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Nano Research 2022, 15(10): 8922-8927 https://doi.org/10.1007/s12274-022-4869-2
Research Article | Issue | Published: 19 August 2022

N, O-doped carbon foam as metal-free electrocatalyst for efficient hydrogen production from seawater

Show Author's Information Qian Liu1,  Shengjun Sun2,  Longcheng Zhang2,  Yongsong Luo2,  Qin Yang2,  Kai Dong2,  Xiaodong Fang1,  Dongdong Zheng2,  Abdulmohsen Ali Alshehri3,  Xuping Sun2,4( )
Institute for Advanced Study, Chengdu University, Chengdu 610106, China
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China
Keywords:
electrocatalyst, hydrogen evolution reaction, carbon foam, seawater electrolysis
Topics:
Nanocatalysts
Cite this article:
Liu Q, Sun S, Zhang L, et al. N, O-doped carbon foam as metal-free electrocatalyst for efficient hydrogen production from seawater. Nano Research, 2022, 15(10): 8922-8927. https://doi.org/10.1007/s12274-022-4869-2
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Abstract Full text Electronic supplementary material About this article

Seawater electrolysis is the most promising technology for large scale hydrogen production due to the abundance and low cost of seawater in nature. However, compared with the traditional freshwater electrolysis, the issues of electrode poisoning and corrosion will occur during the seawater electrolysis process, and active and stable electrocatalysts for the hydrogen evolution reaction (HER) are thus highly desired. In this work, N, O-doped carbon foam in-situ derived from commercial melamine foam is proposed as a high-active metal-free HER electrocatalyst for seawater splitting. In acidic seawater, our catalyst shows high hydrogen generation performance with small overpotential of 161 mV at 10 mA·cm−2, a low Tafel slop of 97.5 mV·dec−1, and outstanding stability.


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About this article

N, O-doped carbon foam as metal-free electrocatalyst for efficient hydrogen production from seawater

Show Author's information Qian Liu1, Shengjun Sun2, Longcheng Zhang2, Yongsong Luo2, Qin Yang2, Kai Dong2, Xiaodong Fang1, Dongdong Zheng2, Abdulmohsen Ali Alshehri3, Xuping Sun2,4( )
Institute for Advanced Study, Chengdu University, Chengdu 610106, China
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China

Abstract

Seawater electrolysis is the most promising technology for large scale hydrogen production due to the abundance and low cost of seawater in nature. However, compared with the traditional freshwater electrolysis, the issues of electrode poisoning and corrosion will occur during the seawater electrolysis process, and active and stable electrocatalysts for the hydrogen evolution reaction (HER) are thus highly desired. In this work, N, O-doped carbon foam in-situ derived from commercial melamine foam is proposed as a high-active metal-free HER electrocatalyst for seawater splitting. In acidic seawater, our catalyst shows high hydrogen generation performance with small overpotential of 161 mV at 10 mA·cm−2, a low Tafel slop of 97.5 mV·dec−1, and outstanding stability.

Keywords: electrocatalyst, hydrogen evolution reaction, carbon foam, seawater electrolysis

References(37)

1

Xu, S. R.; Zhao, H. T.; Li, T. S.; Liang, J.; Lu, S. Y.; Chen, G.; Gao, S. Y.; Asiri, A. M.; Wu, Q.; Sun, X. P. Iron-based phosphides as electrocatalysts for the hydrogen evolution reaction: Recent advances and future prospects. J. Mater. Chem. A 2020, 8, 19729–19745.
DOI Google Scholar
2

Sun, F.; Qin, J. S.; Wang, Z. Y.; Yu, M. Z.; Wu, X. H.; Sun, X. M.; Qiu, J. S. Energy-saving hydrogen production by chlorine-free hybrid seawater splitting coupling hydrazine degradation. Nat. Commun. 2021, 12, 4182.
DOI Google Scholar
3

Wang, J. H.; Cui, W.; Liu, Q.; Xing, Z. C.; Asiri, A. M.; Sun, X. Recent progress in cobalt-based heterogeneous catalysts for electrochemical water splitting. Adv. Mater. 2016, 28, 215–230.
DOI Google Scholar
4

