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Review Article

Advances in electrolyte safety and stability of ion batteries under extreme conditions

Zhuo Chen1, Keliang Wang1,2( ), Pucheng Pei2, Yayu Zuo1, Manhui Wei1, Hengwei Wang1, Pengfei Zhang1, Nuo Shang1
School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China
State Key Lab. of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China
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Abstract

Electric vehicles have been promoted worldwide due to fast-charge technology of ion batteries. However, ion batteries’ capacity and cycle life severely decay under extreme conditions, which is mostly related to electrolyte conductivity drop and side reactions. This review highlights the safety and stability of ion batteries in terms of thermal stability, non-flammability, low-temperature, and so on, outlining the disadvantages of organic liquid electrolyte, and summarizing effective solutions of polymer electrolytes, solid-state electrolytes, ionic liquid electrolytes, and aqueous electrolytes for the batteries. Moreover, the outlook on the electrolytes is put forward, which is available for research and development of the next generation batteries.

Graphical Abstract

Facing increasingly complex application scenarios, the safety and stability of electrolytes under extreme conditions are becoming more critical. This review summarizes the research progress of the safety and stability of several electrolytes under extreme conditions, and puts out an outlook for future electrolyte development.

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Nano Research
Pages 2311-2324

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Review Status: {{reviewData.commendedNum}} Commended , {{reviewData.revisionRequiredNum}} Revision Required , {{reviewData.notCommendedNum}} Not Commended Under Peer Review

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Cite this article:
Chen Z, Wang K, Pei P, et al. Advances in electrolyte safety and stability of ion batteries under extreme conditions. Nano Research, 2023, 16(2): 2311-2324. https://doi.org/10.1007/s12274-022-4871-x
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Received: 18 July 2022
Revised: 03 August 2022
Accepted: 05 August 2022
Published: 06 September 2022
© Tsinghua University Press 2022