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Nano Research 2023, 16(3): 3781-3803 https://doi.org/10.1007/s12274-022-5147-z
Review Article | Issue | Published: 21 November 2022

Recent advances in modification strategies of silicon-based lithium-ion batteries

Show Author's Information Wenlei Wang,  Yu Wang,  Lixuan Yuan,  Chaolin You,  Junwei Wu,  Lili Liu,  Jilei Ye,  Yunling Wu( ),  Lijun Fu( )
State Key Laboratory of Materials-Oriented Chemical Engineering, School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China
Keywords:
silicon, lithium-ion batteries, silicon oxides, modification strategies
Topics:
Energy storage
Cite this article:
Wang W, Wang Y, Yuan L, et al. Recent advances in modification strategies of silicon-based lithium-ion batteries. Nano Research, 2023, 16(3): 3781-3803. https://doi.org/10.1007/s12274-022-5147-z
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Abstract Full text About this article

As potential alternatives to graphite, silicon (Si) and silicon oxides (SiOx) received a lot of attention as anode materials for lithium-ion batteries owing to their relatively low working potentials, high theoretical specific capacities, and abundant resources. However, the commercialization of Si-based anodes is greatly hindered by their massive volume expansion, low conductivity, unstable solid electrolyte interface (SEI), and low initial Coulombic efficiency (ICE). Continuous endeavors have been devoted to overcoming these challenges to achieve practical usage. This review is centered on the major challenges and latest developments in the modification strategies of Si-based anodes, including structure optimization, surface/interface regulation, novel binders, and innovative design of electrolyte. Finally, outlooks and perspectives of Si-based anodes for future development are presented.


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About this article

Recent advances in modification strategies of silicon-based lithium-ion batteries

Show Author's information Wenlei Wang, Yu Wang, Lixuan Yuan, Chaolin You, Junwei Wu, Lili Liu, Jilei Ye, Yunling Wu( ), Lijun Fu( )
State Key Laboratory of Materials-Oriented Chemical Engineering, School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China

Abstract

As potential alternatives to graphite, silicon (Si) and silicon oxides (SiOx) received a lot of attention as anode materials for lithium-ion batteries owing to their relatively low working potentials, high theoretical specific capacities, and abundant resources. However, the commercialization of Si-based anodes is greatly hindered by their massive volume expansion, low conductivity, unstable solid electrolyte interface (SEI), and low initial Coulombic efficiency (ICE). Continuous endeavors have been devoted to overcoming these challenges to achieve practical usage. This review is centered on the major challenges and latest developments in the modification strategies of Si-based anodes, including structure optimization, surface/interface regulation, novel binders, and innovative design of electrolyte. Finally, outlooks and perspectives of Si-based anodes for future development are presented.

Keywords: silicon, lithium-ion batteries, silicon oxides, modification strategies

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Publication history
Copyright
Acknowledgements

Publication history

Received: 11 July 2022
Revised: 23 September 2022
Accepted: 06 October 2022
Published: 21 November 2022
Issue date: March 2023

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 52122209, 52111530050, and 51772147), Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. SJCX22_0433), and the Research Foundation of State Key Lab (Nos. ZK201906 and ZK201805).

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