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Nano Research 2023, 16(5): 6369-6379 https://doi.org/10.1007/s12274-023-5483-7
Research Article | Issue | Published: 19 February 2023

Multi-componential metal intercalated graphite hybrids synthesized by co-intercalation polymerization towards high-efficient microwave absorptions

Show Author's Information Junhua Su1,  Qinbo Ma1,  Longkun Que1,  Hunan Jiang1,  Xiaoling Xu1,2,  Yong Wang1,2,  Yifan Guo1,2,3,4( ),  Zuowan Zhou1,2,3,5
Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
School of Chemistry, Southwest Jiaotong University, Chengdu 610031, China
Yibin Research Institute, Southwest Jiaotong University, Yibin 644000, China
School of Mechanical Engineering, Southwest Jiaotong University, Chengdu 610031, China
Research Institute of Frontier Science, Southwest Jiaotong University, Chengdu 610031, China
Keywords:
microwave absorption, transition metal, expanded graphite, co-intercalation, intercalation polymerization
Topics:
GraphiteMagnetic materials NanocompositesNanostructures
Cite this article:
Su J, Ma Q, Que L, et al. Multi-componential metal intercalated graphite hybrids synthesized by co-intercalation polymerization towards high-efficient microwave absorptions. Nano Research, 2023, 16(5): 6369-6379. https://doi.org/10.1007/s12274-023-5483-7
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Abstract Full text Electronic supplementary material About this article

Magnetic expanded graphite (EG) hybrids were synthesized by co-intercalation polymerization of aniline together with transition metal ions. Experimental results show that metal ions (Fe, Co, Ni, and Cu) and even their mixtures can co-intercalate into graphite interlayers with flexibly controllable ratios and contents. Among these co-intercalation compounds, Fe/Ni-intercalated graphite with a predesigned mole ratio of 1:3 transforms into NiFe2O4/FeNi3@EG during the annealing process. The synthesized magnetic EG hybrids present multiband microwave absorption in C and X bands due to improved impedance match as well as significantly enhanced interfacial polarization relaxation induced by multi-componential metals. The reflection values of −39.1 dB at 6.95 GHz and −25.7 dB at 9.4 GHz are achieved with an ultra-low loading of 5 wt.%. This work provides a flexible approach for tuning the components and structures of magnetic EG hybrids, which may contribute to the development of microwave absorption materials with superior performances.


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Electronic supplementary material
About this article

Multi-componential metal intercalated graphite hybrids synthesized by co-intercalation polymerization towards high-efficient microwave absorptions

Show Author's information Junhua Su1, Qinbo Ma1, Longkun Que1, Hunan Jiang1, Xiaoling Xu1,2, Yong Wang1,2, Yifan Guo1,2,3,4( ), Zuowan Zhou1,2,3,5
Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
School of Chemistry, Southwest Jiaotong University, Chengdu 610031, China
Yibin Research Institute, Southwest Jiaotong University, Yibin 644000, China
School of Mechanical Engineering, Southwest Jiaotong University, Chengdu 610031, China
Research Institute of Frontier Science, Southwest Jiaotong University, Chengdu 610031, China

Abstract

Magnetic expanded graphite (EG) hybrids were synthesized by co-intercalation polymerization of aniline together with transition metal ions. Experimental results show that metal ions (Fe, Co, Ni, and Cu) and even their mixtures can co-intercalate into graphite interlayers with flexibly controllable ratios and contents. Among these co-intercalation compounds, Fe/Ni-intercalated graphite with a predesigned mole ratio of 1:3 transforms into NiFe2O4/FeNi3@EG during the annealing process. The synthesized magnetic EG hybrids present multiband microwave absorption in C and X bands due to improved impedance match as well as significantly enhanced interfacial polarization relaxation induced by multi-componential metals. The reflection values of −39.1 dB at 6.95 GHz and −25.7 dB at 9.4 GHz are achieved with an ultra-low loading of 5 wt.%. This work provides a flexible approach for tuning the components and structures of magnetic EG hybrids, which may contribute to the development of microwave absorption materials with superior performances.

