorimetric channel changed from yellow to orange or red and the corresponding luminescent channel from orange to orange-red or red, has also been found. The weak and equivalent strength of ion-dipole interaction and hydrogen bond that generated between formaldehyde/water and Pt(II) salt result in the easy-control reversibility between the three forms. Furthermore, by introducing different polymer matrices, 1Cl·ClO4@PMMA (1Cl·ClO4:[Pt(tpy)Cl]·ClO4, tpy: 2,2':6',2''-terpyridine), PMMA: poly(methyl methacrylate)) and 1Cl·ClO4@PVA (PVA: polyvinyl alcohol) are successfully constructed, which exhibit different reversible behaviors since the PMMA and PVA matrix exert different influences on the strength of hydrogen-bond. Those smart Pt(II) salt nanostructures present great potential for high-security-level anticounterfeiting application.

Keywords

reversibilityPt(II) complexmultiresponseanticounterfeitinginformation encryption

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Nano Research
Volume 17 Issue 1,
January 2024
Pages 372-381
DOI: 10.1007/s12274-023-6032-0
Cite this article:
Su Z, Li D, Zhang L, et al. Multiresponsive, easy-reversible, and dual-visual Pt(II) salt nanostructures for advanced anti-counterfeiting application. Nano Research, 2024, 17(1): 372-381. https://doi.org/10.1007/s12274-023-6032-0
Topics:
Nano detection

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Received: 30 April 2023
Revised: 22 July 2023
Accepted: 23 July 2023
Published: 24 August 2023
© Tsinghua University Press 2023
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