Biomimetic three-dimensional multilevel nanoarray electrodes with superaerophobicity as efficient bifunctional catalysts for electrochemical water splitting

Dongdong Wang; Yue Liu; Lili Liu; Dongfang Shan; Guixin Shen; Shanlong Peng; Heng Zhang; Xindong Wang

doi:10.1007/s12274-022-5373-4

Nano Research 2023, 16(5): 6584-6592 https://doi.org/10.1007/s12274-022-5373-4

Research Article | Issue | Published: 19 February 2023

Biomimetic three-dimensional multilevel nanoarray electrodes with superaerophobicity as efficient bifunctional catalysts for electrochemical water splitting

Show Author's Information Hide Author's Information Dongdong Wang^{¹^,²}, Yue Liu^{¹^,²}, Lili Liu^{¹^,²}, Dongfang Shan^{¹^,²}, Guixin Shen^{¹^,²}, Shanlong Peng^{¹^,²}, Heng Zhang^{¹^,²}(

), Xindong Wang^{¹^,²}(

)

1State Key Laboratory of Advanced Metallurgy, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China

2Energy Storage Science and Engineering, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China

Keywords:

oxygen evolution reaction, hydrogen evolution reaction, superaerophobicity, biomimetic structure

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Electrocatalysts

Cite this article:

Wang D, Liu Y, Liu L, et al. Biomimetic three-dimensional multilevel nanoarray electrodes with superaerophobicity as efficient bifunctional catalysts for electrochemical water splitting. Nano Research, 2023, 16(5): 6584-6592. https://doi.org/10.1007/s12274-022-5373-4

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Abstract

The design and preparation of cost-effective and durable catalysts for electrochemical water splitting are significant for the development and application of hydrogen production. Herein, inspired by the underwater superaerophobicity of fish scales, a three-dimensional multilevel nanoarray electrode with superaerophobicity was designed and fabricated by the hydrothermal method to solve the bubble shielding effect in electrochemical reactions. Benefiting from the high specific surface area, superaerophobic properties, and Al doping, the Al-CoS₂ nanosheets (NSs)/nickel foam (NF)-30 exhibits outstanding electrocatalytic activity and superior durability for electrochemical water splitting in 1 M KOH. Significantly, the Al-CoS₂ NSs/NF-30 only required extremely low overpotential of 176 mV for oxygen evolution reaction (OER) to reach a current density of 10 mA·cm^–2. Al-CoS₂ NSs/NF-30 was employed as bifunctional electrode for electrochemical water splitting with a cell voltage of 1.58 V at 10 mA·cm^–2. Meanwhile, Al-CoS₂ NSs/NF-30 exhibited excellent durability (250 h@10 mA·cm^–2 and 50 h@100 mA·cm^–2). The cobalt-based catalyst (Al-CoS₂ NSs/NF-30) with superaerophobicity exhibits excellent performance in activity and durability, and therefore is a promising electrochemical water splitting catalyst.

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About this article

Biomimetic three-dimensional multilevel nanoarray electrodes with superaerophobicity as efficient bifunctional catalysts for electrochemical water splitting

Show Author's information Hide Author's Information Dongdong Wang^{¹^,²}, Yue Liu^{¹^,²}, Lili Liu^{¹^,²}, Dongfang Shan^{¹^,²}, Guixin Shen^{¹^,²}, Shanlong Peng^{¹^,²}, Heng Zhang^{¹^,²}(

), Xindong Wang^{¹^,²}(

)

1State Key Laboratory of Advanced Metallurgy, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China

2Energy Storage Science and Engineering, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China

Abstract

Keywords: oxygen evolution reaction, hydrogen evolution reaction, superaerophobicity, biomimetic structure

References(55)

[1]

Han, X.; Tao, K.; Wang, D.; Han, L. Design of a porous cobalt sulfide nanosheet array on Ni foam from zeolitic imidazolate frameworks as an advanced electrode for supercapacitors. Nanoscale 2018, 10, 2735–2741.

