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Nano Research 2023, 16(10): 12173-12185 https://doi.org/10.1007/s12274-023-5631-0
Research Article | Issue | Published: 18 May 2023

A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion

Show Author's Information Yuntai Xi1,2,  Fang Dong1,3( ),  Xin Xu4,  Shixing Wu2,  Zhicheng Tang1( ),  Jiyi Zhang2( )
State Key Laboratory for Oxo Synthesis and Selective Oxidation, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
School of Petroleum and Chemical, Lanzhou University of Technology, Lanzhou 730050, China
Dalian National Laboratory for Clean Energy, Dalian 116023, China
Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China
Keywords:
three-dimensional (3D) printing, catalytic oxidation, volatile organic compounds (VOCs), Co-phyllosilicate, ordered porous
Topics:
Oxidation
Cite this article:
Xi Y, Dong F, Xu X, et al. A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion. Nano Research, 2023, 16(10): 12173-12185. https://doi.org/10.1007/s12274-023-5631-0
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Abstract Full text Electronic supplementary material About this article

In this study, a novel three-dimensional (3D)-OMm-Co3O4/SiO2-0.5AP (OMm = ordered macro–meso porous, AP = aluminum phosphate) monolithic catalyst was for the first time constructed successfully with the hierarchical Co-phyllosilicate ultrathin nanosheets growth on the surface of 3D printed ordered macropore–mesoporous SiO2 support. On the one hand, we discovered that the construction of ordered macropore–mesoporous structures is beneficial to the diffusion and adsorption of reactants, intermediates, and products. On the other hand, the formation of hierarchical Co-phyllosilicate ultrathin nanosheets could provide more active Co&+ species, abundant acid sites, and active oxygen. The above factors are in favor of improving the catalytic performance of benzene oxidation, and then a 3D-OMm-Co3O4/SiO2-0.5AP catalyst exhibited the superior catalytic activity. To explore the effect of catalysts structure and morphology, various Co-based catalysts were also constructed. Simultaneously, the 3D-OMm-Co3O4/SiO2-0.5AP catalyst has excellent catalytic performance, water resistance, and thermal stability in the catalytic combustion of benzene due to the strong interactions between Co&+ species and SiO2 in the phyllosilicate. Therefore, this study proposes a new catalyst synthesis method through 3D printing, and presents considerable prospects for the removal of VOCs from industrial applications.


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Electronic supplementary material
About this article

A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion

Show Author's information Yuntai Xi1,2, Fang Dong1,3( ), Xin Xu4, Shixing Wu2, Zhicheng Tang1( ), Jiyi Zhang2( )
State Key Laboratory for Oxo Synthesis and Selective Oxidation, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
School of Petroleum and Chemical, Lanzhou University of Technology, Lanzhou 730050, China
Dalian National Laboratory for Clean Energy, Dalian 116023, China
Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China

Abstract

In this study, a novel three-dimensional (3D)-OMm-Co3O4/SiO2-0.5AP (OMm = ordered macro–meso porous, AP = aluminum phosphate) monolithic catalyst was for the first time constructed successfully with the hierarchical Co-phyllosilicate ultrathin nanosheets growth on the surface of 3D printed ordered macropore–mesoporous SiO2 support. On the one hand, we discovered that the construction of ordered macropore–mesoporous structures is beneficial to the diffusion and adsorption of reactants, intermediates, and products. On the other hand, the formation of hierarchical Co-phyllosilicate ultrathin nanosheets could provide more active Co&+ species, abundant acid sites, and active oxygen. The above factors are in favor of improving the catalytic performance of benzene oxidation, and then a 3D-OMm-Co3O4/SiO2-0.5AP catalyst exhibited the superior catalytic activity. To explore the effect of catalysts structure and morphology, various Co-based catalysts were also constructed. Simultaneously, the 3D-OMm-Co3O4/SiO2-0.5AP catalyst has excellent catalytic performance, water resistance, and thermal stability in the catalytic combustion of benzene due to the strong interactions between Co&+ species and SiO2 in the phyllosilicate. Therefore, this study proposes a new catalyst synthesis method through 3D printing, and presents considerable prospects for the removal of VOCs from industrial applications.

