Journal Home > Volume 16 , Issue 4
Nano Research 2023, 16(4): 5857-5863 https://doi.org/10.1007/s12274-023-5384-9
Communication | Issue | Published: 23 December 2022

Electrochemical NO reduction to NH3 on Cu single atom catalyst

Show Author's Information Kai Chen1,§,  Guike Zhang1,§,  Xiaotian Li1,  Xiaolin Zhao2,  Ke Chu1( )
School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
National Engineering Laboratory for Electric Vehicles, Beijing Institute of Technology, Beijing 100081, China

§ Kai Chen and Guike Zhang contributed equally to this work.

Keywords:
theoretical calculations, electrochemical NO reduction to NH3, Cu single-atom catalyst
Topics:
Synthesis
Cite this article:
Chen K, Zhang G, Li X, et al. Electrochemical NO reduction to NH3 on Cu single atom catalyst. Nano Research, 2023, 16(4): 5857-5863. https://doi.org/10.1007/s12274-023-5384-9
Download citation
EndNote(RIS)
BibTeX

7764

Views

666

Downloads

Citations

63

Crossref

60

WoS

60

Scopus

2

CSCD

Abstract Full text Electronic supplementary material About this article

Electrochemical NO reduction reaction (NORR) to generate NH3 emerges as a fascinating approach to achieve both NO pollution mitigation and sustainable NH3 synthesis. Herein, we demonstrate that single-atomic Cu anchored on MoS2 (Cu1/MoS2) comprising Cu1-S3 motifs can serve as a highly efficient NORR catalyst. Cu1/MoS2 exhibits an NH3 yield rate of 337.5 μmol·h−1·cm−2 with a Faradaic efficiency of 90.6% at −0.6 V vs. reversible hydrogen electrode (RHE). Combined experiments and theoretical calculations reveal that Cu1-S3 motifs enable the effective activation and hydrogenation of NO through a mixed pathway and simultaneously retard proton coverage, contributing to the high activity and selectivity of Cu1/MoS2 for the NORR.


menu
Abstract
Full text
Outline
Electronic supplementary material
About this article

Electrochemical NO reduction to NH3 on Cu single atom catalyst

Show Author's information Kai Chen1,§, Guike Zhang1,§, Xiaotian Li1, Xiaolin Zhao2, Ke Chu1( )
School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
National Engineering Laboratory for Electric Vehicles, Beijing Institute of Technology, Beijing 100081, China

§ Kai Chen and Guike Zhang contributed equally to this work.

Abstract

Electrochemical NO reduction reaction (NORR) to generate NH3 emerges as a fascinating approach to achieve both NO pollution mitigation and sustainable NH3 synthesis. Herein, we demonstrate that single-atomic Cu anchored on MoS2 (Cu1/MoS2) comprising Cu1-S3 motifs can serve as a highly efficient NORR catalyst. Cu1/MoS2 exhibits an NH3 yield rate of 337.5 μmol·h−1·cm−2 with a Faradaic efficiency of 90.6% at −0.6 V vs. reversible hydrogen electrode (RHE). Combined experiments and theoretical calculations reveal that Cu1-S3 motifs enable the effective activation and hydrogenation of NO through a mixed pathway and simultaneously retard proton coverage, contributing to the high activity and selectivity of Cu1/MoS2 for the NORR.

Keywords: theoretical calculations, electrochemical NO reduction to NH3, Cu single-atom catalyst

References(66)

[1]

Liang, J.; Liu, Q.; Alshehri, A. A.; Sun, X. P. Recent advances in nanostructured heterogeneous catalysts for N-cycle electrocatalysis. Nano Res. Energy 2022, 1, e9120010.
DOI Google Scholar
[2]

Chu, K.; Li, X. C.; Li, Q. Q.; Guo, Y. L.; Zhang, H. Synergistic enhancement of electrocatalytic nitrogen reduction over boron nitride quantum dots decorated Nb2CTx-MXene. Small 2021, 17, 2102363.
DOI Google Scholar
[3]

Shen, H. D.; Choi, C.; Masa, J.; Li, X.; Qiu, J. S.; Jung, Y.; Sun, Z. Y. Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design. Chem 2021, 7, 1708–1754.
DOI Google Scholar
[4]

Zhao, X.; Li, X.; Zhang, H. B.; Chen, X.; Xu, J.; Yang, J.; Zhang, H. C.; Hu, G. Z. Atomic-dispersed copper simultaneously achieve high-efficiency removal and high-value-added conversion to ammonia of nitrate in sewage. J. Hazard. Mater. 2022, 424, 127319.
DOI Google Scholar
[5]