Chen, S.; Duan, J. J.; Jaroniec, M.; Qiao, S. Z. Three-dimensional N-doped graphene hydrogel/NiCo double hydroxide electrocatalysts for highly efficient oxygen evolution. Angew. Chem., Int. Ed. 2013, 52, 13567–13570.
DOI Google Scholar
5

Ye, C.; Zhang, L. C.; Yue, L. C.; Deng, B.; Cao, Y.; Liu, Q.; Luo, Y. L.; Lu, S. Y.; Zheng, B. Z.; Sun, X. P. A NiCo LDH nanosheet array on graphite felt: An efficient 3D electrocatalyst for the oxygen evolution reaction in alkaline media. Inorg. Chem. Front. 2021, 8, 3162–3166.
DOI Google Scholar
6

Shan, J. Q.; Zheng, Y.; Shi, B. Y.; Davey, K.; Qiao, S. Z. Regulating electrocatalysts via surface and interface engineering for acidic water electrooxidation. ACS Energy Lett. 2019, 4, 2719–2730.
DOI Google Scholar
7

Meng, C. Q.; Cao, Y.; Luo, Y. L.; Zhang, F.; Kong, Q. Q.; Alshehri, A. A.; Alzahrani, K. A.; Li, T. S.; Liu, Q.; Sun, X. P. A Ni-MOF nanosheet array for efficient oxygen evolution electrocatalysis in alkaline media. Inorg. Chem. Front. 2021, 8, 3007–3011.
DOI Google Scholar
8

Xiu, L.; Pei, W.; Zhou, S.; Wang, Z. Y.; Yang, P. J.; Zhao, J. J.; Qiu, J. S. Multilevel hollow MXene tailored low-Pt catalyst for efficient hydrogen evolution in full-pH range and seawater. Adv. Funct. Mater. 2020, 30, 1910028.
DOI Google Scholar
9

Schmidt, O.; Gambhir, A.; Staffell, I.; Hawkes, A.; Nelson, J.; Few, S. Future cost and performance of water electrolysis: An expert elicitation study. Int. J. Hydrogen Energy 2017, 42, 30470–30492.
DOI Google Scholar
10
Platzer, M. F.; Sarigul-Klijn, N. Hydrogen production methods. In The Green Energy Ship Concept: Renewable Energy from Wind Over Water. Platzer, M. F.; Sarigul-Klijn, N., Eds.; Springer: Cham, 2021; pp 59–62.
11
Zhang, L.; Liang, J.; Yue, L.; Dong, K.; Li, J.; Zhao, D.; Li, Z.; Sun, S.; Luo, Y.; Liu, Q. et al. Benzoate anions-intercalated NiFe-layered double hydroxide nanosheet array with enhanced stability for electrochemical seawater oxidation. Nano Res. Energy 2022, DOI: 10.26599/NRE.2022.9120028.
12

Zhang, L. C.; Wang, J. Q.; Liu, P. Y.; Liang, J.; Luo, Y. S.; Cui, G. W.; Tang, B.; Liu, Q.; Yan, X. D.; Hao, H. G. et al. Ni(OH)2 nanoparticles encapsulated in conductive nanowire array for high-performance alkaline seawater oxidation. Nano Res. 2022, 15, 6084–6090.
DOI Google Scholar
13

Wu, X. H.; Zhou, S.; Wang, Z. Y.; Liu, J. S.; Pei, W.; Yang, P. J.; Zhao, J. J.; Qiu, J. S. Engineering multifunctional collaborative catalytic interface enabling efficient hydrogen evolution in all pH range and seawater. Adv. Energy Mater. 2019, 9, 1901333.
DOI Google Scholar
14

Ding, P.; Song, H. Q.; Chang, J. W.; Lu, S. Y. N-doped carbon dots coupled NiFe-LDH hybrids for robust electrocatalytic alkaline water and seawater oxidation. Nano Res 2022, 15, 7063–7070.
DOI Google Scholar
15