Keywords: three-dimensional (3D) printing, catalytic oxidation, volatile organic compounds (VOCs), Co-phyllosilicate, ordered porous

References(79)

[1]

Wen, M.; Dong, F.; Yao, J. F.; Tang, Z. C.; Zhang, J. Y. Pt nanoparticles confined in the ordered mesoporous CeO2 as a highly efficient catalyst for the elimination of VOCs. J. Catal. 2022, 412, 42–58.
DOI Google Scholar
[2]

Chen, J.; Chen, X.; Chen, X.; Xu, W. J.; Xu, Z.; Jia, H. P.; Chen, J. Homogeneous introduction of CeOy into MnOx-based catalyst for oxidation of aromatic VOCs. Appl. Catal. B: Environ. 2018, 224, 825–835.
DOI Google Scholar
[3]

Li, L.; Liu, S. Q.; Liu, J. X. Surface modification of coconut shell based activated carbon for the improvement of hydrophobic VOC removal. J. Hazard. Mater. 2011, 192, 683–690.
DOI Google Scholar
[4]

Destaillats, H.; Sleiman, M.; Sullivan, D. P.; Jacquiod, C.; Sablayrolles, J.; Molins, L. Key parameters influencing the performance of photocatalytic oxidation (PCO) air purification under realistic indoor conditions. Appl. Catal. B: Environ. 2012, 128, 159–170.
DOI Google Scholar
[5]

Parmar, G. R.; Rao, N. N. Emerging control technologies for volatile organic compounds. Crit. Rev. Environ. Sci. Technol. 2008, 39, 41–78.
DOI Google Scholar
[6]

Luo, Y. J.; Wang, K. C.; Chen, Q. H.; Xu, Y. X.; Xue, H.; Qian, Q. R. Preparation and characterization of electrospun La1−xCexCoOδ: Application to catalytic oxidation of benzene. J. Hazard. Mater. 2015, 296, 17–22.
DOI Google Scholar
[7]

Zhang, C. H.; Guo, Y. L.; Guo, Y.; Lu, G. Z.; Boreave, A.; Retailleau, L.; Baylet, A.; Giroir-Fendler, A. LaMnO3 perovskite oxides prepared by different methods for catalytic oxidation of toluene. Appl. Catal. B: Environ. 2014, 148–149, 490–498.
DOI Google Scholar
[8]

Wang, X. Y.; Liu, Y.; Zhang, T. H.; Luo, Y. J.; Lan, Z. X.; Zhang, K.; Zuo, J. C.; Jiang, L. L.; Wang, R. H. Geometrical-site-dependent catalytic activity of ordered mesoporous Co-based spinel for benzene oxidation: In situ DRIFTS study coupled with Raman and XAFS spectroscopy. ACS Catal. 2017, 7, 1626–1636.
DOI Google Scholar
[9]

Feng, X. B.; Chen, C. W.; He, C.; Chai, S. N.; Yu, Y. K.; Cheng, J. Non-thermal plasma coupled with MOF-74 derived Mn-Co-Ni-O porous composite oxide for toluene efficient degradation. J. Hazard. Mater. 2020, 383, 121143.
DOI Google Scholar
[10]

Solsona, B.; Garcia, T.; Aylón, E.; Dejoz, A. M.; Vázquez, I.; Agouram, S.; Davies, T. E.; Taylor, S. H. Promoting the activity and selectivity of high surface area Ni-Ce-O mixed oxides by gold deposition for VOC catalytic combustion. Chem. Eng. J. 2011, 175, 271–278.
DOI Google Scholar
[11]

Wang, C.; Zhang, C. H.; Hua, W. C.; Guo, Y. L.; Lu, G. Z.; Gil, S.; Giroir-Fendler, A. Catalytic oxidation of vinyl chloride emissions over Co-Ce composite oxide catalysts. Chem. Eng. J. 2017, 315, 392–402.
DOI Google Scholar
[12]

