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Nano Research 2023, 16(8): 10922-10930 https://doi.org/10.1007/s12274-023-5793-9
Research Article | Issue | Published: 29 June 2023

Insight into the influence of ether and ester electrolytes on the sodium-ion transportation kinetics for hard carbon

Show Author's Information Xiuping Yin,  Zhaomin Wang,  Yang Liu,  Zhixiu Lu,  Hongli Long,  Tao Liu,  Jiujun Zhang,  Yufeng Zhao( )
College of Sciences & Institute for Sustainable Energy, Shanghai University, Shanghai 200444, China
Keywords:
sodium-ion batteries, ether electrolyte, desolvation energy, transportation kinetics, hard carbon (HC)
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Yin X, Wang Z, Liu Y, et al. Insight into the influence of ether and ester electrolytes on the sodium-ion transportation kinetics for hard carbon. Nano Research, 2023, 16(8): 10922-10930. https://doi.org/10.1007/s12274-023-5793-9
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Abstract Full text Electronic supplementary material About this article

The electrochemical performance of hard carbon (HC) materials is closely related to the electrolyte used in the sodium ion batteries (SIBs). Conventional electrolytes carbonate (EC) demonstrates low initial Columbic efficiency (ICE) and poor rate performance, which is one of the main bottlenecks that limits the practical application of HCs. Ether electrolyte (diglyme) was reported to improve the rate performance of HCs. Nevertheless, the underlying mechanism for the excellent rate capability is still lack of in-depth study. In this work, the differences of sodium-ion diffusion between ether and carbonate-base electrolytes in HCs are analyzed layer by layer. Firstly, when sodium-ions are diffused in electrolyte, the diffusion coefficient of sodium-ion in ether electrolyte is about 2.5 times higher than that in ester electrolytes by molecular dynamics (MD) simulation and experimental characterization. Furthermore, when the solvated sodium-ions are diffused into the solid electrolyte interphase (SEI) interface and the HCs material, the enhanced charge transfer kinetics (thin SEI layer (4.6 vs. 12 nm) and low RSEI (1.5 vs. 24 Ω)) at the SEI combined with low desolvation energy (0.248 eV) are responsible for high-rate performance and good cycling stability of HC in ether electrolyte. Therefore, high diffusion coefficient, low desolvation energy, and good interface are the intrinsic reasons for enhanced rate performance in ether electrolyte, which also has guiding significance for the design of other high-rate electrolytes.


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About this article

Insight into the influence of ether and ester electrolytes on the sodium-ion transportation kinetics for hard carbon

Show Author's information Xiuping Yin, Zhaomin Wang, Yang Liu, Zhixiu Lu, Hongli Long, Tao Liu, Jiujun Zhang, Yufeng Zhao( )
College of Sciences & Institute for Sustainable Energy, Shanghai University, Shanghai 200444, China

Abstract

The electrochemical performance of hard carbon (HC) materials is closely related to the electrolyte used in the sodium ion batteries (SIBs). Conventional electrolytes carbonate (EC) demonstrates low initial Columbic efficiency (ICE) and poor rate performance, which is one of the main bottlenecks that limits the practical application of HCs. Ether electrolyte (diglyme) was reported to improve the rate performance of HCs. Nevertheless, the underlying mechanism for the excellent rate capability is still lack of in-depth study. In this work, the differences of sodium-ion diffusion between ether and carbonate-base electrolytes in HCs are analyzed layer by layer. Firstly, when sodium-ions are diffused in electrolyte, the diffusion coefficient of sodium-ion in ether electrolyte is about 2.5 times higher than that in ester electrolytes by molecular dynamics (MD) simulation and experimental characterization. Furthermore, when the solvated sodium-ions are diffused into the solid electrolyte interphase (SEI) interface and the HCs material, the enhanced charge transfer kinetics (thin SEI layer (4.6 vs. 12 nm) and low RSEI (1.5 vs. 24 Ω)) at the SEI combined with low desolvation energy (0.248 eV) are responsible for high-rate performance and good cycling stability of HC in ether electrolyte. Therefore, high diffusion coefficient, low desolvation energy, and good interface are the intrinsic reasons for enhanced rate performance in ether electrolyte, which also has guiding significance for the design of other high-rate electrolytes.

Keywords: sodium-ion batteries, ether electrolyte, desolvation energy, transportation kinetics, hard carbon (HC)

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Publication history
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Acknowledgements

Publication history

Received: 22 March 2023
Revised: 22 April 2023
Accepted: 02 May 2023
Published: 29 June 2023
Issue date: August 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work is supported by the National Natural Science Foundation of China (Nos. 22179077, 51774251, and 21908142), Shanghai Science and Technology Commission’s “2020 Science and Technology In-novation Action Plan” (No. 20511104003), and Natural Science Foundation in Shanghai (No. 21ZR1424200). The authors also thank Shiyanjia Lab (www.shiyanjia.com) for the XPS measurement.

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