DOI Google Scholar

[2]

Nowotny, J.; Dodson, J.; Fiechter, S.; Gür, T. M.; Kennedy, B.; Macyk, W.; Bak, T.; Sigmund, W.; Yamawaki, M.; Rahman, K. A. Towards global sustainability: Education on environmentally clean energy technologies. Renew. Sust. Energ. Rev. 2018, 81, 2541–2551.

DOI Google Scholar

[3]

Su, J. W.; Ge, R. X.; Jiang, K. M.; Dong, Y.; Hao, F.; Tian, Z. Q.; Chen, G. X.; Chen, L. Assembling ultrasmall copper-doped ruthenium oxide nanocrystals into hollow porous polyhedra: Highly robust electrocatalysts for oxygen evolution in acidic media. Adv. Mater. 2018, 30, 1801351.

DOI Google Scholar

[4]

Andersson, J.; Grönkvist, S. Large-scale storage of hydrogen. Int. J. Hydrogen Energy 2019, 44, 11901–11919.

DOI Google Scholar

[5]

Capurso, T.; Stefanizzi, M.; Torresi, M.; Camporeale, S. M. Perspective of the role of hydrogen in the 21^st century energy transition. Energy Convers Manag. 2022, 251, 114898.

DOI Google Scholar

[6]

Shit, S.; Chhetri, S.; Jang, W.; Murmu, N. C.; Koo, H.; Samanta, P.; Kuila, T. Cobalt sulfide/nickel sulfide heterostructure directly grown on nickel foam: An efficient and durable electrocatalyst for overall water splitting application. ACS Appl. Mater. Interfaces 2018, 10, 27712–27722.

DOI Google Scholar

[7]

Zubair, M.; UL Hassan, M. M.; Mehran, M. T.; Baig, M. M.; Hussain, S.; Shahzad, F. 2D MXenes and their heterostructures for HER, OER, and overall water splitting: A review. Int. J. Hydrogen Energy 2022, 47, 2794–2818.

DOI Google Scholar

[8]

Seh, Z. W.; Kibsgaard, J.; Dickens, C. F.; Chorkendorff, I.; Nørskov, J. K.; Jaramillo, T. F. Combining theory and experiment in electrocatalysis: Insights into materials design. Science 2017, 355, eaad4998.

DOI Google Scholar

[9]

Ullah, N.; Zhao, W. T.; Lu, X. Q.; Oluigbo, C. J.; Shah, S. A.; Zhang, M. M.; Xie, J. M.; Xu, Y. G. In situ growth of M-MO (M = Ni, Co) in 3D graphene as a competent bifunctional electrocatalyst for OER and HER. Electrochim. Acta 2019, 298, 163–171.

DOI Google Scholar

[10]

Wang, Y.; Kong, B.; Zhao, D. Y.; Wang, H. T.; Selomulya, C. Strategies for developing transition metal phosphides as heterogeneous electrocatalysts for water splitting. Nano Today 2017, 15, 26–55.

DOI Google Scholar

[11]

Zheng, S. S.; Guo, X. T.; Xue, H. G.; Pan, K. M.; Liu, C. S.; Pang, H. Facile one-pot generation of metal oxide/hydroxide@metal-organic framework composites: Highly efficient bifunctional electrocatalysts for overall water splitting. Chem. Commun. 2019, 55, 10904–10907.

DOI Google Scholar

[12]

Talib, S. H.; Lu, Z. S.; Yu, X. H.; Ahmad, K.; Bashir, B.; Yang, Z. X.; Li, J. Theoretical inspection of M₁/PMA single-atom electrocatalyst: Ultra-high performance for water splitting (HER/OER) and oxygen reduction reactions (OER). ACS Catal. 2021, 11, 8929–8941.

DOI Google Scholar

[13]

Singh, T. I.; Rajeshkhanna, G.; Pan, U. N.; Kshetri, T.; Lin, H.; Kim, N. H.; Lee, J. H. Alkaline water splitting enhancement by MOF-derived Fe-Co-oxide/Co@NC-mNS heterostructure: Boosting OER and HER through defect engineering and in situ oxidation. Small 2021, 17, 2101312.

