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Nano Research 2023, 16(2): 2428-2435 https://doi.org/10.1007/s12274-022-4980-4
Research Article | Issue | Published: 27 September 2022

Porous needle-like Fe-Ni-P doped with Ru as efficient electrocatalyst for hydrogen generation powered by sustainable energies

Show Author's Information Yue Wang1,§,  Zhi Chen1,§,  Qichang Li1,  Xinping Wang1,  Weiping Xiao2,  Yunlei Fu3,  Guangrui Xu4,  Bin Li4,  Zhenjiang Li4,  Zexing Wu1( ),  Lei Wang1,3( )
Key Laboratory of Eco-chemical Engineering, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
College of Science, Nanjing Forestry University, Nanjing 210037, China
Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection, College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266061, China

§ Yue Wang and Zhi Chen contributed equally to this work.

Keywords:
hydrogen generation, overall water splitting, metal phosphide, needle-like morphology
Topics:
Energy
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Wang Y, Chen Z, Li Q, et al. Porous needle-like Fe-Ni-P doped with Ru as efficient electrocatalyst for hydrogen generation powered by sustainable energies. Nano Research, 2023, 16(2): 2428-2435. https://doi.org/10.1007/s12274-022-4980-4
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Abstract Full text Electronic supplementary material About this article

Electrocatalytic water electrolysis, involving hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), two half-reactions, is an eco-friendly approach toward hydrogen production. In this work, needle-like Ru-Fe-Ni-P on NiFe foam is prepared through corrosive engineering and following a low-temperature phosphorization procedure for overall water-splitting. The as-designed Ru-Fe-Ni-P exhibits a porous needle-like structure, surface, and binder-free merits, and then can expose rich active sites, favor the transportation of mass/electron, and accelerate the reaction kinetics during catalytic process. Then, the synthesized Ru-Fe-Ni-P owns remarkable catalytic performance for HER, with 18 and 67 mV to reach 10 mA·cm−2 in alkaline and neutral media. Moreover, a low cell voltage of 1.51 V is required to produce a current of 10 mA·cm−2 in a two electrode electrolyzer with excellent stability. Interestingly, sustainable energies can power the electrolyzer effectively with abundant hydrogen generation.


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Abstract
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Electronic supplementary material
About this article

Porous needle-like Fe-Ni-P doped with Ru as efficient electrocatalyst for hydrogen generation powered by sustainable energies

Show Author's information Yue Wang1,§, Zhi Chen1,§, Qichang Li1, Xinping Wang1, Weiping Xiao2, Yunlei Fu3, Guangrui Xu4, Bin Li4, Zhenjiang Li4, Zexing Wu1( ), Lei Wang1,3( )
Key Laboratory of Eco-chemical Engineering, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
College of Science, Nanjing Forestry University, Nanjing 210037, China
Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection, College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266061, China

§ Yue Wang and Zhi Chen contributed equally to this work.

Abstract

Electrocatalytic water electrolysis, involving hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), two half-reactions, is an eco-friendly approach toward hydrogen production. In this work, needle-like Ru-Fe-Ni-P on NiFe foam is prepared through corrosive engineering and following a low-temperature phosphorization procedure for overall water-splitting. The as-designed Ru-Fe-Ni-P exhibits a porous needle-like structure, surface, and binder-free merits, and then can expose rich active sites, favor the transportation of mass/electron, and accelerate the reaction kinetics during catalytic process. Then, the synthesized Ru-Fe-Ni-P owns remarkable catalytic performance for HER, with 18 and 67 mV to reach 10 mA·cm−2 in alkaline and neutral media. Moreover, a low cell voltage of 1.51 V is required to produce a current of 10 mA·cm−2 in a two electrode electrolyzer with excellent stability. Interestingly, sustainable energies can power the electrolyzer effectively with abundant hydrogen generation.

Keywords: hydrogen generation, overall water splitting, metal phosphide, needle-like morphology

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Publication history
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Acknowledgements

Publication history

Received: 15 June 2022
Revised: 30 July 2022
Accepted: 28 August 2022
Published: 27 September 2022
Issue date: February 2023

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

The authors acknowledge funding support from the National Natural Science Foundation of China (Nos. 22002068, 21971132, 51772162, and 52072197), a project funded by China Postdoctoral Science Foundation (No. 2021M691700), Youth Innovation and Technology Foundation of Shandong Higher Education Institutions, China (No. 2019KJC004), Outstanding Youth Foundation of Shandong Province, China (No. ZR2019JQ14), Taishan Scholar Young Talent Program (No. tsqn201909114), Major Scientific and Technological Innovation Project (No. 2019JZZY020405), Major Basic Research Program of Natural Science Foundation of Shandong Province (No. ZR2020ZD09), the Natural Science Foundation of Shandong Province of China (Nos. ZR2019BB002 and ZR2018BB031), and Talent Foundation funded by Province and Ministry Co-construction Collaborative Innovation Center of Eco-chemical Engineering (No. STHGYX2202).

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