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Nano Research 2023, 16(4): 5880-5886 https://doi.org/10.1007/s12274-022-5118-4
Research Article | Issue | Published: 24 October 2022

Atomic Pt anchored on hierarchically porous monolithic carbon nanowires as high-performance catalyst for liquid hydrogenation

Show Author's Information Zhengbin Tian1,2,  Xiaohui Deng1,  Ping He1,  Guang-Hui Wang1,2( )
Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
University of Chinese Academy of Sciences, 100049 Beijing, China
Keywords:
hydrogenation, dual-templating strategy, monolithic catalysts, porous carbon nanowires, Pt single atoms
Topics:
Structural design
Cite this article:
Tian Z, Deng X, He P, et al. Atomic Pt anchored on hierarchically porous monolithic carbon nanowires as high-performance catalyst for liquid hydrogenation. Nano Research, 2023, 16(4): 5880-5886. https://doi.org/10.1007/s12274-022-5118-4
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Abstract Full text Electronic supplementary material About this article

Monolithic catalysts play a crucial role in various catalytic applications, e.g., chemical synthesis, energy conversion, and environmental treatment, but their catalytic efficiency is often limited by the restricted mass transfer and insufficient exposure of active sites. Herein, we present a dual-templating strategy to fabricate atomic Pt dispersed on monolithic N-doped mesoporous carbon nanowires (Pt1/NMCW) with abundant super-/macropores, which, as monolithic catalyst, exhibits high catalytic performance in hydrogenation of 4-nitrophenol (4-NP). During synthesis, triblock copolymer (Pluronic F127) is employed as a primary soft template to generate the mesoporous structured carbon nanowires to improve the accessibility of Pt single sites; KCl crystallite is used as a secondary hard template to create the super-/macropores, which are beneficial for enhancing the mass transfer efficiency. Thanks to the dual-templating strategy that creates the monolithic carbon nanowires with hierarchically porous structure, the obtained Pt1/NMCW shows highly enhanced catalytic activity in 4-NP hydrogenation, outperforming its analogue synthesized without using KCl as template and being comparable to the nano-powder catalyst (i.e., atomic Pt loaded on the N-doped carbon nanospheres, Pt1/NCS).


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Electronic supplementary material
About this article

Atomic Pt anchored on hierarchically porous monolithic carbon nanowires as high-performance catalyst for liquid hydrogenation

Show Author's information Zhengbin Tian1,2, Xiaohui Deng1, Ping He1, Guang-Hui Wang1,2( )
Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
University of Chinese Academy of Sciences, 100049 Beijing, China

Abstract

Monolithic catalysts play a crucial role in various catalytic applications, e.g., chemical synthesis, energy conversion, and environmental treatment, but their catalytic efficiency is often limited by the restricted mass transfer and insufficient exposure of active sites. Herein, we present a dual-templating strategy to fabricate atomic Pt dispersed on monolithic N-doped mesoporous carbon nanowires (Pt1/NMCW) with abundant super-/macropores, which, as monolithic catalyst, exhibits high catalytic performance in hydrogenation of 4-nitrophenol (4-NP). During synthesis, triblock copolymer (Pluronic F127) is employed as a primary soft template to generate the mesoporous structured carbon nanowires to improve the accessibility of Pt single sites; KCl crystallite is used as a secondary hard template to create the super-/macropores, which are beneficial for enhancing the mass transfer efficiency. Thanks to the dual-templating strategy that creates the monolithic carbon nanowires with hierarchically porous structure, the obtained Pt1/NMCW shows highly enhanced catalytic activity in 4-NP hydrogenation, outperforming its analogue synthesized without using KCl as template and being comparable to the nano-powder catalyst (i.e., atomic Pt loaded on the N-doped carbon nanospheres, Pt1/NCS).

Keywords: hydrogenation, dual-templating strategy, monolithic catalysts, porous carbon nanowires, Pt single atoms

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Publication history
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Acknowledgements

Publication history

Received: 11 July 2022
Revised: 28 September 2022
Accepted: 29 September 2022
Published: 24 October 2022
Issue date: April 2023

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21872159), SEI (No. SEI I202134), and QIBEBT (No. QIBEBT ZZBS201802).

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