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Nano Research 2023, 16(6): 8345-8353 https://doi.org/10.1007/s12274-022-5089-5
Research Article | Issue | Published: 01 November 2022

In situ formed synaptic Zn@LiZn host derived from ZnO nanofiber decorated Zn foam for dendrite-free lithium metal anode

Show Author's Information Jian Bao1,  Hai-Juan Pei2,  Xin-Yang Yue3,  Xun-Lu Li1,  Cui Ma1,  Rui-Jie Luo1,  Chong-Yu Du1,  Yong-Ning Zhou1( )
Department of Materials Science, Fudan University, Shanghai 200433, China
State Key Laboratory of Space Power-Sources Technology, Shanghai Institute of Space Power-Sources, Shanghai 200245, China
Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
Keywords:
Li metal, anode, lithium batteries, thermal infusion, LiZn alloy
Topics:
Lithium batteries
Cite this article:
Bao J, Pei H-J, Yue X-Y, et al. In situ formed synaptic Zn@LiZn host derived from ZnO nanofiber decorated Zn foam for dendrite-free lithium metal anode. Nano Research, 2023, 16(6): 8345-8353. https://doi.org/10.1007/s12274-022-5089-5
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Abstract Full text Electronic supplementary material About this article

Lithium metal is regarded as the most promising anode material for next generation high energy density lithium batteries due to its high theoretical capacity and lowest potential versus standard hydrogen electrode. However, lithium dendrite growth and huge volume change during cycling hinder its practical application. It is of great importance to design advanced Li metal anodes to solve these problems. Herein, we report a ZnO-coated Zn foam as the host matrix to pre-store lithium through thermal infusing, achieving a Zn@ZnO foam supported Li composite electrode (LZO). Needlelike ZnO nanofibers grown on the Zn foam greatly increase the surface area and enhance the lithiophilicity of the Zn foam. In situ formed synaptic LiZn layer after lithium infusion can disperse local current density and lower Li diffusion barrier effectively, leading to homogeneous Li deposition behavior, thus suppressing dendrite formation. The porous Zn foam skeleton can accommodate volume variation of the electrode during long-term cycling. Benefiting from these merits, the LZO anode exhibits much better cycle stability and rate capability in both symmetrical and full cells with low voltage hysteresis than the bare Li anode. This work opens a new opportunity in designing high performance composite Li anode for lithium-metal batteries.


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Electronic supplementary material
About this article

In situ formed synaptic Zn@LiZn host derived from ZnO nanofiber decorated Zn foam for dendrite-free lithium metal anode

Show Author's information Jian Bao1, Hai-Juan Pei2, Xin-Yang Yue3, Xun-Lu Li1, Cui Ma1, Rui-Jie Luo1, Chong-Yu Du1, Yong-Ning Zhou1( )
Department of Materials Science, Fudan University, Shanghai 200433, China
State Key Laboratory of Space Power-Sources Technology, Shanghai Institute of Space Power-Sources, Shanghai 200245, China
Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Abstract

Lithium metal is regarded as the most promising anode material for next generation high energy density lithium batteries due to its high theoretical capacity and lowest potential versus standard hydrogen electrode. However, lithium dendrite growth and huge volume change during cycling hinder its practical application. It is of great importance to design advanced Li metal anodes to solve these problems. Herein, we report a ZnO-coated Zn foam as the host matrix to pre-store lithium through thermal infusing, achieving a Zn@ZnO foam supported Li composite electrode (LZO). Needlelike ZnO nanofibers grown on the Zn foam greatly increase the surface area and enhance the lithiophilicity of the Zn foam. In situ formed synaptic LiZn layer after lithium infusion can disperse local current density and lower Li diffusion barrier effectively, leading to homogeneous Li deposition behavior, thus suppressing dendrite formation. The porous Zn foam skeleton can accommodate volume variation of the electrode during long-term cycling. Benefiting from these merits, the LZO anode exhibits much better cycle stability and rate capability in both symmetrical and full cells with low voltage hysteresis than the bare Li anode. This work opens a new opportunity in designing high performance composite Li anode for lithium-metal batteries.

Keywords: Li metal, anode, lithium batteries, thermal infusion, LiZn alloy

References(36)

[1]

Armand, M.; Tarascon, J. M. Building better batteries. Nature 2008, 451, 652–657.
DOI Google Scholar
[2]

Guo, Y. P.; Li, H. Q.; Zhai, T. Y. Reviving lithium-metal anodes for next-generation high-energy batteries. Adv. Mater. 2017, 29, 1700007.
DOI Google Scholar
[3]

He, P.; Zhang, T.; Jiang, J.; Zhou, H. S. Lithium-air batteries with hybrid electrolytes. J. Phys. Chem. Lett. 2016, 7, 1267–1280.
DOI Google Scholar
[4]

Cheng, X. B.; Zhang, R.; Zhao, C. Z.; Zhang, Q. Toward safe lithium metal anode in rechargeable batteries: A review. Chem. Rev. 2017, 117, 10403–10473.
DOI Google Scholar
[5]