Keywords: microwave absorption, transition metal, expanded graphite, co-intercalation, intercalation polymerization

References(77)

[1]

Zhao, X. X.; Yan, J.; Huang, Y.; Liu, X. D.; Ding, L.; Zong, M.; Liu, P. B.; Li, T. H. Magnetic porous CoNi@C derived from bamboo fiber combined with metal–organic framework for enhanced electromagnetic wave absorption. J. Colloid Interface Sci. 2021, 595, 78–87.
DOI Google Scholar
[2]

Xing, J. Y. Electromagnetic radiation on human health hazards and protective measures in modern society. Adv. Mater. Res. 2012, 518–523, 1022–1026.
DOI Google Scholar
[3]

Zhou, C. L.; Wang, X. X.; Luo, H.; Deng, L. W.; Wei, S.; Zheng, Y. W.; Jia, Q.; Liu, J. Q. Rapid and direct growth of bipyramid TiO2 from Ti3C2Tx MXene to prepare Ni/TiO2/C heterogeneous composites for high-performance microwave absorption. Chem. Eng. J. 2020, 383, 123095.
DOI Google Scholar
[4]

Song, S. W.; Zhang, A. T.; Chen, L.; Jia, Q.; Zhou, C. L.; Liu, J. Q.; Wang, X. X. A novel multi-cavity structured MOF derivative/porous graphene hybrid for high performance microwave absorption. Carbon 2021, 176, 279–289.
DOI Google Scholar
[5]

Chen, C. Y.; Pu, N. W.; Liu, Y. M.; Huang, S. Y.; Wu, C. H.; Ger, M. D.; Gong, Y. J.; Chou, Y. C. Remarkable microwave absorption performance of graphene at a very low loading ratio. Compos. Part B: Eng. 2017, 114, 395–403.
DOI Google Scholar
[6]

Chen, X.; Jia, X. B.; Wu, Z.; Tang, Z. X.; Zeng, Y. X.; Wang, X. J.; Fu, X. Q.; Zou, Y. H. A graphite-based metamaterial microwave absorber. IEEE Antennas Wireless Propag. Lett. 2019, 18, 1016–1020.
DOI Google Scholar
[7]

Zhu, S. Q.; Lei, Z. K.; Liu, Z. H.; Wu, F. Y.; Song, J. L.; Yang, Z.; Tan, G. G.; Man, Q. K.; Liu, X. C. Synthesis and microwave absorption properties of sandwich microstructure Ce2Fe17N3−δ/expanded graphite composites. J. Alloys Compd. 2022, 907, 164445.
DOI Google Scholar
[8]

Sun, J.; Li, L. J.; Yu, R.; Ma, X. L.; Jin, S. H.; Chen, K.; Chen, S. S.; Lv, X. J.; Shu, Q. H. Synthesis and microwave absorption properties of sulfur-free expanded graphite/Fe3O4 composites. Molecules 2020, 25, 3044.
DOI Google Scholar
[9]

Zhang, X.; Liu, Z. C.; Deng, B. W.; Cai, L.; Dong, Y. Y.; Zhu, X. J.; Lu, W. Honeycomb-like NiCo2O4@MnO2 nanosheets array/3D porous expanded graphite hybrids for high-performance microwave absorber with hydrophobic and flame-retardant functions. Chem. Eng. J. 2021, 419, 129547.
DOI Google Scholar
[10]

Yao, Y. Y.; Jin, S. H.; Sun, J.; Li, L. J.; Zou, H. M.; Wen, P.; Lv, G.; Lv, X. J.; Shu, Q. H. Sandwich-like sulfur-free expanded graphite/CoNi hybrids and their synergistic enhancement of microwave absorption. J. Alloys Compd. 2021, 862, 158005.
DOI Google Scholar
[11]

Liu, Z. C.; Pan, F.; Deng, B. W.; Xiang, Z.; Lu, W. Self-assembled MoS2/3D worm-like expanded graphite hybrids for high-efficiency microwave absorption. Carbon 2021, 174, 59–69.
DOI Google Scholar
[12]

Liu, L.; He, Z. D.; Zhao, Y. T.; Sun, J. C.; Tong, G. X. Modulation of the composition and surface morphology of expanded graphite/Fe/Fe3O4 composites for plasmon resonance-enhanced microwave absorption. J. Alloys Compd. 2018, 765, 1218–1227.
DOI Google Scholar
[13]

