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Nano Research 2023, 16(5): 6903-6913 https://doi.org/10.1007/s12274-023-5445-0
Research Article | Issue | Published: 15 February 2023

Metal oxyacid salts-confined pyrolysis towards hierarchical porous metal oxide@carbon (MO@C) composites as lithium-ion battery anodes

Show Author's Information Huizhong Xu1,  Chang Gao1,  Zhaoyang Cheng1,  Linghui Kong1,  Wei Li2( ),  Xiaochen Dong3,  Jianjian Lin1( )
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, Ministry of Education (MOE), Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Engineering Research Center of High Performance Polymer and Molding Technology, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China
Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing, 211800, China
Keywords:
transition metal oxides, anode materials, hierarchical porous carbon framework, lithium storage performance
Topics:
Lithium batteries
Cite this article:
Xu H, Gao C, Cheng Z, et al. Metal oxyacid salts-confined pyrolysis towards hierarchical porous metal oxide@carbon (MO@C) composites as lithium-ion battery anodes. Nano Research, 2023, 16(5): 6903-6913. https://doi.org/10.1007/s12274-023-5445-0
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Abstract Full text Electronic supplementary material About this article

Transition metal oxides (TMOs) have been thought of potential anodic materials for lithium-ion batteries (LIBs) owing to their intriguing properties. However, the limited conductivity and drastic volume change still hinder their practical applications. Herein, a metal oxyacid salts-confined pyrolysis strategy is proposed to construct hierarchical porous metal oxide@carbon (MO@C, MO = MoO2, V2O5, and WO3) composites for solving the aforementioned problems. A water-evaporation-induced self-assembly mechanism has been put forward for fabricating the MO@polyvinyl pyrrolidone (PVP)@SiO2 precursors. After the following pyrolysis and etching process, small MO nanoparticles can be successfully encapsulated in the hierarchical porous carbon framework. Profiting from the synergistic effect of MO nanoparticles and highly conductive carbon framework, MO@C composites show excellent electrochemical properties. For example, the as-obtained MoO2@C composite exhibits a large discharge capacity (1513.7 mAh·g−1 at 0.1 A·g−1), good rate ability (443.5 mAh·g−1 at 5.0 A·g−1), and supernal long-lived stability (669.1 mAh·g−1 after 1000 cycles at 1.0 A·g−1). This work will inspire the design of novel anode materials for high-performance LIBs.


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Electronic supplementary material
About this article

Metal oxyacid salts-confined pyrolysis towards hierarchical porous metal oxide@carbon (MO@C) composites as lithium-ion battery anodes

Show Author's information Huizhong Xu1, Chang Gao1, Zhaoyang Cheng1, Linghui Kong1, Wei Li2( ), Xiaochen Dong3, Jianjian Lin1( )
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, Ministry of Education (MOE), Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Engineering Research Center of High Performance Polymer and Molding Technology, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China
Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing, 211800, China

Abstract

Transition metal oxides (TMOs) have been thought of potential anodic materials for lithium-ion batteries (LIBs) owing to their intriguing properties. However, the limited conductivity and drastic volume change still hinder their practical applications. Herein, a metal oxyacid salts-confined pyrolysis strategy is proposed to construct hierarchical porous metal oxide@carbon (MO@C, MO = MoO2, V2O5, and WO3) composites for solving the aforementioned problems. A water-evaporation-induced self-assembly mechanism has been put forward for fabricating the MO@polyvinyl pyrrolidone (PVP)@SiO2 precursors. After the following pyrolysis and etching process, small MO nanoparticles can be successfully encapsulated in the hierarchical porous carbon framework. Profiting from the synergistic effect of MO nanoparticles and highly conductive carbon framework, MO@C composites show excellent electrochemical properties. For example, the as-obtained MoO2@C composite exhibits a large discharge capacity (1513.7 mAh·g−1 at 0.1 A·g−1), good rate ability (443.5 mAh·g−1 at 5.0 A·g−1), and supernal long-lived stability (669.1 mAh·g−1 after 1000 cycles at 1.0 A·g−1). This work will inspire the design of novel anode materials for high-performance LIBs.

Keywords: transition metal oxides, anode materials, hierarchical porous carbon framework, lithium storage performance

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Publication history
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Acknowledgements

Publication history

Received: 25 October 2022
Revised: 09 December 2022
Accepted: 25 December 2022
Published: 15 February 2023
Issue date: May 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

J. J. Lin is supported by the Taishan Scholar Project of Shandong Province (No. tsqn201909115). And this work was partly supported by Qingdao University of Science and Technology Hua Xue 201919 (No. QUSTHX201919).

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