DOI Google Scholar

[14]

Su, J. W.; Xia, G. L.; Li, R.; Yang, Y.; Chen, J. T.; Shi, R. H.; Jiang, P.; Chen, Q. W. Co₃ZnC/Co nano heterojunctions encapsulated in N-doped graphene layers derived from PBAs as highly efficient bi-functional OER and ORR electrocatalysts. J. Mater. Chem. A 2016, 4, 9204–9212.

DOI Google Scholar

[15]

Li, L.; Wang, B.; Zhang, G. W.; Yang, G.; Yang, T.; Yang, S.; Yang, S. C. Electrochemically modifying the electronic structure of IrO₂ nanoparticles for overall electrochemical water splitting with extensive adaptability. Adv. Energy Mater. 2020, 10, 2001600.

DOI Google Scholar

[16]

Chen, D.; Lu, R. H.; Pu, Z. H.; Zhu, J. W.; Li, H. W.; Liu, F.; Hu, S.; Luo, X.; Wu, J. S.; Zhao, Y. et al. Ru-doped 3D flower-like bimetallic phosphide with a climbing effect on overall water splitting. Appl. Catal. B: Environ. 2020, 279, 119396.

DOI Google Scholar

[17]

Fan, Y. X.; Zhang, X. D.; Zhang, Y. J.; Xie, X.; Ding, J.; Cai, J. L.; Li, B. J.; Lv, H. L.; Liu, L. Y.; Zhu, M. M. et al. Decoration of Ru/RuO₂ hybrid nanoparticles on MoO₂ plane as bifunctional electrocatalyst for overall water splitting. J. Colloid Interface Sci. 2021, 604, 508–516.

DOI Google Scholar

[18]

Chen, G. B.; Wang, T.; Zhang, J.; Liu, P.; Sun, H. J.; Zhuang, X. D.; Chen, M. W.; Feng, X. L. Accelerated hydrogen evolution kinetics on NiFe-layered double hydroxide electrocatalysts by tailoring water dissociation active sites. Adv. Mater. 2018, 30, 1706279.

DOI Google Scholar

[19]

Cai, P. W.; Li, Y.; Wang, G. X.; Wen, Z. H. Alkaline–acid Zn-H₂O fuel cell for the simultaneous generation of hydrogen and electricity. Angew. Chem., Int. Ed. 2018, 57, 3910–3915.

DOI Google Scholar

[20]

Zhang, Q.; Han, W. J.; Xu, Z. X.; Li, Y. L.; Chen, L.; Bai, Z. Y.; Yang, L.; Wang, X. L. Hollow waxberry-like cobalt-nickel oxide/S, N-codoped carbon nanospheres as a trifunctional electrocatalyst for OER, ORR, and HER. RSC Adv. 2020, 10, 27788–27793.

DOI Google Scholar

[21]

Guo, Y. Y.; Yuan, P. F.; Zhang, J. N.; Xia, H. C.; Cheng, F. Y.; Zhou, M. F.; Li, J.; Qiao, Y. Y.; Mu, S. C.; Xu, Q. Co₂-CoN double active centers confined in N-doped carbon nanotube: Heterostructural engineering for trifunctional catalysis toward HER, ORR, OER, and Zn-air batteries driven water splitting. Adv. Funct. Mater. 2018, 28, 1805641.

DOI Google Scholar

[22]

Zhang, J. C.; Zhang, D. J.; Zhang, R. C.; Zhang, N. N.; Cui, C. C.; Zhang, J. R.; Jiang, B.; Yuan, B. Q.; Wang, T. Y.; Xie, H. et al. Facile synthesis of mesoporous and thin-walled Ni-Co sulfide nanotubes as efficient electrocatalysts for oxygen evolution reaction. ACS Appl. Energy Mater. 2018, 1, 495–502.