Wang, Y. F.; Zhang, C. B.; Yu, Y. B.; Yue, R. L.; He, H. Ordered mesoporous and bulk Co3O4 supported Pd catalysts for catalytic oxidation of o-xylene. Catal. Today 2015, 242, 294–299.
DOI Google Scholar
[13]

Liu, Y. X.; Dai, H. X.; Deng, J. G.; Xie, S. H.; Yang, H. G.; Tan, W.; Han, W.; Jiang, Y.; Guo, G. S. Mesoporous Co3O4-supported gold nanocatalysts: Highly active for the oxidation of carbon monoxide, benzene, toluene, and o-xylene. J. Catal. 2014, 309, 408–418.
DOI Google Scholar
[14]

Liotta, L. F.; Wu, H. J.; Pantaleo, G.; Venezia, A. M. Co3O4 nanocrystals and Co3O4-MOx binary oxides for CO, CH4 and VOC oxidation at low temperatures: A review. Catal. Sci. Technol. 2013, 3, 3085–3102.
DOI Google Scholar
[15]

Li, J. J.; Xu, X. Y.; Hao, Z. P.; Zhao, W. Mesoporous silica supported cobalt oxide catalysts for catalytic removal of benzene. J. Porous Mater. 2008, 15, 163–169.
DOI Google Scholar
[16]

Araújo, R. S.; Azevedo, D. C. S.; Rodríguez-Castellón, E.; Jiménez-López, A.; Cavalcante, C. Jr. Al and Ti-containing mesoporous molecular sieves: Synthesis, characterization and redox activity in the anthracene oxidation. J. Mol. Catal. A: Chem. 2008, 281, 154–163.
DOI Google Scholar
[17]

Todorova, S.; Pârvulescu, V.; Kadinov, G.; Tenchev, K.; Somacescu, S.; Su, B. L. Metal states in cobalt-and cobalt-vanadium-modified MCM-41 mesoporous silica catalysts and their activity in selective hydrocarbons oxidation. Micropor. Mesopor. Mater. 2008, 113, 22–30.
DOI Google Scholar
[18]

Szegedi, Á.; Popova, M.; Minchev, C. Catalytic activity of Co/MCM-41 and Co/SBA-15 materials in toluene oxidation. J. Mater. Sci. 2009, 44, 6710–6716.
DOI Google Scholar
[19]

Kim, D. J.; Dunn, B. C.; Cole, P.; Turpin, G.; Ernst, R. D.; Pugmire, R. J.; Kang, M.; Kim, J. M.; Eyring, E. M. Enhancement in the reducibility of cobalt oxides on a mesoporous silica supported cobalt catalyst. Chem. Commun. 2005, 11, 1462–1464.
DOI Google Scholar
[20]

Katsoulidis, A. P.; Petrakis, D. E.; Armatas, G. S.; Trikalitis, P. N.; Pomonis, P. J. Ordered mesoporous CoOx/MCM-41 materials exhibiting long-range self-organized nanostructured morphology. Micropor. Mesopor. Mater. 2006, 92, 71–80.
DOI Google Scholar
[21]

Dong, F.; Han, W. G.; Han, W. L.; Tang, Z. C. Assembling core–shell SiO2@NiaCobOx nanotube decorated by hierarchical NiCo-phyllisilicate ultrathin nanosheets for highly efficient catalytic combustion of VOCs. Appl. Catal. B: Environ. 2022, 315, 121524.
DOI Google Scholar
[22]

Xu, C. F.; Chen, G. X.; Zhao, Y.; Liu, P. X.; Duan, X. P.; Gu, L.; Fu, G.; Yuan, Y. Z.; Zheng, N. F. Interfacing with silica boosts the catalysis of copper. Nat. Commun. 2018, 9, 3367.
DOI Google Scholar
[23]

Kong, X.; Zhu, Y. F.; Zheng, H. Y.; Li, X. Q.; Zhu, Y. L.; Li, Y. W. Ni nanoparticles inlaid nickel phyllosilicate as a metal–acid bifunctional catalyst for low-temperature hydrogenolysis reactions. ACS Catal. 2015, 5, 5914–5920.
DOI Google Scholar
[24]