Zhao, X.; Hu, G. Z.; Tan, F.; Zhang, S. S.; Wang, X. Z.; Hu, X.; Kuklin, A. V.; Baryshnikov, G. V.; Ågren, H.; Zhou, X. H. et al. Copper confined in vesicle-like BCN cavities promotes electrochemical reduction of nitrate to ammonia in water. J. Mater. Chem. A 2021, 9, 23675–23686.
DOI Google Scholar
[6]

Liu, Q.; Xu, T.; Luo, Y. L.; Kong, Q. Q.; Li, T. S.; Lu, S. Y.; Alshehri, A. A.; Alzahrani, K. A.; Sun, X. P. Recent advances in strategies for highly selective electrocatalytic N2 reduction toward ambient NH3 synthesis. Curr. Opin. Electroche. 2021, 29, 100766.
DOI Google Scholar
[7]

Qing, G.; Ghazfar, R.; Jackowski, S. T.; Habibzadeh, F.; Ashtiani, M. M.; Chen, C. P.; Smith, M. R.; Hamann, T. W. Recent advances and challenges of electrocatalytic N2 reduction to ammonia. Chem. Rev. 2020, 120, 5437–5516.
DOI Google Scholar
[8]

Shen, P.; Li, X. C.; Luo, Y. J.; Guo, Y. L.; Zhao, X. L.; Chu, K. High-efficiency N2 electroreduction enabled by Se-vacancy-rich WSe2−x in water-in-salt electrolytes. ACS Nano 2022, 16, 7915–7925.
DOI Google Scholar
[9]

Li, X. C.; Shen, P.; Luo, Y. J.; Li, Y. H.; Guo, Y. L.; Zhang, H.; Chu, K. PdFe single-atom alloy metallene for N2 electroreduction. Angew. Chem., Int. Ed. 2022, 134, e202205923.
DOI Google Scholar
[10]

Chu, K.; Liu, Y. P.; Chen, Y. H.; Li, Q. Q. Synergistic boron-dopants and boron-induced oxygen vacancies in MnO2 nanosheets to promote electrocatalytic nitrogen reduction. J. Mater. Chem. A 2020, 8, 5200–5208.
DOI Google Scholar
[11]

Luo, Y. J.; Chen, K.; Shen, P.; Li, X. C.; Li, X. T.; Li, Y. H.; Chu, K. B-doped MoS2 for nitrate electroreduction to ammonia. J. Colloid Interface Sci. 2023, 629, 950–957.
DOI Google Scholar
[12]

Shen, P.; Wang, G. H.; Chen, K.; Kang, J. L.; Ma, D. W.; Chu, K. Selenium-vacancy-rich WSe2 for nitrate electroreduction to ammonia. J. Colloid Interface Sci. 2023, 629, 563–570.
DOI Google Scholar
[13]

Luo, Y. J.; Li, Q. Q.; Tian, Y.; Liu, Y. P.; Chu, K. Amorphization engineered VSe2−x nanosheets with abundant Se-vacancies for enhanced N2 electroreduction. J. Mater. Chem. A 2022, 10, 1742–1749.
DOI Google Scholar
[14]

Wang, G. H.; Shen, P.; Luo, Y. J.; Li, X. T.; Li, X. C.; Chu, K. A vacancy engineered MnO2−x electrocatalyst promotes nitrate electroreduction to ammonia. Dalton Trans. 2022, 51, 9206–9212.
DOI Google Scholar
[15]

Zhang, G. K.; Li, X. C.; Shen, P.; Luo, Y. J.; Li, X. T.; Chu, K. PdNi nanosheets boost nitrate electroreduction to ammonia. J. Environ. Chem. Eng. 2022, 10, 108362.
DOI Google Scholar
[16]
Qin, Y. Y.; Li, Y.; Zhao, W. S.; Chen, S. H.; Wu, T. T.; Su, Y. Q. Computational study of transition metal single-atom catalysts supported on nitrogenated carbon nanotubes for electrocatalytic nitrogen reduction. Nano Res., in press, https://doi.org/10.1007/s12274-022-4803-7.
[17]
Lin, L. H.; Wei, F. F.; Jiang, R.; Huang, Y. C.; Lin, S. The role of central heteroatom in electrochemical nitrogen reduction catalyzed by polyoxometalate-supported single-atom catalyst. Nano Res., in press, https://doi.org/10.1007/s12274-022-4800-x.
[18]