Khan, M. A.; Al-Attas, T.; Roy, S.; Rahman, M. M.; Ghaffour, N.; Thangadurai, V.; Larter, S.; Hu, J. G.; Ajayan, P. M.; Kibria, M. G. Seawater electrolysis for hydrogen production: A solution looking for a problem? Energy Environ. Sci. 2021, 14, 4831–4839.
DOI Google Scholar
16

Zhang, L. Y.; Wang, Z. Y.; Qiu, J. S. Energy-saving hydrogen production by seawater electrolysis coupling sulfion degradation. Adv. Mater. 2022, 34, 2109321.
DOI Google Scholar
17

Gong, K. P.; Du, F.; Xia, Z. H.; Durstock, M.; Dai, L. M. Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction. Science 2009, 323, 760–764.
DOI Google Scholar
18

Zhai, Q. F.; Pan, Y.; Dai, L. M. Carbon-based metal-free electrocatalysts: Past, present, and future. Acc. Mater. Res. 2021, 2, 1239–1250.
DOI Google Scholar
19

Ouyang, L.; Zhou, Q.; Liang, J.; Zhang, L. C.; Yue, L. C.; Li, Z. R.; Li, J.; Luo, Y. S.; Liu, Q.; Li, N. et al. High-efficiency NO electroreduction to NH3 over honeycomb carbon nanofiber at ambient conditions. J. Colloid Interf. Sci. 2022, 616, 261–267.
DOI Google Scholar
20

Zheng, Y.; Jiao, Y.; Zhu, Y. H.; Li, L. H.; Han, Y.; Chen, Y.; Du, A. J.; Jaroniec, M.; Qiao, S. Z. Hydrogen evolution by a metal-free electrocatalyst. Nat. Commun. 2014, 5, 3783.
DOI Google Scholar
21

Cui, W.; Liu, Q.; Cheng, N. Y.; Asiri, A. M.; Sun, X. P. A. Activated carbon nanotubes: A highly-active metal-free electrocatalyst for hydrogen evolution reaction. Chem. Commun. 2014, 50, 9340–9342.
DOI Google Scholar
22

Cheng, N. Y.; Liu, Q.; Tian, J. Q.; Xue, Y. R.; Asiri, A. M.; Jiang, H. F.; He, Y. Q.; Sun, X. P. Acidically oxidized carbon cloth: A novel metal-free oxygen evolution electrode with high catalytic activity. Chem. Commun. 2015, 51, 1616–1619.
DOI Google Scholar
23

Jia, N.; Weng, Q.; Shi, Y. R.; Shi, X. Y.; Chen, X. B.; Chen, P.; An, Z. W.; Chen, Y. N-doped carbon nanocages: Bifunctional electrocatalysts for the oxygen reduction and evolution reactions. Nano Res 2018, 11, 1905–1916.
DOI Google Scholar
24

Dong, K.; Liang, J.; Wang, Y. Y.; Xu, Z. Q.; Liu, Q.; Luo, Y. L.; Li, T. S.; Li, L.; Shi, X. F.; Asiri, A. M. et al. Honeycomb carbon nanofibers: A superhydrophilic O2-entrapping electrocatalyst enables ultrahigh mass activity for the two-electron oxygen reduction reaction. Angew. Chem. , Int. Ed. 2021, 60, 10583–10587.
DOI Google Scholar
25

Ren, J. T.; Wan, C. Y.; Pei, T. Y.; Lv, X. W.; Yuan, Z. Y. Promotion of electrocatalytic nitrogen reduction reaction on N-doped porous carbon with secondary heteroatoms. Appl. Catal. B:Environ. 2020, 266, 118633.
DOI Google Scholar
26

Xia, L.; Wu, X. F.; Wang, Y.; Niu, Z. G.; Liu, Q.; Li, T. S.; Shi, X. F.; Asiri, A. M.; Sun, X. P. S-doped carbon nanosphere: An efficient electrocatalyst toward artificial N2 fixation to NH3. Small Methods 2019, 3, 1800251.
DOI Google Scholar
27