Kim, J. S.; Park, I.; Jeong, E. S.; Jin, K.; Seong, W. M.; Yoon, G.; Kim, H.; Kim, B.; Nam, K. T.; Kang, K. Amorphous cobalt phyllosilicate with layered crystalline motifs as water oxidation catalyst. Adv. Mater. 2017, 29, 1606893.
DOI Google Scholar
[25]

Wen, M.; Dong, F.; Tang, Z. C.; Zhang, J. Y. In situ confined encapsulation strategy for construction of Co3O4@SiO2 catalyst for the efficient elimination of toluene. Micropor. Mesopor. Mater. 2021, 322, 111156.
DOI Google Scholar
[26]

Mitchell, S.; Michels, N. L.; Kunze, K.; Pérez-Ramírez, J. Visualization of hierarchically structured zeolite bodies from macro to nano length scales. Nat. Chem. 2012, 4, 825–831.
DOI Google Scholar
[27]

Freiding, J.; Kraushaar-Czarnetzki, B. Novel extruded fixed-bed MTO catalysts with high olefin selectivity and high resistance against coke deactivation. Appl. Catal. A: Gen. 2011, 391, 254–260.
DOI Google Scholar
[28]

Williams, J. L. Monolith structures, materials, properties and uses. Catal. Today 2001, 69, 3–9.
DOI Google Scholar
[29]

Díaz-Marta, A. S.; Tubío, C. R.; Carbajales, C.; Fernández, C.; Escalante, L.; Sotelo, E.; Guitián, F.; Barrio, V. L.; Gil, A.; Coelho, A. Three-dimensional printing in catalysis: Combining 3D heterogeneous copper and palladium catalysts for multicatalytic multicomponent reactions. ACS Catal. 2018, 8, 392–404.
DOI Google Scholar
[30]
Crawley, M. L.; Trost, B. M. Applications of Transition Metal Catalysis in Drug Discovery and Development: An Industrial Perspective; John Wiley & Sons, Inc. : Hoboken, 2012.
DOI
[31]

Ciriminna, R.; Carà, P. D.; Sciortino, M.; Pagliaro, M. Catalysis with doped sol-gel silicates. Adv. Synth. Catal. 2011, 353, 677–687.
DOI Google Scholar
[32]

Xu, X.; Zhang, M. X.; Jiang, P.; Liu, D. S.; Wang, Y. X.; Xu, X.; Ji, Z. Y.; Jia, X.; Wang, H. Z.; Wang, X. L. Direct ink writing of Pd-decorated Al2O3 ceramic based catalytic reduction continuous flow reactor. Ceram. Int. 2022, 48, 10843–10851.
DOI Google Scholar
[33]

Muth, J. T.; Dixon, P. G.; Woish, L.; Gibson, L. J.; Lewis, J. A. Architected cellular ceramics with tailored stiffness via direct foam writing. Proc. Natl. Acad. Sci. USA 2017, 114, 1832–1837.
DOI Google Scholar
[34]

Liu, D. S.; Jiang, P.; Li, X. C.; Liu, J. X.; Zhou, L. C.; Wang, X. L.; Zhou, F. 3D printing of metal–organic frameworks decorated hierarchical porous ceramics for high-efficiency catalytic degradation. Chem. Eng. J. 2020, 397, 125392.
DOI Google Scholar
[35]

Liu, M.; Sun, J. R.; Chen, Q. F. Influences of heating temperature on mechanical properties of polydimethylsiloxane. Sens. Actuators A: Phys. 2009, 151, 42–45.
DOI Google Scholar
[36]

Quintanilla, A.; Casas, J. A.; Miranzo, P.; Osendi, M. I.; Belmonte, M. 3D-printed Fe-doped silicon carbide monolithic catalysts for wet peroxide oxidation processes. Appl. Catal. B: Environ. 2018, 235, 246–255.
DOI Google Scholar
[37]