Zhao, X.; Hu, G. Z.; Chen, G. F.; Zhang, H. B.; Zhang, S. S.; Wang, H. H. Comprehensive understanding of the thriving ambient electrochemical nitrogen reduction reaction. Adv. Mater. 2021, 33, 2007650.
DOI Google Scholar
[19]

Li, Y.; Wang, H. H.; Priest, C.; Li, S. W.; Xu, P.; Wu, G. Advanced electrocatalysis for energy and environmental sustainability via water and nitrogen reactions. Adv. Mater. 2021, 33, 2000381.
DOI Google Scholar
[20]

Yan, Z. H.; Ji, M. X.; Xia, J. X.; Zhu, H. Y. Recent advanced materials for electrochemical and photoelectrochemical synthesis of ammonia from dinitrogen: One step closer to a sustainable energy future. Adv. Energy Mater. 2020, 10, 1902020.
DOI Google Scholar
[21]

Shen, P.; Li, X. T.; Luo, Y. J.; Zhang, N. N.; Zhao, X. L.; Chu, K. Ultra-efficient N2 electroreduction achieved over a rhodium single-atom catalyst (Rh1/MnO2) in water-in-salt electrolyte. Appl. Catal. B 2022, 316, 121651.
DOI Google Scholar
[22]

Luo, Y. J.; Shen, P.; Li, X. C.; Guo, Y. L.; Chu, K. Sulfur-deficient Bi2S3−x synergistically coupling Ti3C2Tx-MXene for boosting electrocatalytic N2 reduction. Nano Res. 2022, 15, 3991–3999.
DOI Google Scholar
[23]

Chu, K.; Li, X. C.; Tian, Y.; Li, Q. Q.; Guo, Y. L. Boron nitride quantum dots/Ti3C2Tx-MXene heterostructure for efficient electrocatalytic nitrogen fixation. Energy Environ. Mater. 2022, 5, 1303–1309.
DOI Google Scholar
[24]

Li, X. C.; Luo, Y. J.; Li, Q. Q.; Guo, Y. L.; Chu, K. Constructing an electron-rich interface over an Sb/Nb2CTx-MXene heterojunction for enhanced electrocatalytic nitrogen reduction. J. Mater. Chem. A 2021, 9, 15955–15962.
DOI Google Scholar
[25]

Chu, K.; Wang, J.; Liu, Y. P.; Li, Q. Q.; Guo, Y. L. Mo-doped SnS2 with enriched S-vacancies for highly efficient electrocatalytic N2 reduction: The critical role of the Mo-Sn-Sn trimer. J. Mater. Chem. A 2020, 8, 7117–7124.
DOI Google Scholar
[26]

Xiong, Y. H.; Li, Y. T.; Wan, S. P.; Yu, Y.; Zhang, S. L.; Zhong, Q. Ferrous-based electrolyte for simultaneous NO absorption and electroreduction to NH3 using Au/rGO electrode. J. Hazard. Mater. 2022, 430, 128451.
DOI Google Scholar
[27]

Li, Y. B.; Cheng, C. Q.; Han, S. H.; Huang, Y. M.; Du, X. W.; Zhang, B.; Yu, Y. F. Electrocatalytic reduction of low-concentration nitric oxide into ammonia over Ru nanosheets. ACS Energy Lett. 2022, 7, 1187–1194.
DOI Google Scholar
[28]

Ko, B. H.; Hasa, B.; Shin, H.; Zhao, Y. R.; Jiao, F. Electrochemical reduction of gaseous nitrogen oxides on transition metals at ambient conditions. J. Am. Chem. Soc. 2022, 144, 1258–1266.
DOI Google Scholar
[29]

Long, J.; Chen, S. M.; Zhang, Y. L.; Guo, C. X.; Fu, X. Y.; Deng, D. H.; Xiao, J. P. Direct electrochemical ammonia synthesis from nitric oxide. Angew. Chem., Int. Ed. 2020, 59, 9711–9718.
DOI Google Scholar
[30]

Li, X. T.; Chen, K.; Lu, X. B.; Ma, D. W.; Chu, K. Atomically dispersed Co catalyst for electrocatalytic NO reduction to NH3. Chem. Eng. J. 2023, 454, 140333.
DOI Google Scholar
[31]

