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Polymerization is a valid strategy to solve the dissolution issue of organic electrode materials in aprotic electrolytes. However, conventional polymers usually with amorphous structures and morphology’s influence on electrochemistry have rarely been studied. Herein, a hollow tubular poly phenyl pyrene-4,5,9,10-tetraone (T-PPh-PTO) organic cathode material was designed and synthesized based on the concentration-gradient of the precursor (PTO-Br2) and asymmetrical internal diffusion during the reaction. The unique hollow structure endowed T-PPh-PTO with a short Li+ diffusion path accompanied by a high diffusion coefficient (D
This study was supported by the National Natural Science Foundation of China (Nos. 51771094 and 21835004), the National Key Research and Development (R&D) Program of China (No. 2016YFB0901500), the Ministry of Education of China (No. B12015), and Tianjin Natural Science Foundation (No. 18JCZDJC31500).