DOI Google Scholar

[23]

Guo, Y. N.; Tang, J.; Wang, Z. L.; Kang, Y. M.; Bando, Y.; Yamauchi, Y. Elaborately assembled core–shell structured metal sulfides as a bifunctional catalyst for highly efficient electrochemical overall water splitting. Nano Energy 2018, 47, 494–502.

DOI Google Scholar

[24]

Hua, Y. P.; Jiang, H.; Jiang, H. B.; Zhang, H. X.; Li, C. Z. Hierarchical porous CoS₂ microboxes for efficient oxygen evolution reaction. Electrochim. Acta 2018, 278, 219–225.

DOI Google Scholar

[25]

Zhu, J. Q.; Ren, Z. Y.; Du, S. C.; Xie, Y.; Wu, J.; Meng, H. Y.; Xue, Y. Z.; Fu, H. G. Co-vacancy-rich Co_1–xS nanosheets anchored on rGO for high-efficiency oxygen evolution. Nano Res. 2017, 10, 1819–1831.

DOI Google Scholar

[26]

Guan, C.; Liu, X. M.; Elshahawy, A. M.; Zhang, H.; Wu, H. J.; Pennycook, S. J.; Wang, J. Metal-organic framework derived hollow CoS₂ nanotube arrays: An efficient bifunctional electrocatalyst for overall water splitting. Nanoscale Horiz. 2017, 2, 342–348.

DOI Google Scholar

[27]

Li, Y. G.; Fu, X.; Zhu, W. X.; Gong, J. D.; Sun, J.; Zhang, D. H.; Wang, J. L. Self-ZIF template-directed synthesis of a CoS nanoflake array as a Janus electrocatalyst for overall water splitting. Inorg. Chem. Front. 2019, 6, 2090–2095.

DOI Google Scholar

[28]

Wang, K. X.; Wang, X. Y.; Li, Z. J.; Yang, B.; Ling, M.; Gao, X.; Lu, J. G.; Shi, Q. R.; Lei, L. C.; Wu, G. et al. Designing 3d dual transition metal electrocatalysts for oxygen evolution reaction in alkaline electrolyte: Beyond oxides. Nano Energy 2020, 77, 105162.

DOI Google Scholar

[29]

Men, Y.; Li, P.; Zhou, J. H.; Cheng, G. Z.; Chen, S. L.; Luo, W. Tailoring the electronic structure of Co₂P by N doping for boosting hydrogen evolution reaction at all pH values. ACS Catal. 2019, 9, 3744–3752.

DOI Google Scholar

[30]

Lu, Z. Y.; Zhu, W.; Yu, X. Y.; Zhang, H. C.; Li, Y. J.; Sun, X. M.; Wang, X. W.; Wang, H.; Wang, J. M.; Luo, J. et al. Ultrahigh hydrogen evolution performance of under-water “superaerophobic” MoS₂ nanostructured electrodes. Adv. Mater. 2014, 26, 2683–2687.

DOI Google Scholar

[31]

Xu, W. W.; Lu, Z. Y.; Sun, X. M.; Jiang, L.; Duan, X. Superwetting electrodes for gas-involving electrocatalysis. Acc. Chem. Res. 2018, 51, 1590–1598.

DOI Google Scholar

[32]

Yong, J. L.; Chen, F.; Li, M. J.; Yang, Q.; Fang, Y.; Huo, J. L.; Hou, X. Remarkably simple achievement of superhydrophobicity, superhydrophilicity, underwater superoleophobicity, underwater superoleophilicity, underwater superaerophobicity, and underwater superaerophilicity on femtosecond laser ablated PDMS surfaces. J. Mater. Chem. A 2017, 5, 25249–25257.

DOI Google Scholar

[33]

Tian, Y. M.; Lin, Z. W.; Yu, J.; Zhao, S. J.; Liu, Q.; Liu, J. Y.; Chen, R. R.; Qi, Y. F.; Zhang, H. S.; Li, R. M. et al. Superaerophobic quaternary Ni-Co-S-P nanoparticles for efficient overall water-splitting. ACS Sustainable Chem. Eng. 2019, 7, 14639–14646.