Liang, J.; Liu, P. Y.; Li, Q. Y.; Li, T. S.; Yue, L. C.; Luo, Y. S.; Liu, Q.; Li, N.; Tang, B.; Alshehri, A. A. et al. Amorphous boron carbide on titanium dioxide nanobelt arrays for high-efficiency electrocatalytic NO reduction to NH3. Angew. Chem., Int. Ed. 2022, 61, e202202087.
DOI Google Scholar
[32]

Liang, J.; Hu, W. F.; Song, B. Y.; Mou, T.; Zhang, L. C.; Luo, Y. S.; Liu, Q.; Alshehri, A. A.; Hamdy, M. S.; Yang, L. M. et al. Efficient nitric oxide electroreduction toward ambient ammonia synthesis catalyzed by a CoP nanoarray. Inorg. Chem. Front. 2022, 9, 1366–1372.
DOI Google Scholar
[33]

Liang, J.; Chen, H. Y.; Mou, T.; Zhang, L. C.; Lin, Y. T.; Yue, L. C.; Luo, Y. S.; Liu, Q.; Li, N.; Alshehri, A. A. et al. Coupling denitrification and ammonia synthesis via selective electrochemical reduction of nitric oxide over Fe2O3 nanorods. J. Mater. Chem. A 2022, 10, 6454–6462.
DOI Google Scholar
[34]

Zhang, L. C.; Liang, J.; Wang, Y. Y.; Mou, T.; Lin, Y. T.; Yue, L. C.; Li, T. S.; Liu, Q.; Luo, Y. L.; Li, N. et al. High-performance electrochemical NO reduction into NH3 by MoS2 nanosheet. Angew. Chem., Int. Ed. 2021, 60, 25263–25268.
DOI Google Scholar
[35]

Meng, G.; Jin, M. M.; Wei, T. R.; Liu, Q.; Zhang, S. S.; Peng, X. Y.; Luo, J.; Liu, X. J. MoC nanocrystals confined in N-doped carbon nanosheets toward highly selective electrocatalytic nitric oxide reduction to ammonia. Nano Res. 2022, 15, 8890–8896.
DOI Google Scholar
[36]

Qi, D. F.; Lv, F.; Wei, T. R.; Jin, M. M.; Meng, G.; Zhang, S. S.; Liu, Q.; Liu, W. X.; Ma, D.; Hamdy, M. S. et al. High-efficiency electrocatalytic NO reduction to NH3 by nanoporous VN. Nano Res. Energy 2022, 1, e9120022.
DOI Google Scholar
[37]

Chen, K.; Wang, J. X.; Kang, J. L.; Lu, X. B.; Zhao, X. L.; Chu, K. Atomically Fe-doped MoS2−x with Fe-Mo dual sites for efficient electrocatalytic NO reduction to NH3. Appl. Catal. B 2023, 324, 122241.
DOI Google Scholar
[38]
Li, X. T.; Zhang, G. K.; Shen, P.; Zhao, X. L.; Chu, K. A defect engineered p-block SnS2−x catalyst for efficient electrocatalytic NO reduction to NH3. Inorg. Chem. Front., in press, https://doi.org/10.1039/d2qi02118h.
[39]

Chen, L.; Sun, W. T.; Xu, Z. Y.; Hao, M. H.; Li, B. J.; Liu, X.; Ma, J. J.; Wang, L.; Li, C. H.; Wang, W. T. Ultrafine Cu nanoparticles decorated porous TiO2 for high-efficient electrocatalytic reduction of NO to synthesize NH3. Ceram. Int. 2022, 48, 21151–21161.
DOI Google Scholar
[40]

Shi, J. W.; Wang, C. H.; Yang, R.; Chen, F. P.; Meng, N. N.; Yu, Y. F.; Zhang, B. Promoting nitric oxide electroreduction to ammonia over electron-rich Cu modulated by Ru doping. Sci. China Chem. 2021, 64, 1493–1497.
DOI Google Scholar
[41]

Gao, C.; Low, J.; Long, R.; Kong, T. T.; Zhu, J. F.; Xiong, Y. J. Heterogeneous single-atom photocatalysts: Fundamentals and applications. Chem. Rev. 2020, 120, 12175–12216.
DOI Google Scholar
[42]

Lang, R.; Du, X. R.; Huang, Y. K.; Jiang, X. Z.; Zhang, Q.; Guo, Y. L.; Liu, K. P.; Qiao, B. T.; Wang, A. Q.; Zhang, T. Single-atom catalysts based on the metal–oxide interaction. Chem. Rev. 2020, 120, 11986–12043.
DOI Google Scholar
[43]