Quan, L.; Zhang, H. Y.; Wei, H. J.; Li, Y. Q.; Park, S. O.; Hwang, D. Y.; Tian, Y.; Huang, M.; Wang, C. H.; Wang, M. H. et al. The electromagnetic absorption of a Na-ethylenediamine graphite intercalation compound. ACS Appl. Mater. Interfaces 2020, 12, 16841–16848.
DOI Google Scholar
[14]

Spanu, L.; Sorella, S.; Galli, G. Nature and strength of interlayer binding in graphite. Phys. Rev. Lett. 2009, 103, 196401.
DOI Google Scholar
[15]

Li, Y. Q.; Lu, Y. X.; Adelhelm, P.; Titirici, M. M.; Hu, Y. S. Intercalation chemistry of graphite: Alkali metal ions and beyond. Chem. Soc. Rev. 2019, 48, 4655–4687.
DOI Google Scholar
[16]

Li, Z.; Zhang, C. Z.; Han, F.; Zhang, F. Q.; Zhou, D. W.; Xu, S. H.; Liu, H. B.; Li, X. K.; Liu, J. S. Improving the cycle stability of FeCl3-graphite intercalation compounds by polar Fe2O3 trapping in lithium-ion batteries. Nano Res. 2019, 12, 1836–1844.
DOI Google Scholar
[17]

Fu, W. J.; Kiggans, J.; Overbury, S. H.; Schwartz, V.; Liang, C. D. Low-temperature exfoliation of multilayer-graphene material from FeCl3 and CH3NO2 co-intercalated graphite compound. Chem. Commun. 2011, 47, 5265–5267.
DOI Google Scholar
[18]

Yang, L.; Liu, H. B.; Chen, Y. X.; He, H.; Chen, H. Formation process of FeCl3-NiCl2-graphite intercalation compounds. J. Mater. Eng. Perform. 2012, 21, 339–344.
DOI Google Scholar
[19]

Peng, F. X.; Meng, F. B.; Guo, Y. F.; Wang, H. G.; Huang, F.; Zhou, Z. W. Intercalating hybrids of sandwich-like Fe3O4-graphite: Synthesis and their synergistic enhancement of microwave absorption. ACS Sustainable Chem. Eng. 2018, 6, 16744–16753.
DOI Google Scholar
[20]

Guo, Y. F.; Li, J. Y.; Meng, F. B.; Wei, W.; Yang, Q.; Li, Y.; Wang, H. G.; Peng, F. X.; Zhou, Z. W. Hybridization-induced polarization of graphene sheets by intercalation-polymerized polyaniline toward high performance of microwave absorption. ACS Appl. Mater. Interfaces 2019, 11, 17100–17107.
DOI Google Scholar
[21]

Chen, X. N.; Chen, J. J.; Meng, F. B.; Shan, L. M.; Jiang, M.; Xu, X. L.; Lu, J.; Wang, Y.; Zhou, Z. W. Hierarchical composites of polypyrrole/graphene oxide synthesized by in situ intercalation polymerization for high efficiency and broadband responses of electromagnetic absorption. Compos. Sci. Technol. 2016, 127, 71–78.
DOI Google Scholar
[22]

Lalita, S.; Sankar, N. S.; Aparna, R.; Suvigya, K.; Gopinadhan, K. Selective transport of water molecules through interlayer spaces in graphite. Nat. Commun. 2022, 13, 498.
DOI Google Scholar
[23]

Liu, T.; Pang, Y.; Xie, X. B.; Qi, W.; Wu, Y.; Kobayashi, S.; Zheng, J.; Li, X. G. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties. J. Alloys Compd. 2016, 667, 287–296.
DOI Google Scholar
[24]

Yan, X. D.; Tian, L. H.; Li, K. X.; Atkins, S.; Zhao, H. F.; Murowchick, J.; Liu, L.; Chen, X. B. FeNi3/NiFeOx nanohybrids as highly efficient bifunctional electrocatalysts for overall water splitting. Adv. Mater. Interfaces 2016, 3, 1600368.
DOI Google Scholar
[25]

