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Nano Research 2023, 16(7): 9240-9249 https://doi.org/10.1007/s12274-023-5478-4
Research Article | Issue | Published: 19 February 2023

Manipulating dielectric property of polymer coatings toward high-retention-rate lithium metal full batteries under harsh critical conditions

Show Author's Information Qi Kang1,  Zechao Zhuang2,  Yong Li3,  Yinze Zuo4,  Jian Wang5,  Yijie Liu1,  Chaoqun Shi6,  Jie Chen1,  Hongfei Li1,  Pingkai Jiang1,  Xingyi Huang1( )
Department of Polymer Science and Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Department of Chemistry, Tsinghua University, Beijing 100084, China
Institute of Applied and Physical Chemistry and Center for Environmental Research and Sustainable Technology, University of Bremen, Bremen 28359, Germany
Institute for Sustainable Energy/College of Sciences, Shanghai University, Shanghai 200444, China
Helmholtz Institute Ulm (HIU), Ulm D89081, Germany
School of Electrical Engineering, Xi’an Jiaotong University, Xi’an 710049, China
Keywords:
nanofiber, high dielectric functional polymer, Li metal full cell, low N/P ratio, high-retention capacity
Topics:
Lithium batteries
Cite this article:
Kang Q, Zhuang Z, Li Y, et al. Manipulating dielectric property of polymer coatings toward high-retention-rate lithium metal full batteries under harsh critical conditions. Nano Research, 2023, 16(7): 9240-9249. https://doi.org/10.1007/s12274-023-5478-4
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Abstract Full text Electronic supplementary material About this article

Lithium (Li) metal batteries (LMBs) can potentially deliver much higher energy density but remain plagued by uncontrollable Li plating with dendrite growth, unstable interfaces, and highly abundant excess Li (> 50 mAh∙cm−2). Herein, different from the artificial layer or three-dimensional (3D) matrix host constructions, various dielectric polymers are initially well-comprehensively investigated from experimental characterizations to theoretical simulation to evaluate their functions in modulating Li ion distribution. As a proof of concept, a 3D interwoven high dielectric functional polymer (HDFP) nanofiber network with polar C–F dipole moments electrospun on copper (Cu) foil is designed, realizing uniform and controllable Li deposition capacity up to 5.0 mAh∙cm−2, thereby enabling stable Li plating/stripping cycling over 1400 h at 1.0 mA∙cm−2. More importantly, under the high-cathode loading (~ 3.1 mAh∙cm−2) and only 0.6 × excess Li (N/P ratio of 1.6), the full cells retain capacity retention of 97.4% after 200 cycles at 3.36 mA∙cm−2 and achieve high energy density (297.7 Wh∙kg−1 at cell-level) under lean electrolyte conditions (15 μL), much better than ever-reported literatures. Our work provides a new direction for designing high dielectric polymer coating toward high-retention-rate practical Li full batteries.


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Abstract
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Electronic supplementary material
About this article

Manipulating dielectric property of polymer coatings toward high-retention-rate lithium metal full batteries under harsh critical conditions

Show Author's information Qi Kang1, Zechao Zhuang2, Yong Li3, Yinze Zuo4, Jian Wang5, Yijie Liu1, Chaoqun Shi6, Jie Chen1, Hongfei Li1, Pingkai Jiang1, Xingyi Huang1( )
Department of Polymer Science and Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Department of Chemistry, Tsinghua University, Beijing 100084, China
Institute of Applied and Physical Chemistry and Center for Environmental Research and Sustainable Technology, University of Bremen, Bremen 28359, Germany
Institute for Sustainable Energy/College of Sciences, Shanghai University, Shanghai 200444, China
Helmholtz Institute Ulm (HIU), Ulm D89081, Germany
School of Electrical Engineering, Xi’an Jiaotong University, Xi’an 710049, China

Abstract

Lithium (Li) metal batteries (LMBs) can potentially deliver much higher energy density but remain plagued by uncontrollable Li plating with dendrite growth, unstable interfaces, and highly abundant excess Li (> 50 mAh∙cm−2). Herein, different from the artificial layer or three-dimensional (3D) matrix host constructions, various dielectric polymers are initially well-comprehensively investigated from experimental characterizations to theoretical simulation to evaluate their functions in modulating Li ion distribution. As a proof of concept, a 3D interwoven high dielectric functional polymer (HDFP) nanofiber network with polar C–F dipole moments electrospun on copper (Cu) foil is designed, realizing uniform and controllable Li deposition capacity up to 5.0 mAh∙cm−2, thereby enabling stable Li plating/stripping cycling over 1400 h at 1.0 mA∙cm−2. More importantly, under the high-cathode loading (~ 3.1 mAh∙cm−2) and only 0.6 × excess Li (N/P ratio of 1.6), the full cells retain capacity retention of 97.4% after 200 cycles at 3.36 mA∙cm−2 and achieve high energy density (297.7 Wh∙kg−1 at cell-level) under lean electrolyte conditions (15 μL), much better than ever-reported literatures. Our work provides a new direction for designing high dielectric polymer coating toward high-retention-rate practical Li full batteries.

Keywords: nanofiber, high dielectric functional polymer, Li metal full cell, low N/P ratio, high-retention capacity

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Publication history
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Acknowledgements

Publication history

Received: 12 December 2022
Revised: 04 January 2023
Accepted: 05 January 2023
Published: 19 February 2023
Issue date: July 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work was financial supported by the National Natural Science Foundation of China (Nos. 51877132, 52003153, and 22005186) and the Program of Shanghai Academic Research Leader (No. 21XD1401600).

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