Peng, X. Y.; Mi, Y. Y.; Bao, H. H.; Liu, Y. F.; Qi, D. F.; Qiu, Y.; Zhuo, L. C.; Zhao, S. Z.; Sun, J. Q.; Tang, X. L. et al. Ambient electrosynthesis of ammonia with efficient denitration. Nano Energy 2020, 78, 105321.
DOI Google Scholar
[44]

Bao, H. H.; Qiu, Y.; Peng, X. Y.; Wang, J. A.; Mi, Y. Y.; Zhao, S. Z.; Liu, X. J.; Liu, Y. F.; Cao, R.; Zhuo, L. C. et al. Isolated copper single sites for high-performance electroreduction of carbon monoxide to multicarbon products. Nat. Commun. 2021, 12, 238.
DOI Google Scholar
[45]

Xu, H. B.; Jia, H. X.; Li, H. Z.; Liu, J.; Gao, X. W.; Zhang, J. C.; Liu, M.; Sun, D. L.; Chou, S. L.; Fang, F. et al. Dual carbon-hosted Co-N3 enabling unusual reaction pathway for efficient oxygen reduction reaction. Appl. Catal. B 2021, 297, 120390.
DOI Google Scholar
[46]

Zang, W. J.; Sun, T.; Yang, T.; Xi, S. B.; Waqar, M.; Kou, Z. K.; Lyu, Z.; Feng, Y. P.; Wang, J.; Pennycook, S. J. Efficient hydrogen evolution of oxidized Ni-N3 defective sites for alkaline freshwater and seawater electrolysis. Adv. Mater. 2021, 33, 2003846.
DOI Google Scholar
[47]

Li, J.; Chen, S.; Quan, F. J.; Zhan, G. M.; Jia, F. L.; Ai, Z. H.; Zhang, L. Z. Accelerated dinitrogen electroreduction to ammonia via interfacial polarization triggered by single-atom protrusions. Chem 2020, 6, 885–901.
DOI Google Scholar
[48]

Chu, K.; Luo, Y. J.; Shen, P.; Li, X. C.; Li, Q. Q.; Guo, Y. L. Unveiling the synergy of O-vacancy and heterostructure over MoO3−x/MXene for N2 electroreduction to NH3. Adv. Energy Mater. 2022, 12, 2103022.
DOI Google Scholar
[49]

Li, Q. Q.; Shen, P.; Tian, Y.; Li, X. C.; Chu, K. Metal-free BN quantum dots/graphitic C3N4 heterostructure for nitrogen reduction reaction. J. Colloid Interface Sci. 2022, 606, 204–212.
DOI Google Scholar
[50]

Chu, K.; Liu, Y. P.; Li, Y. B.; Wang, J.; Zhang, H. Electronically coupled SnO2 quantum dots and graphene for efficient nitrogen reduction reaction. ACS Appl. Mater. Interfaces 2019, 11, 31806–31815.
DOI Google Scholar
[51]

Zhang, L. C.; Liang, J.; Yue, L. C.; Dong, K.; Li, J.; Zhao, D. L.; Li, Z. R.; Sun, S. J.; Luo, Y. S.; Liu, Q. et al. Benzoate anions-intercalated NiFe-layered double hydroxide nanosheet array with enhanced stability for electrochemical seawater oxidation. Nano Res. Energy 2022, 1, e9120028.
DOI Google Scholar
[52]

Safaei, J.; Wang, G. X. Progress and prospects of two-dimensional materials for membrane-based osmotic power generation. Nano Res. Energy 2022, 1, e9120008.
DOI Google Scholar
[53]

Gao, F.; He, J. Q.; Wang, H. W.; Lin, J. H.; Chen, R. X.; Yi, K.; Huang, F.; Lin, Z.; Wang, M. Y. Te-mediated electro-driven oxygen evolution reaction. Nano Res. Energy 2022, 1, e9120029.
DOI Google Scholar
[54]

Chen, K.; Luo, Y. J.; Shen, P.; Liu, X. X.; Li, X. C.; Li, X. T.; Chu, K. Boosted nitrate electroreduction to ammonia on Fe-doped SnS2 nanosheet arrays rich in S-vacancies. Dalton Trans. 2022, 51, 10343–10350.
DOI Google Scholar
[55]

Li, Q. Q.; Wang, J.; Cheng, Y. H.; Chu, K. Zn nanosheets: An earth-abundant metallic catalyst for efficient electrochemical ammonia synthesis. J. Energy Chem. 2021, 54, 318–322.
DOI Google Scholar
[56]

