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Communication

Co-doped Ni3S2 nanosheet array: A high-efficiency electrocatalyst for alkaline seawater oxidation

Meng Yue1, Xun He2, Shengjun Sun1, Yuntong Sun1, Mohamed S. Hamdy3( ), Mhamed Benaissa4, Alsamani A. M. Salih4, Jun Liu5( ), Xuping Sun1,2( )
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia
Department of Chemical Engineering, College of Engineering, University of Ha’il, P.O. Box 2440, Ha’il 81441, Saudi Arabia
Department of Otolaryngology-Head & Neck Surgery, West China Hospital, Sichuan University, Chengdu 610041, China
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Abstract

Developing efficient and durable oxygen evolution reaction (OER) catalysts holds great promise for green hydrogen production via seawater electrolysis, but remains a challenge. Herein, we report a Co-doped Ni3S2 nanosheet array on Ni foam (Co-Ni3S2/NF) as a high-efficiency OER electrocatalyst for seawater. In alkaline conditions, Co-Ni3S2/NF requires an overpotential of only 368 mV to drive 100 mA·cm–2, superior to Ni3S2/NF (385 mV). Besides, it exhibits at least 50-h continuous electrolysis.

Graphical Abstract

A Co-doped Ni3S2 nanosheet array on Ni foam exhibits remarkable performance towards seawater oxidation, requiring an overpotential of only 368 mV to drive 100 mA·cm−2 in alkaline conditions.

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Nano Research
Pages 1050-1055

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Cite this article:
Yue M, He X, Sun S, et al. Co-doped Ni3S2 nanosheet array: A high-efficiency electrocatalyst for alkaline seawater oxidation. Nano Research, 2024, 17(3): 1050-1055. https://doi.org/10.1007/s12274-023-6002-6
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Received: 25 May 2023
Revised: 28 June 2023
Accepted: 13 July 2023
Published: 01 August 2023
© Tsinghua University Press 2023