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Nano Research 2023, 16(5): 6552-6559 https://doi.org/10.1007/s12274-022-5322-2
Research Article | Issue | Published: 22 February 2023

High activity and stability in Ni2P/(Co,Ni)OOH heterointerface with a multiple-hierarchy structure for alkaline hydrogen evolution reaction

Show Author's Information LiLi Zhang1,2,  Zongpeng Wang2( ),  Jitang Zhang2,  Zhiping Lin2,  Qinghua Zhang3,  Wenwu Zhong2( ),  Guangfeng Wu1( )
College of Material Science and Engineering, Changchun University of Technology, Changchun 130051, China
Zhejiang Provincial Key Laboratory for Cutting Tools, Taizhou University, Jiaojiang 318000, China
Institution of Physics, Chinese Academic of Science, Beijing 100190, China
Keywords:
hierarchy, hydrogen evolution reaction, heterointerface, Ni2P/(Co,Ni)OOH
Topics:
Catalytic
Cite this article:
Zhang L, Wang Z, Zhang J, et al. High activity and stability in Ni2P/(Co,Ni)OOH heterointerface with a multiple-hierarchy structure for alkaline hydrogen evolution reaction. Nano Research, 2023, 16(5): 6552-6559. https://doi.org/10.1007/s12274-022-5322-2
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Abstract Full text Electronic supplementary material About this article

The fabrication of heterointerface materials with hierarchical morphologies more than two levels is a challenging yet promising approach to achieve optimal electrocatalyst for hydrogen evolution reaction (HER). Here, using a facile two-step method, we are able to prepare the Ni2P/(Co,Ni)OOH heterointerface with a three-level hierarchy morphology. The multiple levels of hierarchy structures not only offer considerable area for active sites loading, but also facilitate the substance transportation, both beneficial for HER. Meanwhile, the strong charge transfer at the Ni2P/(Co,Ni)OOH heterointerface eliminates the spin asymmetry and achieves the thermos-neutral adsorption of active H species. Moreover, the resulted Coulomb attraction stacks the two materials firmly, facilitating the stability. Density functional theory (DFT) and in-situ Raman measurements reveal the sufficient Ni atoms acting as the active sites. With these merits, the Ni2P/(Co,Ni)OOH exhibits much better HER activity than the separate Ni2P or (Co,Ni)OOH, affording a current density of 100 mA/cm2 at an overpotential of 169 mV and a Tafel slope of 41 mV/dec, when tested in alkaline electrolyte. This work provides inspiration for optimizing the intrinsic HER activity utilizing multiple-level hierarchy structures.


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Electronic supplementary material
About this article

High activity and stability in Ni2P/(Co,Ni)OOH heterointerface with a multiple-hierarchy structure for alkaline hydrogen evolution reaction

Show Author's information LiLi Zhang1,2, Zongpeng Wang2( ), Jitang Zhang2, Zhiping Lin2, Qinghua Zhang3, Wenwu Zhong2( ), Guangfeng Wu1( )
College of Material Science and Engineering, Changchun University of Technology, Changchun 130051, China
Zhejiang Provincial Key Laboratory for Cutting Tools, Taizhou University, Jiaojiang 318000, China
Institution of Physics, Chinese Academic of Science, Beijing 100190, China

Abstract

The fabrication of heterointerface materials with hierarchical morphologies more than two levels is a challenging yet promising approach to achieve optimal electrocatalyst for hydrogen evolution reaction (HER). Here, using a facile two-step method, we are able to prepare the Ni2P/(Co,Ni)OOH heterointerface with a three-level hierarchy morphology. The multiple levels of hierarchy structures not only offer considerable area for active sites loading, but also facilitate the substance transportation, both beneficial for HER. Meanwhile, the strong charge transfer at the Ni2P/(Co,Ni)OOH heterointerface eliminates the spin asymmetry and achieves the thermos-neutral adsorption of active H species. Moreover, the resulted Coulomb attraction stacks the two materials firmly, facilitating the stability. Density functional theory (DFT) and in-situ Raman measurements reveal the sufficient Ni atoms acting as the active sites. With these merits, the Ni2P/(Co,Ni)OOH exhibits much better HER activity than the separate Ni2P or (Co,Ni)OOH, affording a current density of 100 mA/cm2 at an overpotential of 169 mV and a Tafel slope of 41 mV/dec, when tested in alkaline electrolyte. This work provides inspiration for optimizing the intrinsic HER activity utilizing multiple-level hierarchy structures.

Keywords: hierarchy, hydrogen evolution reaction, heterointerface, Ni2P/(Co,Ni)OOH

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Publication history
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Acknowledgements

Publication history

Received: 25 September 2022
Revised: 07 November 2022
Accepted: 13 November 2022
Published: 22 February 2023
Issue date: May 2023

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This study was supported by the Major Research plan of the National Natural Science Foundation of China (No. 92163115), the National Natural Science Foundation (No. 52072255), the Science Fund for Distinguished Young Scholars of Zhejiang Province (No. LR22E020003), and the Natural Science Foundation of Zhejiang Province (Nos. LY21E020001 and LTY20E020001).

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