Mu, Z.; Li, J. J.; Tian, H.; Hao, Z. P.; Qiao, S. Z. Synthesis of mesoporous Co/Ce-SBA-15 materials and their catalytic performance in the catalytic oxidation of benzene. Mater. Res. Bull. 2008, 43, 2599–2606.
DOI Google Scholar
[38]

Wang, X. Y.; Zuo, J. C.; Luo, Y. J.; Jiang, L. L. New route to CeO2/LaCoO3 with high oxygen mobility for total benzene oxidation. Appl. Surf. Sci. 2017, 396, 95–101.
DOI Google Scholar
[39]

Zuo, S. F.; Liu, F. J.; Tong, J.; Qi, C. Z. Complete oxidation of benzene with cobalt oxide and ceria using the mesoporous support SBA-16. Appl. Catal. A: Gen. 2013, 467, 1–6.
DOI Google Scholar
[40]

Han, D. W.; Xiao, M. L.; Wei, Y. C.; Yang, X. Q.; Guo, Y. C.; Ma, L. J.; Yu, X. L.; Ge, M. F. Enhanced sulfur resistance by constructing MnOx-Co3O4 interface on Ni foam in the removal of benzene. Environ. Sci.: Nano 2023, 10, 284–294.
DOI Google Scholar
[41]

Xiang, Y.; Zhu, Y.; Lu, J.; Zhu, C. Z.; Zhu, M. Y.; Xie, Q. Q.; Chen, T. H. Co3O4/α-Fe2O3 catalyzed oxidative degradation of gaseous benzene: Preparation, characterization and its catalytic properties. Solid State Sci. 2019, 93, 79–86.
DOI Google Scholar
[42]

Yao, J. F.; Dong, F.; Xu, X.; Wen, M.; Ji, Z. Y.; Feng, H.; Wang, X. L.; Tang, Z. C. Rational design and construction of monolithic ordered mesoporous Co3O4@SiO2 catalyst by a novel 3D printed technology for catalytic oxidation of toluene. ACS Appl. Mater. Interfaces 2022, 14, 22170–22185.
DOI Google Scholar
[43]

Zhang, L.; Yang, J. W.; Wang, A. Q.; Chai, S. H.; Guan, J.; Nie, L. F.; Fan, G. J.; Han, N.; Chen, Y. F. High performance ozone decomposition spinel (Mn,Co)3O4 catalyst accelerating the rate-determining step. Appl. Catal. B: Environ. 2022, 303, 120927.
DOI Google Scholar
[44]

Scott, S. L.; Gunnoe, T. B.; Fornasiero, P.; Crudden, C. M. To err is human; to reproduce takes time. ACS Catal. 2022, 12, 3644–3650.
DOI Google Scholar
[45]

Lefevere, J.; Protasova, L.; Mullens, S.; Meynen, V. 3D-printing of hierarchical porous ZSM-5: The importance of the binder system. Mater. Des. 2017, 134, 331–341.
DOI Google Scholar
[46]

Dong, F.; Han, W. G.; Guo, Y.; Han, W. L.; Tang, Z. C. CeCoOx-MNS catalyst derived from three-dimensional mesh nanosheet Co-based metal-organic frameworks for highly efficient catalytic combustion of VOCs. Chem. Eng. J. 2021, 405, 126948.
DOI Google Scholar
[47]

Wang, H.; Chen, C. L.; Zhang, Y. X.; Peng, L. X.; Ma, S.; Yang, T.; Guo, H. H.; Zhang, Z. D.; Su, D. S.; Zhang, J. In situ oxidation of carbon-encapsulated cobalt nanocapsules creates highly active cobalt oxide catalysts for hydrocarbon combustion. Nat. Commun. 2015, 6, 7181.
DOI Google Scholar
[48]

Sun, S. J.; Gao, Q. M.; Wang, H. L.; Zhu, J. K.; Guo, H. L. Influence of textural parameters on the catalytic behavior for CO oxidation over ordered mesoporous Co3O4. Appl. Catal. B: Environ. 2010, 97, 284–291.
DOI Google Scholar
[49]

