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Nano Research 2023, 16(5): 6753-6770 https://doi.org/10.1007/s12274-022-5366-3
Review Article | Issue | Published: 19 February 2023

Recent progress in COF-based electrode materials for rechargeable metal-ion batteries

Show Author's Information Shunhang Wei1,§,  Jiwei Wang4,§,  Yuzhao Li5,  Zebo Fang1( ),  Lei Wang3( ),  Yuxi Xu2( )
Zhejiang Engineering Research Center of MEMS, Shaoxing University, Shaoxing 312000, China
School of Engineering, Westlake University, Hangzhou 310024, China
School of Mechatronics Engineering and Automation, Foshan University, Foshan 528225, China
Department of Chemistry, Binghamton University, Binghamton, New York 13902, USA
China Electronics Corporation, Beijing 100086, China

§ Shunhang Wei and Jiwei Wang contributed equally to this work.

Keywords:
electrochemical performance, structure–property relationship, covalent organic frameworks, synthetic methods, metal-ion batteries
Topics:
Ion batteries
Cite this article:
Wei S, Wang J, Li Y, et al. Recent progress in COF-based electrode materials for rechargeable metal-ion batteries. Nano Research, 2023, 16(5): 6753-6770. https://doi.org/10.1007/s12274-022-5366-3
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Abstract Full text About this article

Covalent organic frameworks (COFs) have emerged as promising electrode materials for rechargeable metal-ion batteries and have gained much attention in recent years due to their high specific surface area, inherent porosity, tunable molecular structure, robust framework, and abundant active sites. Moreover, compared with inorganic materials and small organic molecules, COFs have the advantages of multi-electron transfer, short pathways, and high cycling stability. Although great progress on COF-based electrodes has been made, the corresponding electrochemical performance is still far from satisfactory for practical applications. In this review, we first summarize the fundamental background of COFs, including the species of COFs (different active covalent bonds) and typical synthesis methods of COFs. Then, the key challenges and the latest research progress of COF-based cathodes and anodes for metal-ion batteries are reviewed, including Li-ion batteries, Na-ion batteries, K-ion batteries, Zn-ion batteries, et al. Moreover, the effective strategies to enhance electrochemical performance of COF-based electrodes are presented. Finally, this review also covers the typical superiorities of COFs used in energy devices, as well as providing some perspectives and outlooks in this field. We hope this review can provide fundamental guidance for the development of COF-based electrodes for metal-ion batteries in the further research.


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About this article

Recent progress in COF-based electrode materials for rechargeable metal-ion batteries

Show Author's information Shunhang Wei1,§, Jiwei Wang4,§, Yuzhao Li5, Zebo Fang1( ), Lei Wang3( ), Yuxi Xu2( )
Zhejiang Engineering Research Center of MEMS, Shaoxing University, Shaoxing 312000, China
School of Engineering, Westlake University, Hangzhou 310024, China
School of Mechatronics Engineering and Automation, Foshan University, Foshan 528225, China
Department of Chemistry, Binghamton University, Binghamton, New York 13902, USA
China Electronics Corporation, Beijing 100086, China

§ Shunhang Wei and Jiwei Wang contributed equally to this work.

Abstract

Covalent organic frameworks (COFs) have emerged as promising electrode materials for rechargeable metal-ion batteries and have gained much attention in recent years due to their high specific surface area, inherent porosity, tunable molecular structure, robust framework, and abundant active sites. Moreover, compared with inorganic materials and small organic molecules, COFs have the advantages of multi-electron transfer, short pathways, and high cycling stability. Although great progress on COF-based electrodes has been made, the corresponding electrochemical performance is still far from satisfactory for practical applications. In this review, we first summarize the fundamental background of COFs, including the species of COFs (different active covalent bonds) and typical synthesis methods of COFs. Then, the key challenges and the latest research progress of COF-based cathodes and anodes for metal-ion batteries are reviewed, including Li-ion batteries, Na-ion batteries, K-ion batteries, Zn-ion batteries, et al. Moreover, the effective strategies to enhance electrochemical performance of COF-based electrodes are presented. Finally, this review also covers the typical superiorities of COFs used in energy devices, as well as providing some perspectives and outlooks in this field. We hope this review can provide fundamental guidance for the development of COF-based electrodes for metal-ion batteries in the further research.

Keywords: electrochemical performance, structure–property relationship, covalent organic frameworks, synthetic methods, metal-ion batteries

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Publication history
Copyright
Acknowledgements

Publication history

Received: 09 October 2022
Revised: 07 November 2022
Accepted: 27 November 2022
Published: 19 February 2023
Issue date: May 2023

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 51872186), Project funded by China Postdoctoral Science Foundation (No. 2021M702316), and Guangdong Basic and Applied Basic Research Foundation (No. 2020A1515110999).

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