Contreras-Celedón, C. A.; Chacón-García, L.; Lira-Corral, N. J. An efficient synthesis of phenols via oxidative hydroxylation of arylboronic acids using (NH4)2S2O8. J. Chem. 2014, 2014, 569572.
DOI Google Scholar
[26]

Qiu, Y. F.; Lu, B.; Yan, Y. Y.; Zhou, J.; Wang, J. Simple and convenient two step synthesis of 5-bromo-2,3-dimethoxy-6-methyl-1,4-benzoquinone. Green Process. Synth. 2019, 8, 825–827.
DOI Google Scholar
[27]

Tang, J. S.; Jing, X. B.; Wang, B. C.; Wang, F. S. Infrared spectra of soluble polyaniline. Synth. Metals 1988, 24, 231–238.
DOI Google Scholar
[28]

Malard, L. M.; Pimenta, M. A.; Dresselhaus, G.; Dresselhaus, M. S. Raman spectroscopy in graphene. Phys. Rep. 2009, 473, 51–87.
DOI Google Scholar
[29]

Bourdo, S.; Li, Z. R.; Biris, A. S.; Watanabe, F.; Viswanathan, T.; Pavel, I. Structural, electrical, and thermal behavior of graphite-polyaniline composites with increased crystallinity. Adv. Funct. Mater. 2008, 18, 432–440.
DOI Google Scholar
[30]

Chen, X. N.; Meng, F. C.; Zhou, Z. W.; Tian, X.; Shan, L. M.; Zhu, S. B.; Xu, X. L.; Jiang, M.; Wang, L.; Hui, D. et al. One-step synthesis of graphene/polyaniline hybrids by in situ intercalation polymerization and their electromagnetic properties. Nanoscale 2014, 6, 8140–8148.
DOI Google Scholar
[31]

Yue, J.; Epstein, A. J. XPS study of self-doped conducting polyaniline and parent systems. Macromolecules 1991, 24, 4441–4445.
DOI Google Scholar
[32]

Ryu, K. S.; Kim, K. M.; Kang, S. G.; Lee, G. J.; Joo, J.; Chang, S. H. Electrochemical and physical characterization of lithium ionic salt doped polyaniline as a polymer electrode of lithium secondary battery. Synth. Metals 2000, 110, 213–217.
DOI Google Scholar
[33]

Song, H. H.; Zhang, J.; Song, P. F.; Xiong, Y. B. Maize-like ionic liquid@polyaniline nanocomposites for high performance supercapacitor. e-Polymers 2019, 19, 313–322.
DOI Google Scholar
[34]

Salvatierra, R. V.; Zitzer, G.; Savu, S. A.; Alves, A. P.; Zarbin, A. J. G.; Chassé, T.; Casu, M. B.; Rocco, M. L. M. Carbon nanotube/polyaniline nanocomposites: Electronic structure, doping level, and morphology investigations. Synth. Metals 2015, 203, 16–21.
DOI Google Scholar
[35]

Popova, A. N. Crystallographic analysis of graphite by X-ray diffraction. Coke Chem. 2017, 60, 361–365.
DOI Google Scholar
[36]

Pistorius, C. W. F. T. A new quenchable high-temperature polymorph of FeSO4. Naturwissenschaften 1961, 48, 129.
DOI Google Scholar
[37]

Poljak, R. J. On the structure of anhydrous nickel sulfate. Acta Cryst. 1958, 11, 306.
DOI Google Scholar
[38]

Zhou, J.; Ma, J. F.; Sun, C.; Xie, L. J.; Zhao, Z. Q.; Tian, H.; Wang, Y. G.; Tao, J. T.; Zhu, X. Y. Low-temperature synthesis of NiFe2O4 by a hydrothermal method. J. Am. Ceram. Soc. 2005, 88, 3535–3537.
DOI Google Scholar
[39]

Xie, J. L.; Jiang, H. A.; Li, J. Y.; Huang, F.; Zaman, A.; Chen, X. X.; Gao, D.; Guo, Y. F.; Hui, D.; Zhou, Z. W. Improved impedance matching by multi-componential metal-hybridized rGO toward high performance of microwave absorption. Nanotechnol. Rev. 2021, 10, 1–9.
DOI Google Scholar
[40]