DOI Google Scholar

[34]

Chen, X. B.; Sheng, L.; Li, S. X.; Cui, Y.; Lin, T. R.; Que, X. Y.; Du, Z. H.; Zhang, Z. Y.; Peng, J.; Ma, H. L. et al. Facile syntheses and in-situ study on electrocatalytic properties of superaerophobic Co_xP-nanoarray in hydrogen evolution reaction. Chem. Eng. J. 2021, 426, 131029.

DOI Google Scholar

[35]

Yao, Y. L.; He, J. M.; Yang, X.; Peng, L.; Zhu, X. D.; Li, K. S.; Qu, M. N. Superhydrophilic/underwater superaerophobic self-supporting CuS/Cu foam electrode for efficient oxygen evolution reaction. Colloid. Surf. A Physicochem. Eng. Aspects 2022, 634, 127934.

DOI Google Scholar

[36]

Shen, J. J.; Li, B.; Zheng, Y.; Dai, Z. Y.; Li, J. L.; Bao, X. Z.; Guo, J. P.; Yu, X. Q.; Guo, Y. Z. et al. Engineering the composition and structure of superaerophobic nanosheet array for efficient hydrogen evolution. Chem. Eng. J. 2022, 433, 133517.

DOI Google Scholar

[37]

Yong, J. L.; Chen, F.; Fang, Y.; Huo, J. L.; Yang, Q. Z.; Zhang, J.; Bian, H.; Hou, X. Bioinspired design of underwater superaerophobic and superaerophilic surfaces by femtosecond laser ablation for anti- or capturing bubbles. ACS Appl. Mater. Interfaces 2017, 9, 39863–39871.

DOI Google Scholar

[38]

Quan, H. C.; Yang, W.; Lapeyriere, M.; Schaible, E.; Ritchie, R. O.; Meyers, M. A. Structure and mechanical adaptability of a modern elasmoid fish scale from the common carp. Matter 2020, 3, 842–863.

DOI Google Scholar

[39]

Liu, H. X.; Liu, X. J.; Mao, Z. Y.; Zhao, Z.; Peng, X. Y.; Luo, J.; Sun, X. M. Plasma-activated Co₃(PO₄)₂ nanosheet arrays with Co³⁺-rich surfaces for overall water splitting. J. Power Sources 2018, 400, 190–197.

DOI Google Scholar

[40]

Wang, M.; Zhang, W. J.; Zhang, F. F.; Zhang, Z. H.; Tang, B.; Li, J. P.; Wang, X. G. Theoretical expectation and experimental implementation of in situ Al-doped CoS₂ nanowires on dealloying-derived nanoporous intermetallic substrate as an efficient electrocatalyst for boosting hydrogen production. ACS Catal. 2019, 9, 1489–1502.

DOI Google Scholar

[41]

Waghmode, R. B.; Jadhav, H. S.; Kanade, K. G.; Torane, A. P. Morphology-controlled synthesis of NiCo₂O₄ nanoflowers on stainless steel substrates as high-performance supercapacitors. Mater. Sci. Energy Technol. 2019, 2, 556–564.

DOI Google Scholar

[42]

Lin, E. Z.; Huang, R.; Wu, J.; Kang, Z. H.; Ke, K. H.; Qin, N.; Bao, D. H. Recyclable CoFe₂O₄ modified BiOCl hierarchical microspheres utilizing photo, photothermal, and mechanical energy for organic pollutant degradation. Nano Energy 2021, 89, 106403.

DOI Google Scholar

[43]

Guo, R. N.; Qi, X. Y.; Zhang, X. Y.; Zhang, H. X.; Cheng, X. W. Synthesis of Ag₂CO₃/α-Fe₂O₃ heterojunction and it high visible light driven photocatalytic activity for elimination of organic pollutants. Sep. Purif. Technol. 2019, 211, 504–513.

