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Review Article

Recent progress of two-dimensional metal-organic-frameworks: From synthesis to electrocatalytic oxygen evolution

Huakai Xu, Xiaofei Wei, Hui Zeng, Chuanhai Jiang, Zhifei Wang, Yuguo Ouyang, Chunyu Lu, Yuan Jing, Shiwei Yao, Fangna Dai( )
School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China
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Graphical Abstract

This review summarizes the evaluation parameters of oxygen evolution reaction (OER) catalyst performance and the synthesis strategy of two-dimensional (2D) metal-organic framework (MOF), and then, the recent progress of 2D MOFs and their derivatives as OER catalysis, including hydroxide, metal/alloy/oxide, metal sulfide/selenide, and metal phosphide, was reviewed. Finally, the challenges and prospects of 2D MOF nanosheets and their derivatives in OER electrocatalysis are discussed with a view to advancing the field.

Abstract

High-performance electrocatalysts for oxygen evolution reaction (OER) are crucial for water splitting and metal-air batteries. Two-dimensional (2D) metal-organic framework (MOF) has become a new class of efficient OER electrocatalysts due to the rich coordination unsaturated metal nodes, large specific surface area, and adjustable structures. In addition, because inheriting the original microstructure of MOFs and having stronger chemical and mechanical stability, metal/alloy/oxide, metal sulfide/selenide/phosphide, and other compounds derived from 2D MOFs have also shown their unique OER catalytic ability. Here, we briefly introduced the existing reaction mechanism and evaluation parameters of catalyst performance of OER, introduced the synthesis methods and corresponding characterization techniques of 2D MOFs and their derivatives, and summarized the latest progress of 2D MOFs and their derivatives as OER catalysts. Finally, we put forward some views and suggestions on the existing problems hindering the development of 2D MOFs as OER for advancing the field.

Keywords

two-dimensional metal-organic frameworkderivativessynthesiscatalysisoxygen evolution reaction

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Nano Research
Volume 16 Issue 7,
July 2023
Pages 8614-8637
DOI: 10.1007/s12274-023-5576-3
Cite this article:
Xu H, Wei X, Zeng H, et al. Recent progress of two-dimensional metal-organic-frameworks: From synthesis to electrocatalytic oxygen evolution. Nano Research, 2023, 16(7): 8614-8637. https://doi.org/10.1007/s12274-023-5576-3
Topics:
Electrocatalysts

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Received: 29 December 2022
Revised: 09 February 2023
Accepted: 13 February 2023
Published: 02 April 2023
© Tsinghua University Press 2023
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