Díaz-Marta, A. S.; Yáñez, S.; Tubio, C. R.; Barrio, V. L.; Piñeiro, Y.; Pedrido, R.; Rivas, J.; Amorín, M.; Guitián, F.; Coelho, A. Multicatalysis combining 3D-printed devices and magnetic nanoparticles in one-pot reactions: Steps forward in compartmentation and recyclability of catalysts. ACS Appl. Mater. Interfaces 2019, 11, 25283–25294.
DOI Google Scholar
[50]

Yang, Q. X.; Lu, R.; Ren, S. S.; Zhou, H. M.; Wu, Q. X.; Zhen, Y. Y.; Chen, Z. J.; Fang, S. M. Magnetic beads embedded in poly (sodium-p-styrenesulfonate) and ZIF-67: Removal of nitrophenol from water. J. Solid State Chem. 2018, 265, 200–207.
DOI Google Scholar
[51]

Peng, M. W.; Shi, D. L.; Sun, Y. H.; Cheng, J.; Zhao, B.; Xie, Y. M.; Zhang, J. C.; Guo, W.; Jia, Z.; Liang, Z. Q. et al. 3D printed mechanically robust graphene/CNT electrodes for highly efficient overall water splitting. Adv. Mater. 2020, 32, 1908201.
DOI Google Scholar
[52]

Ghasemzadeh, M. A.; Mirhosseini-Eshkevari, B.; Abdollahi-Basir, M. H. Rapid and efficient one-pot synthesis of 3,4-dihydroquinoxalin-2-amine derivatives catalyzed by Co3O4@SiO2 core−shell nanoparticles under ultrasound irradiation. Comb. Chem. High Throughput Screen. 2016, 19, 592–601.
DOI Google Scholar
[53]

Kucharczyk, S.; Zajac, M.; Stabler, C.; Thomsen, R. M.; Haha, M. B.; Skibsted, J.; Deja, J. Structure and reactivity of synthetic CaO-Al2O3-SiO2 glasses. Cem. Concr. Res. 2019, 120, 77–91.
DOI Google Scholar
[54]

Gu, F.; Li, C. Z.; Hu, Y. J.; Zhang, L. Synthesis and optical characterization of Co3O4 nanocrystals. J. Cryst. Growth 2007, 304, 369–373.
DOI Google Scholar
[55]

Mamontov, E.; Egami, T.; Brezny, R.; Koranne, M.; Tyagi, S. Lattice defects and oxygen storage capacity of nanocrystalline ceria and ceria-zirconia. J. Phys. Chem. B 2000, 104, 11110–11116.
DOI Google Scholar
[56]

Cheng, Q. P.; Tian, Y.; Lyu, S. S.; Zhao, N.; Ma, K.; Ding, T.; Jiang, Z.; Wang, L. H.; Zhang, J.; Zheng, L. R. et al. Confined small-sized cobalt catalysts stimulate carbon-chain growth reversely by modifying ASF law of Fischer–Tropsch synthesis. Nat. Commun. 2018, 9, 3250.
DOI Google Scholar
[57]

Ward, M. R.; Boyes, E. D.; Gai, P. L. In situ aberration-corrected environmental TEM: Reduction of model Co3O4 in H2 at the atomic level. ChemCatChem 2013, 5, 2655–2661.
DOI Google Scholar
[58]

Song, W. Q.; Poyraz, A. S.; Meng, Y. T.; Ren, Z.; Chen, S. Y.; Suib, S. L. Mesoporous Co3O4 with controlled porosity: Inverse micelle synthesis and high-performance catalytic CO oxidation at −60 °C. Chem. Mater. 2014, 26, 4629–4639.
DOI Google Scholar
[59]

Subramanian, V.; Cheng, K.; Lancelot, C.; Heyte, S.; Paul, S.; Moldovan, S.; Ersen, O.; Marinova, M.; Ordomsky, V. V.; Khodakov, A. Y. Nanoreactors: An efficient tool to control the chain-length distribution in Fischer–Tropsch synthesis. ACS Catal. 2016, 6, 1785–1792.
DOI Google Scholar
[60]