Tarascon, J. M.; Armand, M. Issues and challenges facing rechargeable lithium batteries. Nature 2001, 414, 359–367.
DOI Google Scholar
[6]

Aurbach, D.; Zinigrad, E.; Cohen, Y.; Teller, H. A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions. Solid State Ion. 2002, 148, 405–416.
DOI Google Scholar
[7]

Tao, R.; Bi, X. X.; Li, S.; Yao, Y.; Wu, F.; Wang, Q.; Zhang, C. Z.; Lu, J. Kinetics tuning the electrochemistry of lithium dendrites formation in lithium batteries through electrolytes. ACS Appl. Mater. Interfaces 2017, 9, 7003–7008.
DOI Google Scholar
[8]

Chen, R. J.; Qu, W. J.; Guo, X.; Li, L.; Wu, F. The pursuit of solid-state electrolytes for lithium batteries: From comprehensive insight to emerging horizons. Mater. Horiz. 2016, 3, 487–516.
DOI Google Scholar
[9]

Janek, J.; Zeier, W. G. A solid future for battery development. Nat. Energy 2016, 1, 16141.
DOI Google Scholar
[10]

Shi, L.; Xu, A.; Zhao, T. S. First-principles investigations of the working mechanism of 2D h-BN as an interfacial layer for the anode of lithium metal batteries. ACS Appl. Mater. Interfaces 2017, 9, 1987–1994.
DOI Google Scholar
[11]

Zhang, J. F.; Su, Y. P.; Zhang, Y. G. Recent advances in research on anodes for safe and efficient lithium-metal batteries. Nanoscale 2020, 12, 15528–15559.
DOI Google Scholar
[12]

Zhang, R.; Li, N. W.; Cheng, X. B.; Yin, Y. X.; Zhang, Q.; Guo, Y. G. Advanced micro/nanostructures for lithium metal anodes. Adv. Sci. 2017, 4, 1600445.
DOI Google Scholar
[13]

Liu, Y. Y.; Lin, D. C.; Liang, Z.; Zhao, J.; Yan, K.; Cui, Y. Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode. Nat. Commun. 2016, 7, 10992.
DOI Google Scholar
[14]

Lin, D. C.; Liu, Y. Y.; Liang, Z.; Lee, H. W.; Sun, J.; Wang, H. T.; Yan, K.; Xie, J.; Cui, Y. Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes. Nat. Nanotechnol. 2016, 11, 626–632.
DOI Google Scholar
[15]

Deng, W.; Zhu, W. H.; Zhou, X. F.; Liu, Z. P. Graphene nested porous carbon current collector for lithium metal anode with ultrahigh areal capacity. Energy Storage Mater. 2018, 15, 266–273.
DOI Google Scholar
[16]

Yue, X. Y.; Wang, W. W.; Wang, Q. C.; Meng, J. K.; Zhang, Z. Q.; Wu, X. J.; Yang, X. Q.; Zhou, Y. N. CoO nanofiber decorated nickel foams as lithium dendrite suppressing host skeletons for high energy lithium metal batteries. Energy Storage Mater. 2018, 14, 335–344.
DOI Google Scholar
[17]

Qiu, H. L.; Tang, T. Y.; Asif, M.; Huang, X. X.; Hou, Y. L. 3D porous Cu current collectors derived by hydrogen bubble dynamic template for enhanced Li metal anode performance. Adv. Funct. Mater. 2019, 29, 1808468.
DOI Google Scholar
[18]

Chen, C.; Yang, Y. F.; Shao, H. X. Enhancement of the lithium cycling capability using Li-Zn alloy substrate for lithium metal batteries. Electrochim. Acta 2014, 137, 476–483.
DOI Google Scholar
[19]

Liang, Y; Cao, S; Wei, Q. L.; Zeng, R. S.; Zhao, J. L.; Li, H. Z.; Yu, W. W.; Zou, B. S. Reversible Zn2+ insertion in tungsten ion-activated titanium dioxide nanocrystals for electrochromic windows. Nano-Micro Lett. 2021, 13, 196.
DOI Google Scholar
[20]

Wang, G.; Xiong, X. H.; Zou, P. J.; Fu, X. X.; Lin, Z. H.; Li, Y. P.; Liu, Y. Z.; Yang, C. H.; Liu, M. L. Lithiated zinc oxide nanorod arrays on copper current collectors for robust Li metal anodes. Chem. Eng. J. 2019, 378, 122243.
DOI Google Scholar
[21]

Chi, S. S.; Wang, Q. R.; Han, B.; Luo, C.; Jiang, Y. D.; Wang, J.; Wang, C. Y.; Yu, Y.; Deng, Y. H. Lithiophilic Zn sites in porous CuZn alloy induced uniform Li nucleation and dendrite-free Li metal deposition. Nano Lett. 2020, 20, 2724–2732.
DOI Google Scholar
[22]

Ye, Y.; Liu, Y. T.; Wu, J. L.; Yang, Y. F. Lithiophilic Li-Zn alloy modified 3D Cu foam for dendrite-free lithium metal anode. J. Power Sources 2020, 472, 228520.
DOI Google Scholar
[23]

