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Nano Research 2022, 15(9): 8536-8545 https://doi.org/10.1007/s12274-022-4628-4
Research Article | Issue | Published: 01 July 2022

In-situ growth of polypyrrole on aramid nanofibers for electromagnetic interference shielding films with high stability

Show Author's Information Jianyu Zhou1,  Sineenat Thaiboonrod2,  Jianhui Fang1,  Shaomei Cao1,  Miao Miao1,  Xin Feng1( )
Research Center of Nano Science and Technology, College of Sciences, Shanghai University, Shanghai 200444, China
National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Thailand Science Park, Pathum Thani 12120, Thailand
Keywords:
high stability, in-situ growth of polypyrrole (PPy) on aramid nanofibers (ANF) , electromagnetic interference (EMI) shielding films, water-resistance, thermal mechanical properties
Topics:
Nanofibers
Cite this article:
Zhou J, Thaiboonrod S, Fang J, et al. In-situ growth of polypyrrole on aramid nanofibers for electromagnetic interference shielding films with high stability. Nano Research, 2022, 15(9): 8536-8545. https://doi.org/10.1007/s12274-022-4628-4
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Abstract Full text Electronic supplementary material About this article

Flexible electromagnetic interference (EMI) shielding films with high stability have shown promising prospect in harsh working conditions such as military, communication, and special protection fields. Herein, flexible aramid nanofibers@polypyrrole (ANF@PPy) films with high stability were easily achieved by the in-situ growth of PPy on the surface of ANF and the subsequent pressured-filtration film-forming process. When the amount of pyrrole (Py) monomer is 40 µL, the ANF@PPy (AP40) film exhibited excellent EMI shielding performance with shielding effectiveness (SE) of 41.69 dB, tensile strength of 96.01 MPa, and fracture strain of 21.95% at the thickness of 75.76 μm. Particularly, the anticipated EMI shielding performance can be maintained even after being heated at 200 °C in air, soaked in 3.5% NaCl solution, repeated folding for one million times, or burned directly, indicating superior environmental durability in harsh conditions. Therefore, it is believed that the ANF@PPy films with high stability offer a facile solution for practical protection for high-performance EMI shielding applications.


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Electronic supplementary material
About this article

In-situ growth of polypyrrole on aramid nanofibers for electromagnetic interference shielding films with high stability

Show Author's information Jianyu Zhou1, Sineenat Thaiboonrod2, Jianhui Fang1, Shaomei Cao1, Miao Miao1, Xin Feng1( )
Research Center of Nano Science and Technology, College of Sciences, Shanghai University, Shanghai 200444, China
National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Thailand Science Park, Pathum Thani 12120, Thailand

Abstract

Flexible electromagnetic interference (EMI) shielding films with high stability have shown promising prospect in harsh working conditions such as military, communication, and special protection fields. Herein, flexible aramid nanofibers@polypyrrole (ANF@PPy) films with high stability were easily achieved by the in-situ growth of PPy on the surface of ANF and the subsequent pressured-filtration film-forming process. When the amount of pyrrole (Py) monomer is 40 µL, the ANF@PPy (AP40) film exhibited excellent EMI shielding performance with shielding effectiveness (SE) of 41.69 dB, tensile strength of 96.01 MPa, and fracture strain of 21.95% at the thickness of 75.76 μm. Particularly, the anticipated EMI shielding performance can be maintained even after being heated at 200 °C in air, soaked in 3.5% NaCl solution, repeated folding for one million times, or burned directly, indicating superior environmental durability in harsh conditions. Therefore, it is believed that the ANF@PPy films with high stability offer a facile solution for practical protection for high-performance EMI shielding applications.

Keywords: high stability, in-situ growth of polypyrrole (PPy) on aramid nanofibers (ANF) , electromagnetic interference (EMI) shielding films, water-resistance, thermal mechanical properties

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Received: 14 May 2022
Revised: 30 May 2022
Accepted: 01 June 2022
Published: 01 July 2022
Issue date: September 2022

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© Tsinghua University Press 2022

Acknowledgements

This work was financially sponsored by the Science and Technology Commission of Shanghai Municipality (Nos. 20230742300 and 18595800700) and the project of “joint assignment” in Shanghai University led by Prof. Tongyue Gao from School of Mechatronic Engineering and Automation. We are grateful to Instrumental Analysis & Research Center of Shanghai University.

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