Sun, X. H.; Suarez, A. I. O.; Meijerink, M.; Van Deelen, T.; Ould-Chikh, S.; Zečević, J.; De Jong, K. P.; Kapteijn, F.; Gascon, J. Manufacture of highly loaded silica-supported cobalt Fischer–Tropsch catalysts from a metal organic framework. Nat. Commun. 2017, 8, 1680.
DOI Google Scholar
[61]

Yan, N.; Chen, Q. W.; Wang, F.; Wang, Y.; Zhong, H.; Hu, L. High catalytic activity for CO oxidation of Co3O4 nanoparticles in SiO2 nanocapsules. J. Mater. Chem. A 2013, 1, 637–643.
DOI Google Scholar
[62]

Li, B. F.; Wei, F.; Su, B.; Guo, Z.; Ding, Z. X.; Yang, M. Q.; Wang, S. B. Mesoporous cobalt tungstate nanoparticles for efficient and stable visible-light-driven photocatalytic CO2 reduction. Mater. Today Energy 2022, 24, 100943.
DOI Google Scholar
[63]

Li, Q.; Odoom-Wubah, T.; Zhou, Y. P.; Mulka, R.; Zheng, Y. M.; Huang, J. L.; Sun, D. H.; Li, Q. B. Coral-like CoMnOx as a highly active catalyst for benzene catalytic oxidation. Ind. Eng. Chem. Res. 2019, 58, 2882–2890.
DOI Google Scholar
[64]

Mo, S. P.; Zhang, Q.; Li, J. Q.; Sun, Y. H.; Ren, Q. M.; Zou, S. B.; Zhang, Q.; Lu, J. H.; Fu, M. L.; Mo, D. Q. et al. Highly efficient mesoporous MnO2 catalysts for the total toluene oxidation: Oxygen-vacancy defect engineering and involved intermediates using in situ DRIFTS. Appl. Catal. B: Environ. 2020, 264, 118464.
DOI Google Scholar
[65]

Hu, Z.; Qiu, S.; You, Y.; Guo, Y.; Guo, Y. L.; Wang, L.; Zhan, W. C.; Lu, G. Z. Hydrothermal synthesis of NiCeOx nanosheets and its application to the total oxidation of propane. Appl. Catal. B: Environ. 2018, 225, 110–120.
DOI Google Scholar
[66]

Ma, Y.; Wang, L.; Ma, J. Z.; Wang, H. H.; Zhang, C. B.; Deng, H.; He, H. Investigation into the enhanced catalytic oxidation of o-xylene over MOF-derived Co3O4 with different shapes: The role of surface twofold-coordinate lattice oxygen (O2f). ACS Catal. 2021, 11, 6614–6625.
DOI Google Scholar
[67]

Soghrati, E.; Ong, T. K. C.; Poh, C. K.; Kawi, S.; Borgna, A. Zeolite-supported nickel phyllosilicate catalyst for C-O hydrogenolysis of cyclic ethers and polyols. Appl. Catal. B: Environ. 2018, 235, 130–142.
DOI Google Scholar
[68]

Fang, J. X.; Huang, Z. W.; Wang, L. P.; Guo, S. F.; Li, M. X.; Liu, Y. C.; Chen, J. M.; Wu, X. M.; Shen, H. Z.; Zhao, H. W. et al. Activation of oxygen on the surface of the Co3O4 catalyst by single-atom Ag toward efficient catalytic benzene combustion. J. Phys. Chem. C 2022, 126, 5873–5884.
DOI Google Scholar
[69]

Zhao, X. T.; Xu, D. J.; Wang, Y. N.; Zheng, Z. W.; Li, K.; Zhang, Y. R.; Zhan, R.; Lin, H. Electric field assisted benzene oxidation over Pt-Ce-Zr nano-catalysts at low temperature. J. Hazard. Mater. 2021, 407, 124349.
DOI Google Scholar
[70]