Chen, M. J.; Wang, S.; Zhang, H. Y.; Zhang, P.; Tian, Z. Q.; Lu, M.; Xie, X. J.; Huang, L.; Huang, W. Intrinsic defects in biomass-derived carbons facilitate electroreduction of CO2. Nano Res. 2020, 13, 729–735.
DOI Google Scholar
28

Chang, K.; Zhang, H. C.; Chen, J. G.; Lu, Q.; Cheng, M. J. Constant electrode potential quantum mechanical study of CO2 electrochemical reduction catalyzed by N-doped graphene. ACS Catal. 2019, 9, 8197–8207.
DOI Google Scholar
29

Huang, S. C.; Meng, Y. Y.; Cao, Y. F.; He, S. M.; Li, X. H.; Tong, S. F.; Wu, M. M. N-, O- and P-doped hollow carbons: Metal-free bifunctional electrocatalysts for hydrogen evolution and oxygen reduction reactions. Appl. Catal. B: Environ. 2019, 248, 239–248.
DOI Google Scholar
30

Stolz, A.; Le Floch, S.; Reinert, L.; Ramos, S. M. M.; Tuaillon-Combes, J.; Soneda, Y.; Chaudet, P.; Baillis, D.; Blanchard, N.; Duclaux, L. et al. Melamine-derived carbon sponges for oil–water separation. Carbon 2016, 107, 198–208.
DOI Google Scholar
31

Wang, Y.; Kong, D. Z.; Huang, S. Z.; Shi, Y. M.; Ding, M.; Von Lim, Y.; Xu, T. T.; Chen, F. M.; Li, X. J.; Yang, H. Y. 3D carbon foam-supported WS2 nanosheets for cable-shaped flexible sodium ion batteries. J. Mater. Chem. A 2018, 6, 10813–10824.
DOI Google Scholar
32

Shi, Y. Y.; Liu, G. J.; Jin, R. C.; Xu, H.; Wang, Q. Y.; Gao, S. M. Carbon materials from melamine sponges for supercapacitors and lithium battery electrode materials: A review. Carbon Energy 2019, 1, 253–275.
DOI Google Scholar
33

Zhang, P.; Wang, R. T.; He, M.; Lang, J. W.; Xu, S.; Yan, X. B. 3D hierarchical Co/CoO-graphene-carbonized melamine foam as a superior cathode toward long-life lithium oxygen batteries. Adv. Funct. Mater. 2016, 26, 1354–1364.
DOI Google Scholar
34

An, Y. B.; Zhu, Q. Z.; Hu, L. F.; Yu, S. K.; Zhao, Q.; Xu, B. A hollow carbon foam with ultra-high sulfur loading for an integrated cathode of lithium-sulfur batteries. J. Mater. Chem. A 2016, 4, 15605–15611.
DOI Google Scholar
35

Zhang, R.; Jing, X. X.; Chu, Y. T.; Wang, L.; Kang, W. J.; Wei, D. H.; Li, H. B.; Xiong, S. L. Nitrogen/oxygen co-doped monolithic carbon electrodes derived from melamine foam for high-performance supercapacitors. J. Mater. Chem. A 2018, 6, 17730–17739.
DOI Google Scholar
36

Schindler, M.; Hawthorne, F. C.; Freund, M. S.; Burns, P. C. XPS spectra of uranyl minerals and synthetic uranyl compounds II: The O 1s spectrum. Geochim. Cosmochim. Acta 2009, 73, 2488–2509.
DOI Google Scholar
37

Gangadharan, P. K.; Unni, S. M.; Kumar, N.; Ghosh, P.; Kurungot, S. Nitrogen-doped graphene with a three-dimensional architecture assisted by carbon nitride tetrapods as an efficient metal-free electrocatalyst for hydrogen evolution. ChemElectroChem 2017, 4, 2643–2652.
DOI Google Scholar
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Publication history
Copyright
Acknowledgements

Publication history

Received: 01 July 2022
Revised: 30 July 2022
Accepted: 04 August 2022
Published: 19 August 2022
Issue date: October 2022

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 22072015).

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