Bifunctional Fe-doped CoP@Ni₂P heteroarchitectures for high-efficient water electrocatalysis

It is important to develop economical and durable electrocatalysts for sustainable energy conversion technology. However, the current catalysts still suffer from insufficient hydrogen adsorption energy. Herein, we report a kind of novel bi-phosphide catalyst through constructing heterogeneous structures and cation doping. The obtained sample delivers an outstanding hydrogen evolution reaction (HER) performance at all pH range. As oxygen evolution reaction (OER) electrocatalyst, Fe-CoP@Ni₂P samples show an overpotential of 237 mV at 50 mA·cm⁻² in alkaline solution. For electrolysis of water, Fe-CoP@Ni₂P catalysts deliver a cell voltage of 1.59 V at 50 mA·cm⁻² and long durability. Furthermore, density functional theory (DFT) calculation further confirms that the doped heterostructure promotes Gibbs free energy for hydrogen adsorption. And the significant increase in the density of total states (DOS) also enhances the catalytic activity of HER.