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Nano Research 2023, 16(12): 12919-12935 https://doi.org/10.1007/s12274-023-5935-0
Review Article | Issue | Published: 08 August 2023

Recent advances in bimetallic metal-organic frameworks and their derivatives for thermal catalysis

Show Author's Information Fengbin Zheng1,2,  Tian Lin2,3,  Kun Wang1,2,  Yinglong Wang1( ),  Guodong Li2,4( )
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
School of Chemical Science, University of Chinese Academy of Sciences, Beijing 100049, China
School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China
Keywords:
metal-organic frameworks, heterogeneous catalysis, synthesis methods, bimetallic metal nodes, function synergy
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Nanocatalysts
Cite this article:
Zheng F, Lin T, Wang K, et al. Recent advances in bimetallic metal-organic frameworks and their derivatives for thermal catalysis. Nano Research, 2023, 16(12): 12919-12935. https://doi.org/10.1007/s12274-023-5935-0
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Abstract Full text About this article

Compared with monometallic metal-organic frameworks (MOFs) that are synthesized by reacting inorganic metal ions or clusters with bidentate or multidentate ligands via hydrothermal or solvothermal methods, the construction of heterogeneous frameworks like at least two kinds of metal sites in the individual nodes is proved to be an effective way to modulate their properties for advanced catalysis, especially for selective catalysis and multifunctional catalysis. However, it is still very challenging to precisely characterize their microstructures and reveal the relationship among the composition, structure, and their performances. Therefore, it is necessary to summarize the recent progress on bimetallic MOFs for thermal catalysis. First, we summarize the synthesis strategies and characterization methods of bimetallic MOFs and their derivatives. Second, the application of bimetallic MOFs and their derivatives as catalysts in thermal catalysis is discussed, and the relationship among the active components, structures, and their properties is elucidated. Third, the potential challenges and prospects of bimetallic MOF based nanocatalysts are proposed. This review will bring some insights into the design and preparation of bimetallic MOFs based nanocatalysts in the future.


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About this article

Recent advances in bimetallic metal-organic frameworks and their derivatives for thermal catalysis

Show Author's information Fengbin Zheng1,2, Tian Lin2,3, Kun Wang1,2, Yinglong Wang1( ), Guodong Li2,4( )
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
School of Chemical Science, University of Chinese Academy of Sciences, Beijing 100049, China
School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Compared with monometallic metal-organic frameworks (MOFs) that are synthesized by reacting inorganic metal ions or clusters with bidentate or multidentate ligands via hydrothermal or solvothermal methods, the construction of heterogeneous frameworks like at least two kinds of metal sites in the individual nodes is proved to be an effective way to modulate their properties for advanced catalysis, especially for selective catalysis and multifunctional catalysis. However, it is still very challenging to precisely characterize their microstructures and reveal the relationship among the composition, structure, and their performances. Therefore, it is necessary to summarize the recent progress on bimetallic MOFs for thermal catalysis. First, we summarize the synthesis strategies and characterization methods of bimetallic MOFs and their derivatives. Second, the application of bimetallic MOFs and their derivatives as catalysts in thermal catalysis is discussed, and the relationship among the active components, structures, and their properties is elucidated. Third, the potential challenges and prospects of bimetallic MOF based nanocatalysts are proposed. This review will bring some insights into the design and preparation of bimetallic MOFs based nanocatalysts in the future.

Keywords: metal-organic frameworks, heterogeneous catalysis, synthesis methods, bimetallic metal nodes, function synergy

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Publication history
Copyright
Acknowledgements

Publication history

Received: 04 May 2023
Revised: 13 June 2023
Accepted: 14 June 2023
Published: 08 August 2023
Issue date: December 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

The authors acknowledge financial support from the National Key Research and Development Program of China (No. 2021YFA1500403), Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB36000000), the National Natural Science Foundation of China (Nos. 22173024 and 21722102), and Youth Innovation Promotion Association CAS (G. D. L.).

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