DOI Google Scholar

[44]

Si, H. N.; Liao, Q. L.; Zhang, Z.; Li, Y.; Yang, X. H.; Zhang, G. J.; Kang, Z.; Zhang, Y. An innovative design of perovskite solar cells with Al₂O₃ inserting at ZnO/perovskite interface for improving the performance and stability. Nano Energy 2016, 22, 223–231.

DOI Google Scholar

[45]

Liu, Y.; Zhang, M. F.; Nie, Y.; Zhang, J.; Wang, J. Z. Growth of YAG: Ce³⁺-Al₂O₃ eutectic ceramic by HDS method and its application for white LEDs. J. Eur. Ceram. Soc. 2017, 37, 4931–4937.

DOI Google Scholar

[46]

Takahashi, K.; Imamura, M.; Hirama, K.; Kasu, M. Electronic states of NO_2-exposed H-terminated diamond/Al₂O₃ heterointerface studied by synchrotron radiation photoemission and X-ray absorption spectroscopy. Appl. Phys. Lett. 2014, 104, 072101.

DOI Google Scholar

[47]

Nakamura, S.; Yamamoto, A. Electrodeposition of pyrite (FeS₂) thin films for photovoltaic cells. Sol. Energy Mater. Sol. Cells 2001, 65, 79–85.

DOI Google Scholar

[48]

Cheng, N. Y.; Liu, Q.; Asiri, A. M.; Xing, W.; Sun, X. P. A Fe-doped Ni₃S₂ particle film as a high-efficiency robust oxygen evolution electrode with very high current density. J. Mater. Chem. A. 2015, 3, 23207–23212.

DOI Google Scholar

[49]

Guo, M. R.; Qayum, A.; Dong, S.; Jiao, X. L.; Chen, D. R.; Wang, T. In situ conversion of metal (Ni, Co, or Fe) foams into metal sulfide (Ni₃S₂, Co₉S₈, or FeS) foams with surface grown N-doped carbon nanotube arrays as efficient superaerophobic electrocatalysts for overall water splitting. J. Mater. Chem. A. 2020, 8, 9239–9247.

DOI Google Scholar

[50]

Gao, Y.; Mi, L. W.; Wei, W. T.; Cui, S. Z.; Zheng, Z.; Hou, H. W.; Chen, W. H. Double metal ions synergistic effect in hierarchical multiple sulfide microflowers for enhanced supercapacitor performance. ACS Appl. Mater. Interfaces 2015, 7, 4311–4319.

DOI Google Scholar

[51]

Cui, X. D.; Xie, Z. Q.; Wang, Y. Novel CoS₂ embedded carbon nanocages by direct sulfurizing metal-organic frameworks for dye-sensitized solar cells. Nanoscale 2016, 8, 11984–11992.

DOI Google Scholar

[52]

Shaat, S. K. K.; Swart, H. C.; Ntwaeaborwa, O. M. Tunable and white photoluminescence from Tb³⁺-Eu³⁺ activated Ca_0.3Sr_0.7Al₂O₄ phosphors and analysis of chemical states by X-ray photoelectron spectroscopy. J. Alloys Compd. 2014, 587, 600–605.

DOI Google Scholar

[53]

Andreu, N.; Flahaut, D.; Dedryvère, R.; Minvielle, M.; Martinez, H.; Gonbeau, D. XPS investigation of surface reactivity of electrode materials: Effect of the transition metal. ACS Appl. Mater. Interfaces 2015, 7, 6629–6636.

DOI Google Scholar

[54]

Mansour, A. N. Nickel monochromated Al Kα XPS spectra from the physical electronics model 5400 spectrometer. Surf. Sci. Spectra 1994, 3, 221–230.

DOI Google Scholar

[55]

Strydom, C. A.; Strydom, H. J. X-ray photoelectron spectroscopy studies of some cobalt(II) nitrate complexes. Inorg. Chim. Acta 1989, 159, 191–195.

DOI Google Scholar

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