Ponpandian, N.; Balaya, P.; Narayanasamy, A. Electrical conductivity and dielectric behaviour of nanocrystalline NiFe2O4 spinel. J. Phys.: Condens. Matter 2002, 14, 3221–3237.
DOI Google Scholar
[41]

Niaura, G.; Malinauskas, A. Surface-enhanced Raman spectroscopy of ClO4− and SO42− anions adsorbed at a Cu electrode. J. Chem. Soc., Faraday Trans. 1998, 94, 2205–2211.
DOI Google Scholar
[42]

Ahlawat, A.; Sathe, V. G. Raman study of NiFe2O4 nanoparticles, bulk, and films: Effect of laser power. J. Raman Spectrosc. 2011, 42, 1087–1094.
DOI Google Scholar
[43]

Li, J. H.; Li, J.; Li, M. Preparation of expandable graphite with ultrasound irradiation. Mater. Lett. 2007, 61, 5070–5073.
DOI Google Scholar
[44]

Li, W.; Han, C.; Liu, W.; Zhang, M. H.; Tao, K. Y. Expanded graphite applied in the catalytic process as a catalyst support. Catal. Today 2007, 125, 278–281.
DOI Google Scholar
[45]

Yadav, R. S.; Kuřitka, I.; Vilcakova, J.; Havlica, J.; Masilko, J.; Kalina, L.; Tkacz, J.; Enev, V.; Hajdúchová, M. Structural, magnetic, dielectric, and electrical properties of NiFe2O4 spinel ferrite nanoparticles prepared by honey-mediated sol-gel combustion. J. Phys. Chem. Solids 2017, 107, 150–161.
DOI Google Scholar
[46]

Chen, D.; Zhu, J. W.; Mu, X. Q.; Cheng, R. L.; Li, W. Q.; Liu, S. L.; Pu, Z. H.; Lin, C.; Mu, S. C. Nitrogen-doped carbon coupled FeNi3 intermetallic compound as advanced bifunctional electrocatalyst for OER, ORR, and Zn-air batteries. Appl. Catal. B: Environ. 2020, 268, 118729.
DOI Google Scholar
[47]

Gu, Y.; Chen, S.; Ren, J.; Jia, Y. A.; Chen, C. M.; Komarneni, S.; Yang, D. J.; Yao, X. D. Electronic structure tuning in Ni3FeN/r-GO aerogel toward bifunctional electrocatalyst for overall water splitting. ACS Nano 2018, 12, 245–253.
DOI Google Scholar
[48]

Ali-Löytty, H.; Louie, M. W.; Singh, M. R.; Li, L.; Casalongue, H. G. S.; Ogasawara, H.; Crumlin, E. J.; Liu, Z.; Bell, A. T.; Nilsson, A. et al. Ambient-pressure XPS study of a Ni-Fe electrocatalyst for the oxygen evolution reaction. J. Phys. Chem. C 2016, 120, 2247–2253.
DOI Google Scholar
[49]

Bahgat, M.; Paek, M. K.; Pak, J. J. Reduction kinetics and mechanisms of NiFe2O4 with synthesis of nanocrystalline Fe-Ni alloy. Mater. Trans. 2007, 48, 3132–3139.
DOI Google Scholar
[50]

Liu, Z.; Tang, B.; Gu, X. C.; Liu, H.; Feng, L. G. Selective structure transformation for NiFe/NiFe2O4 embedded porous nitrogen-doped carbon nanosphere with improved oxygen evolution reaction activity. Chem. Eng. J. 2020, 395, 125170.
DOI Google Scholar
[51]

Sun, L.; Zhang, R.; Wang, Z. D.; Ju, L.; Cao, E. S.; Zhang, Y. J. Structural, dielectric, and magnetic properties of NiFe2O4 prepared via sol-gel auto-combustion method. J. Magn. Magn. Mater. 2017, 421, 65–70.
DOI Google Scholar
[52]

Lu, X. G.; Liang, G. Y.; Zhang, Y. M. Synthesis and characterization of magnetic FeNi3 particles obtained by hydrazine reduction in aqueous solution. Mater. Sci. Eng. :B 2007, 139, 124–127.
DOI Google Scholar
[53]

