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Nano Research 2023, 16(5): 7874-7905 https://doi.org/10.1007/s12274-023-5419-2
Review Article | Issue | Published: 27 February 2023

A review on the rational design and fabrication of nanosized high- entropy materials

Show Author's Information Yuanbo Zhou1,2,§,  Xiaowei Shen4,§,  Tao Qian3,5,  Chenglin Yan2,5( ),  Jianmei Lu1( )
Collaborative Innovation Center of Suzhou Nano Science and Technology, College of Chemistry Chemical Engineering and Materials Science Soochow University, 199 Ren’ai Road, Suzhou 215123, China
Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, College of Energy, Soochow University, Suzhou 215006, China
School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China
School of Electrical Engineering, Nantong University, Nantong 226019, China
Light Industry Institute of Electrochemical Power Sources, Suzhou 215600, China

§ Yuanbo Zhou and Xiaowei Shen contributed equally to this work.

Keywords:
characterization, application, high-entropy alloys, synthesis strategies, rational design, high-entropy alloy (HEA) derivate
Topics:
EnergyAlloysElectrocatalystsFabricationNanocrystalline alloys Structural design
Cite this article:
Zhou Y, Shen X, Qian T, et al. A review on the rational design and fabrication of nanosized high- entropy materials. Nano Research, 2023, 16(5): 7874-7905. https://doi.org/10.1007/s12274-023-5419-2
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Abstract Full text About this article

High-entropy materials are mainly composed of high-entropy alloys (HEAs) and their derivates. Among them, HEAs account for a big part. As a new kind of alloy, they are now arousing great interests because of their high mechanical strength, extraordinary fracture toughness, and corrosion resistance compared with traditional alloys. These characteristics allow the use of HEAs in various fields, including mechanical manufacturing, heat-resistant, radiation-resistant, corrosion-resistant, and wear-resistant coatings, energy storage, heterocatalysis, etc. In order to promote the extensive application of HEAs, it is of significance to realize their rational design and preparation. In this paper, a systematic review focusing on the rational design and fabrication of nanosized HEAs is given. The design principles of how to match different elements in HEAs and the premise for the formation of single-phase solid solution HEAs are first illustrated. Computation methods for the prediction of formation conditions and properties of HEAs are also in discussion. Then, a detailed description and comparison of the synthesis methods of HEAs and their derivate, as well as their growing mechanism under various synthetic environments is provided. The commonly used characterization methods for the detection of HEAs, along with the typical cases of the application of HEAs in industrial materials, energy storage materials and catalytic materials are also included. Finally, the challenges and perspectives in the design and synthesis of HEAs would be proposed. We hope this review will give guidance for the future development of HEAs materials.


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About this article

A review on the rational design and fabrication of nanosized high- entropy materials

Show Author's information Yuanbo Zhou1,2,§, Xiaowei Shen4,§, Tao Qian3,5, Chenglin Yan2,5( ), Jianmei Lu1( )
Collaborative Innovation Center of Suzhou Nano Science and Technology, College of Chemistry Chemical Engineering and Materials Science Soochow University, 199 Ren’ai Road, Suzhou 215123, China
Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, College of Energy, Soochow University, Suzhou 215006, China
School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China
School of Electrical Engineering, Nantong University, Nantong 226019, China
Light Industry Institute of Electrochemical Power Sources, Suzhou 215600, China

§ Yuanbo Zhou and Xiaowei Shen contributed equally to this work.

Abstract

High-entropy materials are mainly composed of high-entropy alloys (HEAs) and their derivates. Among them, HEAs account for a big part. As a new kind of alloy, they are now arousing great interests because of their high mechanical strength, extraordinary fracture toughness, and corrosion resistance compared with traditional alloys. These characteristics allow the use of HEAs in various fields, including mechanical manufacturing, heat-resistant, radiation-resistant, corrosion-resistant, and wear-resistant coatings, energy storage, heterocatalysis, etc. In order to promote the extensive application of HEAs, it is of significance to realize their rational design and preparation. In this paper, a systematic review focusing on the rational design and fabrication of nanosized HEAs is given. The design principles of how to match different elements in HEAs and the premise for the formation of single-phase solid solution HEAs are first illustrated. Computation methods for the prediction of formation conditions and properties of HEAs are also in discussion. Then, a detailed description and comparison of the synthesis methods of HEAs and their derivate, as well as their growing mechanism under various synthetic environments is provided. The commonly used characterization methods for the detection of HEAs, along with the typical cases of the application of HEAs in industrial materials, energy storage materials and catalytic materials are also included. Finally, the challenges and perspectives in the design and synthesis of HEAs would be proposed. We hope this review will give guidance for the future development of HEAs materials.

Keywords: characterization, application, high-entropy alloys, synthesis strategies, rational design, high-entropy alloy (HEA) derivate

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Publication history
Copyright
Acknowledgements

Publication history

Received: 05 October 2022
Revised: 28 November 2022
Accepted: 18 December 2022
Published: 27 February 2023
Issue date: May 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21703149, 51872193, 21938006, and 5192500409), the National Key Research & Development Program of China (No. 2020YFC1808401), Cutting-Edge Technology Basic Research Project of Jiangsu (No. BK20202012), and the project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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