Li, Q. Q.; Guo, Y. L.; Tian, Y.; Liu, W. M.; Chu, K. Activating VS2 basal planes for enhanced NRR electrocatalysis: The synergistic role of S-vacancies and B dopants. J. Mater. Chem. A 2020, 8, 16195–16202.
DOI Google Scholar
[57]

Liu, Q.; Lin, Y. T.; Yue, L. C.; Liang, J.; Zhang, L. C.; Li, T. S.; Luo, Y. S.; Liu, M. L.; You, J. M.; Alshehri, A. A. et al. Bi nanoparticles/carbon nanosheet composite: A high-efficiency electrocatalyst for NO reduction to NH3. Nano Res. 2022, 15, 5032–5037.
DOI Google Scholar
[58]

Liang, J.; Zhou, Q.; Mou, T.; Chen, H. Y.; Yue, L. C.; Luo, Y. S.; Liu, Q.; Hamdy, M. S.; Alshehri, A. A.; Gong, F. et al. FeP nanorod array: A high-efficiency catalyst for electroreduction of NO to NH3 under ambient conditions. Nano Res. 2022, 15, 4008–4013.
DOI Google Scholar
[59]

Chu, K.; Cheng, Y. H.; Li, Q. Q.; Liu, Y. P.; Tian, Y. Fe-doping induced morphological changes, oxygen vacancies and Ce3+–Ce3+ pairs in CeO2 for promoting electrocatalytic nitrogen fixation. J. Mater. Chem. A 2020, 8, 5865–5873.
DOI Google Scholar
[60]

Chu, K.; Liu, Y. P.; Li, Y. B.; Guo, Y. L.; Tian, Y. Two-dimensional (2D)/2D interface engineering of a MoS2/C3N4 heterostructure for promoted electrocatalytic nitrogen fixation. ACS Appl. Mater. Interfaces 2020, 12, 7081–7090.
DOI Google Scholar
[61]

Chu, K.; Li, Q. Q.; Cheng, Y. H.; Liu, Y. P. Efficient electrocatalytic nitrogen fixation on FeMoO4 nanorods. ACS Appl. Mater. Interfaces 2020, 12, 11789–11796.
DOI Google Scholar
[62]

Chu, K.; Liu, Y. P.; Li, Y. B.; Zhang, H.; Tian, Y. Efficient electrocatalytic N2 reduction on CoO quantum dots. J. Mater. Chem. A 2019, 7, 4389–4394.
DOI Google Scholar
[63]
Cheng, Y. H.; Li, X. C.; Shen, P.; Guo, Y. L.; Chu, K. MXene quantum dots/copper nanocomposites for synergistically enhanced N2 electroreduction. Energy Environ. Mater., in press, https://doi.org/10.1002/eem2.12268.
[64]

Lv, P.; Wu, D. H.; He, B. L.; Li, X.; Zhu, R.; Tang, G.; Lu, Z. S.; Ma, D. W.; Jia, Y. An efficient screening strategy towards multifunctional catalysts for the simultaneous electroreduction of NO3−, NO2− and NO to NH3. J. Mater. Chem. A 2022, 10, 9707–9716.
DOI Google Scholar
[65]

Wang, Y. Y.; Wang, M. R.; Lu, Z. S.; Ma, D. W.; Jia, Y. Enabling multifunctional electrocatalysts by modifying the basal plane of unifunctional 1T'-MoS2 with anchored transition metal single atoms. Nanoscale 2021, 13, 13390–13400.
DOI Google Scholar
[66]

He, B. L.; Lv, P.; Wu, D. H.; Li, X.; Zhu, R.; Chu, K.; Ma, D. W.; Jia, Y. Confinement catalysis of a single atomic vacancy assisted by aliovalent ion doping enabled efficient NO electroreduction to NH3. J. Mater. Chem. A 2022, 10, 18690–18700.
DOI Google Scholar
File
12274_2023_5384_MOESM1_ESM.pdf (2.2 MB)
Publication history
Copyright
Acknowledgements

Publication history

Received: 05 October 2022
Revised: 02 December 2022
Accepted: 04 December 2022
Published: 23 December 2022
Issue date: April 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgement

This work is supported by the National Natural Science Foundation of China (No. 52161025) and Fundamental Researches Top Talent Program of Lanzhou Jiaotong University (No. 2022JC03).

Return