Abellán, G.; Prima-García, H.; Coronado, E. Graphene enhances the magnetoresistance of FeNi3 nanoparticles in hierarchical FeNi3-graphene nanocomposites. J. Mater. Chem. C 2016, 4, 2252–2258.
DOI Google Scholar
[54]

Lu, X. G.; Liang, G.; Zhang, Y.; Zhang, W. Synthesis of FeNi3/(Ni0.5Zn0.5)Fe2O4 nanocomposite and its high frequency complex permeability. Nanotechnology 2007, 18, 015701.
DOI Google Scholar
[55]

Wu, Z. C.; Pei, K.; Xing, L. S.; Yu, X. F.; You, W. B.; Che, R. C. Enhanced microwave absorption performance from magnetic coupling of magnetic nanoparticles suspended within hierarchically tubular composite. Adv. Funct. Mater. 2019, 29, 1901448.
DOI Google Scholar
[56]

Yang, X. F.; Fan, B. X.; Tang, X.; Wang, J. L.; Tong, G. X.; Chen, D. B.; Guan, J. G. Interface modulation of chiral PPy/Fe3O4 planar microhelixes to achieve electric/magnetic-coupling and wide-band microwave absorption. Chem. Eng. J. 2022, 430, 132747.
DOI Google Scholar
[57]

Sun, Y. P.; Liu, X. G.; Feng, C.; Fan, J. C.; Lv, Y. H.; Wang, Y. R.; Li, C. T. A facile synthesis of FeNi3@C nanowires for electromagnetic wave absorber. J. Alloys Compd. 2014, 586, 688–692.
DOI Google Scholar
[58]

Wu, C.; Wang, H.; Luo, D. H.; Zhou, C. H.; Yan, M. Core–heteroshell FeNi3/NiFe2O4/NiSex via facile one-step selenylation for enhanced electromagnetic performance. J. Alloys Compd. 2021, 856, 157819.
DOI Google Scholar
[59]

Golchinvafa, S.; Masoudpanah, S. M. Magnetic and microwave absorption properties of FeNi3/NiFe2O4 composites synthesized by solution combustion method. J. Alloys Compd. 2019, 787, 390–396.
DOI Google Scholar
[60]

Peng, F. X.; Dai, M. F.; Wang, Z. Y.; Guo, Y. F.; Zhou, Z. W. Progress in graphene-based magnetic hybrids towards highly efficiency for microwave absorption. J. Mater. Sci. Technol. 2022, 106, 147–161.
DOI Google Scholar
[61]

Li, Y.; Xu, Z. K.; Jia, A. L.; Yang, X. L.; Feng, W.; Wang, P.; Li, K.; Lei, W. W.; He, H. Y.; Tian, Y. R. et al. Controllable modification of helical carbon nanotubes for high-performance microwave absorption. Nanotechnol. Rev. 2021, 10, 671–679.
DOI Google Scholar
[62]

Kumar, R.; Choudhary, H. K.; Pawar, S. P.; Bose, S.; Sahoo, B. Carbon encapsulated nanoscale iron/iron-carbide/graphite particles for EMI shielding and microwave absorption. Phys. Chem. Chem. Phys. 2017, 19, 23268–23279.
DOI Google Scholar
[63]

Shen, Y. Q.; Wei, Y. P.; Ma, J. Q.; Li, Q. L.; Li, J.; Shao, W. J.; Yan, P. Z.; Huang, G. W.; Du, X. Y. Tunable microwave absorption properties of nickel-carbon nanofibers prepared by electrospinning. Ceram. Int. 2019, 45, 3313–3324.
DOI Google Scholar
[64]

Wang, B. L.; Fu, Y. G.; Li, J.; Liu, T. Yolk–shelled Co@SiO2@mesoporous carbon microspheres: Construction of multiple heterogeneous interfaces for wide-bandwidth microwave absorption. J. Colloid Interface Sci. 2022, 607, 1540–1550.
DOI Google Scholar
[65]