Yang, K.; Liu, Y. X.; Deng, J. G.; Zhao, X. T.; Yang, J.; Han, Z.; Hou, Z. Q.; Dai, H. X. Three-dimensionally ordered mesoporous iron oxide-supported single-atom platinum: Highly active catalysts for benzene combustion. Appl. Catal. B: Environ. 2019, 244, 650–659.
DOI Google Scholar
[71]

Hou, J. C.; Hu, J. L.; Chang, L. P.; Wang, J. C.; Zeng, Z. Q.; Wu, D. X.; Cui, X. M.; Bao, W. R.; Yao, J. X. Synergistic effects between highly dispersed CuOx and the surface Cu-[Ox]-Ce structure on the catalysis of benzene combustion. J. Catal. 2022, 408, 9–23.
DOI Google Scholar
[72]

Lichtenberger, J.; Amiridis, M. D. Catalytic oxidation of chlorinated benzenes over V2O5/TiO2 catalysts. J. Catal. 2004, 223, 296–308.
DOI Google Scholar
[73]

Li, L.; Yang, Q. L.; Wang, D.; Peng, Y.; Yan, J. L.; Li, J. H.; Crittenden, J. Facile synthesis λ-MnO2 spinel for highly effective catalytic oxidation of benzene. Chem. Eng. J. 2021, 421, 127828.
DOI Google Scholar
[74]

Li, J. J.; Yu, E. Q.; Cai, S. C.; Chen, X.; Chen, J.; Jia, H. P.; Xu, Y. J. Noble metal free, CeO2/LaMnO3 hybrid achieving efficient photo-thermal catalytic decomposition of volatile organic compounds under IR light. Appl. Catal. B: Environ. 2019, 240, 141–152.
DOI Google Scholar
[75]

Xue, L.; Zhang, C. B.; He, H.; Teraoka, Y. Catalytic decomposition of N2O over CeO2 promoted Co3O4 spinel catalyst. Appl. Catal. B: Environ. 2007, 75, 167–174.
DOI Google Scholar
[76]

Liu, X. L.; Zeng, J. L.; Shi, W. B.; Wang, J.; Zhu, T. Y.; Chen, Y. F. Catalytic oxidation of benzene over ruthenium-cobalt bimetallic catalysts and study of its mechanism. Catal. Sci. Technol. 2017, 7, 213–221.
DOI Google Scholar
[77]

Kang, S. Y.; Wang, M.; Zhu, N.; Wang, C. Y.; Deng, H.; He, H. Significant enhancement in water resistance of Pd/Al2O3 catalyst for benzene oxidation by Na addition. Chin. Chem. Lett. 2019, 30, 1450–1454.
DOI Google Scholar
[78]

Odoom-Wubah, T.; Li, Q.; Adilov, I.; Huang, J. L.; Li, Q. B. Towards efficient Pd/Mn3O4 catalyst with enhanced acidic sites and low temperature reducibility for benzene abatement. Mol. Catal. 2019, 477, 110558.
DOI Google Scholar
[79]

Zhong, J. P.; Zeng, Y. K.; Zhang, M. Y.; Feng, W. H.; Xiao, D. R.; Wu, J. L.; Chen, P. R.; Fu, M. L.; Ye, D. Q. Toluene oxidation process and proper mechanism over Co3O4 nanotubes: Investigation through in-situ DRIFTS combined with PTR-TOF-MS and quasi in-situ XPS. Chem. Eng. J. 2020, 397, 125375.
DOI Google Scholar
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Publication history
Copyright
Acknowledgements

Publication history

Received: 17 January 2023
Revised: 23 February 2023
Accepted: 28 February 2023
Published: 18 May 2023
Issue date: October 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work is supported by the LICP Cooperation Foundation for Young Scholars (No. HZJJ21-02), the National Natural Science Foundation of China (Nos. 52070182 and 51908535), the DNL Cooperation Found, Chinese Academy of Sciences (No. DNL202004), Province Natural Science Foundation of GanSu (Nos. 20JR10RA053 and 20JR10RA046), and Major Program of the Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences (No. ZYFZFX-10).

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