Yue, X. Y.; Bao, J.; Yang, S. Y.; Luo, R. J.; Wang, Q. C.; Wu, X. J.; Shadike, Z.; Yang, X. Q.; Zhou, Y. N. Petaloid-shaped ZnO coated carbon felt as a controllable host to construct hierarchical Li composite anode. Nano Energy 2020, 71, 104614.
DOI Google Scholar
[24]

Liu, T. C.; Chen, S. Q.; Sun, W. W.; Lv, L. P.; Du, F. H.; Liu, H.; Wang, Y. Lithiophilic vertical cactus-like framework derived from Cu/Zn-based coordination polymer through in situ chemical etching for stable lithium metal batteries. Adv. Funct. Mater. 2021, 31, 2008514.
DOI Google Scholar
[25]

Sharma, Y.; Sharma, N.; Subbarao, G.; Chowdari, B. Studies on spinel cobaltites, FeCo2O4 and MgCo2O4 as anodes for Li-ion batteries. Solid State Ion. 2008, 179, 587–597.
DOI Google Scholar
[26]

Zhai, N. S.; Li, M. W.; Wang, W. L.; Zhang, D. L.; Xu, D. G. The application of the EIS in Li-ion batteries measurement. J. Phys. Conf. Ser. 2006, 48, 1157–1161.
DOI Google Scholar
[27]

Wang, S. H.; Yue, J. P.; Dong, W.; Zuo, T. T.; Li, J. Y.; Liu, X. L.; Zhang, X. D.; Liu, L.; Shi, J. L.; Yin, Y. X. et al. Tuning wettability of molten lithium via a chemical strategy for lithium metal anodes. Nat. Commun. 2019, 10, 4930.
DOI Google Scholar
[28]

Wang, J. Y.; Wang, H. S.; Xie, J.; Yang, A. K.; Pei, A.; Wu, C. L.; Shi, F. F.; Liu, Y. Y.; Lin, D. C.; Gong, Y. J. et al. Fundamental study on the wetting property of liquid lithium. Energy Storage Mater. 2018, 14, 345–350.
DOI Google Scholar
[29]

Barton, J. L.; Bockris, J. O. The electrolytic growth of dendrites from ionic solutions. Proc. Roy. Soc. A Math. Phys. Eng. Sci. 1962, 268, 485–505.
DOI Google Scholar
[30]

Liu, S. F.; Xia, X. H.; Deng, S. J.; Xie, D.; Yao, Z. J.; Zhang, L. Y.; Zhang, S. Z.; Wang, X. L.; Tu, J. P. In situ solid electrolyte interphase from spray quenching on molten Li: A new way to construct high-performance lithium-metal anodes. Adv. Mater. 2019, 31, 1806470.
DOI Google Scholar
[31]

Li, N. W.; Yin, Y. X.; Yang, C. P.; Guo, Y. G. An artificial solid electrolyte interphase layer for stable lithium metal anodes. Adv. Mater. 2016, 28, 1853–1858.
DOI Google Scholar
[32]

Ding, F.; Xu, W.; Chen, X. L.; Zhang, J.; Engelhard, M. H.; Zhang, Y. H.; Johnson, B. R.; Crum, J. V.; Blake, T. A.; Liu, X. et al. Effects of carbonate solvents and lithium salts on morphology and Coulombic efficiency of lithium electrode. J. Electrochem. Soc. 2013, 160, A1894–A1901.
DOI Google Scholar
[33]

Chang, S. Z.; Jin, X.; He, Q. Y.; Liu, T. C.; Fang, J. B.; Shen, Z. H.; Li, Z. H.; Zhang, S.; Dahbi, M.; Alami, J. et al. In situ formation of polycyclic aromatic hydrocarbons as an artificial hybrid layer for lithium metal anodes. Nano Lett. 2022, 22, 263–270.
DOI Google Scholar
[34]

Zhao, Q.; Stalin, S.; Archer, L. A. Stabilizing metal battery anodes through the design of solid electrolyte interphases. Joule 2021, 5, 1119–1142.
DOI Google Scholar
[35]

Shrestha, N. K.; Hahn, R.; Lee, K.; Tighineanu, A.; Schmuki, P. Electrochemically assisted self-assembling of ZnF2-ZnO nanospheres: Formation of hierarchical thin porous films. ECS Electrochem. Lett. 2013, 3, E1–E3.
DOI Google Scholar
[36]

Contarini, S.; Rabalais, J. W. Ion bombardment-induced decomposition of Li and Ba sulfates and carbonates studied by X-ray photoelectron spectroscopy. J. Electron Spectrosc. Relat. Phenom. 1985, 35, 191–201.
DOI Google Scholar
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Publication history
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Acknowledgements

Publication history

Received: 08 August 2022
Revised: 13 September 2022
Accepted: 22 September 2022
Published: 01 November 2022
Issue date: June 2023

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

The work was supported by the National Natural Science Foundation of China (No. 52071085) and Shanghai Aerospace Science and Technology Innovation Fund (No. SAST2020-102). The authors thank beamline BL02U02 at Shanghai Synchrotron Radiation Facility (SSRF) for XRD measurements.

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