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Nano Research 2024, 17(3): 1427-1440 https://doi.org/10.1007/s12274-023-6005-3
Review Article | Issue | Published: 05 August 2023

Fluorophosphates and fluorosulfates cathode materials: Progress towards high energy density sodium-ion battery

Show Author's Information Mohammed Hadouchi1,2( ),  Jingrong Hou2,  Toshinari Koketsu2,3,  Abdelilah Lahmar4,  Jiwei Ma2( )
Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Science, Mohammed V University in Rabat, Avenue Ibn Battouta, BP 1014, Rabat, Morocco
Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
Battery Materials Development Section, Business Creation Sector R&D Center, Mitsui Mining & Smelting Co., Ltd., 362-0021 Saitama, Japan
Laboratoiry of Condensed Matter Physics, University of Picardie Jules Verne, 33 Rue Saint-Leu 80039, Amiens, France
Keywords:
crystal structure, high energy density, sodium-ion battery, fluorophosphates, fluorosulfates, intercalation mechanism
Topics:
Ion batteries
Cite this article:
Hadouchi M, Hou J, Koketsu T, et al. Fluorophosphates and fluorosulfates cathode materials: Progress towards high energy density sodium-ion battery. Nano Research, 2024, 17(3): 1427-1440. https://doi.org/10.1007/s12274-023-6005-3
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Abstract Full text About this article

The rapid diffusion of renewable energy boosts the wide deployment of large-scale energy storage system. With the low cost and high crustal abundance, sodium-ion battery (SIB) technology is expected to become a dominant technology in that area in the future. Toward the practical application, novel cathode materials are urged to develop that show high energy density without sacrificing their cost and benignity to the environment. While the years of many studies, this still remains a huge challenge to battery scientists. In this review, we discuss recent breakthroughs in SIB cathode materials with high energy density, namely fluorphosphates and fluorosulfates. The design of materials, the crystal structure, the electrochemical performance, and the underlaying intercalation mechanism are systematically reviewed. Useful strategies and research directions are also provided to advance future high-energy, low-cost, and ecofriendly cathode materials for next generation SIB.


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About this article

Fluorophosphates and fluorosulfates cathode materials: Progress towards high energy density sodium-ion battery

Show Author's information Mohammed Hadouchi1,2( ), Jingrong Hou2, Toshinari Koketsu2,3, Abdelilah Lahmar4, Jiwei Ma2( )
Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Science, Mohammed V University in Rabat, Avenue Ibn Battouta, BP 1014, Rabat, Morocco
Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
Battery Materials Development Section, Business Creation Sector R&D Center, Mitsui Mining & Smelting Co., Ltd., 362-0021 Saitama, Japan
Laboratoiry of Condensed Matter Physics, University of Picardie Jules Verne, 33 Rue Saint-Leu 80039, Amiens, France

Abstract

The rapid diffusion of renewable energy boosts the wide deployment of large-scale energy storage system. With the low cost and high crustal abundance, sodium-ion battery (SIB) technology is expected to become a dominant technology in that area in the future. Toward the practical application, novel cathode materials are urged to develop that show high energy density without sacrificing their cost and benignity to the environment. While the years of many studies, this still remains a huge challenge to battery scientists. In this review, we discuss recent breakthroughs in SIB cathode materials with high energy density, namely fluorphosphates and fluorosulfates. The design of materials, the crystal structure, the electrochemical performance, and the underlaying intercalation mechanism are systematically reviewed. Useful strategies and research directions are also provided to advance future high-energy, low-cost, and ecofriendly cathode materials for next generation SIB.

Keywords: crystal structure, high energy density, sodium-ion battery, fluorophosphates, fluorosulfates, intercalation mechanism

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Publication history
Copyright
Acknowledgements

Publication history

Received: 24 May 2023
Revised: 27 June 2023
Accepted: 13 July 2023
Published: 05 August 2023
Issue date: March 2024

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 22179098).

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