Lv, J.; Cheng, Y.; Liu, W.; Quan, B.; Liang, X. H.; Ji, G. B.; Du, Y. W. Achieving better impedance matching by a sulfurization method through converting Ni into NiS/Ni3S4 composites. J. Mater. Chem. C 2018, 6, 1822–1828.
DOI Google Scholar
[66]

Ma, T.; Yuan, M. W.; Islam, S. M.; Li, H. F.; Ma, S. L.; Sun, G. B.; Yang, X. J. FeNi3 alloy nanocrystals grown on graphene: Controllable synthesis, in-depth characterization, and enhanced electromagnetic performance. J. Alloys Compd. 2016, 678, 468–477.
DOI Google Scholar
[67]

Rahmati, M.; Masoudpanah, S. M.; Alamolhoda, S.; Barqi, J. High-performance hybrid capacitors based on the FeNi3/NiFe2O4 composite powders synthesized by combustion method. J. Mater. Res. Technol. 2022, 16, 1578–1587.
DOI Google Scholar
[68]

Guo, J.; Li, X.; Chen, Z. R.; Zhu, J. F.; Mai, X. M.; Wei, R. B.; Sun, K.; Liu, H.; Chen, Y. X.; Naik, N. et al. Magnetic NiFe2O4/polypyrrole nanocomposites with enhanced electromagnetic wave absorption. J. Mater. Sci. Technol. 2022, 108, 64–72.
DOI Google Scholar
[69]

Shi, X. F.; You, W. B.; Zhao, Y. H.; Li, X.; Shao, Z. Z.; Che, R. C. Multi-scale magnetic coupling of Fe@SiO2@C–Ni yolk@triple-shell microspheres for broadband microwave absorption. Nanoscale 2019, 11, 17270–17276.
DOI Google Scholar
[70]

Dai, B. S.; Li, J. Y.; Wang, W. Z.; Liu, X. G.; Qi, Y. J.; Qi, Y. Carbon fibers with eddy current loss characteristics exhibit different microwave absorption properties in different graphitization states. Mater. Lett. 2020, 281, 128667.
DOI Google Scholar
[71]

Li, Q.; Zhang, Z.; Xun, X. C.; Gao, F. F.; Zhao, X.; Kang, Z.; Ding, Y.; Liao, Q. L.; Zhang, Y. Synergistic engineering of dielectric and magnetic losses in M-Co/RGO nanocomposites for use in high-performance microwave absorption. Mater. Chem. Front. 2020, 4, 3013–3021.
DOI Google Scholar
[72]

Segall, M. D.; Lindan, P. J. D.; Probert, M. J.; Pickard, C. J.; Hasnip, P. J.; Clark, S. J.; Payne, M. C. First-principles simulation: Ideas, illustrations, and the CASTEP code. J. Phys.: Condens. Matter 2002, 14, 2717–2744.
DOI Google Scholar
[73]

Payne, M. C.; Teter, M. P.; Allan, D. C.; Arias, T. A.; Joannopoulos, J. D. Iterative minimization techniques for ab initio total-energy calculations: Molecular dynamics and conjugate gradients. Rev. Mod. Phys. 1992, 64, 1045–1097.
DOI Google Scholar
[74]

Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868.
DOI Google Scholar
[75]
Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A. et al. Gaussian 09, Revision D. 01; Gaussian, Inc.: Wallingford, CT, USA, 2013
[76]

Lu, T.; Chen, F. W. Multiwfn: A multifunctional wavefunction analyzer. J. Comput. Chem. 2012, 33, 580–592.
DOI Google Scholar
[77]

Scott, A. P.; Radom, L. Harmonic vibrational frequencies: An evaluation of Hartree–Fock, Møller–Plesset, quadratic configuration interaction, density functional theory, and semiempirical scale factors. J. Phys. Chem. 1996, 100, 16502–16513.
DOI Google Scholar
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Publication history
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Acknowledgements

Publication history

Received: 18 August 2022
Revised: 07 December 2022
Accepted: 09 January 2023
Published: 19 February 2023
Issue date: May 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (No. 51573149) and the Key R&D Projects in Sichuan Province (Nos. 2020ZDZX0005 and 2020ZDZX0008). We would like to thank Analysis and Testing Center of Southwest Jiaotong University for providing Raman test platform and other test consultation.

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