AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Engineering hierarchical heterostructure material based on metal-organic frameworks and cotton fiber for high-efficient microwave absorber

Yan Guo1, Hu Liu1( ), Dedong Wang1, Zeinhom M. El-Bahy2, Jalal T. Althakafy3, Hala M. Abo-Dief4, Zhanhu Guo5, Ben Bin Xu6, Chuntai Liu1, Changyu Shen1
Key Laboratory of Materials Processing and Mold (Zhengzhou University), Ministry of Education; National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou 450002, China
Department of Chemistry, Faculty of Science, Al-Azhar University, Nasr City 11884, Cairo, Egypt
Department of Chemistry, Faculty of Applied Science, Umm Al-Qura University, Mecca 21955, Saudi Arabia
Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia
Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN 37996, USA
Department of Mechanical and Construction Engineering, Faculty of Engineering and Environment, Northumbria University, Newcastle upon Tyne, NE1 8ST, UK
Show Author Information

Graphical Abstract

Hierarchical heterostructure WS2/CoS2@carbonized cotton fiber (CCF) derived from metal-organic frameworks (MOFs) anchored cotton fiber possesses multiple loss mechanisms and exhibits high-performance electromagnetic wave absorption capacity.

Abstract

Rational construction of hierarchical multi-component materials with abundant heterostructure is evolving as a promising strategy to achieve excellent metal-organic frameworks (MOFs) based electromagnetic wave (EMW) absorbers. Herein, hierarchical heterostructure WS2/CoS2@carbonized cotton fiber (CCF) was fabricated using the ZIF-67 MOFs nanosheets anchored cotton fiber (ZIF-67@CF) as a precursor through the tungsten etching, sulfurization, and carbonization process. Apart from the synergetic effect of dielectric-magnetic dual-loss mechanism, the hierarchical heterostructure and multicomponent of WS2/CoS2@CCF also display improved impedance matching. Furthermore, numerous W-S-Co bands and heterojunction interfaces of heterogeneous WS2/CoS2 are beneficial to promoting additional interfacial/dipole polarization loss and conductive loss, thereby enhancing the EMW attenuation performance. Based on the percolation theory, a good balance between impedance matching and EMW absorption capacity was achieved for the WS2/CoS2@CCF/paraffin composite with 20 wt.% filler loading, exhibiting strong EMW absorption capability with a minimum reflection loss (RLmin) value of −51.26 dB at 17.36 GHz with 2 mm thickness and a maximum effective absorption bandwidth (EABmax) as wide as 6.72 GHz. Our research will provide new guidance for designing high-efficient MOFs derived EMW absorbers.

Keywords

hierarchicalheterostructuresulfurizationmetal-organic frameworkmicrowave absorber

Electronic Supplementary Material

Download File(s)
12274_2022_4533_MOESM1_ESM.pdf (960.2 KB)

References

1

Lu, X. K.; Zhu, D. M.; Li, X.; Li, M. H.; Chen, Q.; Qing, Y. C. Gelatin-derived N-doped hybrid carbon nanospheres with an adjustable porous structure for enhanced electromagnetic wave absorption. Adv. Compos. Hybrid Mater. 2021, 4, 946–956.
Crossref Google Scholar
2

Zhang, Y. L.; Gu, J. W. A perspective for developing polymer-based electromagnetic interference shielding composites. Nanomicro Lett. 2022, 14, 89.
Crossref Google Scholar
3

Gao, Q. S.; Pan, Y. M.; Zheng, G. Q.; Liu, C. T.; Shen, C. Y.; Liu, X. H. Flexible multilayered MXene/thermoplastic polyurethane films with excellent electromagnetic interference shielding, thermal conductivity, and management performances. Adv. Compos. Hybrid Mater. 2021, 4, 274–285.
Crossref Google Scholar
4

Wu, N. N.; Du, W. J.; Hu, Q.; Vupputuri, S.; Jiang, Q. L. Recent development in fabrication of co nanostructures and their carbon nanocomposites for electromagnetic wave absorption. Eng. Sci. 2021, 13, 11–23.
Crossref Google Scholar
5

Zhang, Y. L.; Ma, Z. L.; Ruan, K. P.; Gu, J. W. Multifunctional Ti3C2Tx-(Fe3O4/polyimide) composite films with Janus structure for outstanding electromagnetic interference shielding and superior visual thermal management. Nano Res. 2022, 15, 5601–5609.
Crossref Google Scholar
6

Han, Y. X.; Ruan, K. P.; Gu, J. W. Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances. Nano Res. 2022, 15, 4747–4755.
Crossref Google Scholar
7

Wang, Y. F.; Wang, P.; Du, Z. R.; Liu, C. T.; Shen, C. Y.; Wang, Y. M. Electromagnetic interference shielding enhancement of poly (lactic acid)-based carbonaceous nanocomposites by poly (ethylene oxide)-assisted segregated structure: A comparative study of carbon nanotubes and graphene nanoplatelets. Adv. Compos. Hybrid Mater. 2022, 5, 209–219.
Crossref Google Scholar
8

Wang, L.; Ma, Z. L.; Zhang, Y. L.; Chen, L. X.; Cao, D. P.; Gu, J. W. Polymer-based EMI shielding composites with 3D conductive networks: A mini-review. SusMat 2021, 1, 413–431.
Crossref Google Scholar
9

Song, P.; Ma, Z. L.; Qiu, H.; Ru, Y. F.; Gu, J. W. High-efficiency electromagnetic interference shielding of rGO@FeNi/Epoxy composites with regular honeycomb structures. Nano-Micro Lett. 2022, 14, 51.
Crossref Google Scholar
10

Zhu, X. Y.; Qiu, H. F.; Chen, P.; Chen, G. Z.; Min, W. X. Graphitic carbon nitride (g-C3N4) in situ polymerization to synthesize MOF-Co@CNTs as efficient electromagnetic microwave absorption materials. Carbon 2021, 176, 530–539.
Crossref Google Scholar
11

Wang, Y.; Di, X. C.; Lu, Z.; Cheng, R. R.; Wu, X. M.; Gao, P. H. Controllable heterogeneous interfaces of cobalt/carbon nanosheets/rGO composite derived from metal-organic frameworks for high-efficiency microwave attenuation. Carbon 2022, 187, 404–414.
Crossref Google Scholar
12

Guo, Y.; Wang, D. D.; Tian, Y.; Wang, J. W.; Bai, T. T.; Liu, H.; Guo, Z. H.; Liu, C. T.; Shen, C. Y. FeCo alloy nanoparticle decorated cellulose based carbon aerogel as a low-cost and efficient electromagnetic microwave absorber. J. Mater. Chem. C 2022, 10, 126–134.
Crossref Google Scholar
13

Cui, J.; Wang, X. H.; Huang, L.; Zhang, C. W.; Yuan, Y.; Li, Y. B. Environmentally friendly bark-derived Co-Doped porous carbon composites for microwave absorption. Carbon 2022, 187, 115–125.
Crossref Google Scholar
14

Zhu, M.; Yan, X. X.; Xu, H. L.; Xu, Y. J.; Kong, L. Ultralight, compressible, and anisotropic MXene@Wood nanocomposite aerogel with excellent electromagnetic wave shielding and absorbing properties at different directions. Carbon 2021, 182, 806–814.
Crossref Google Scholar
15

Zhang, X.; Dong, Y. Y.; Pan, F.; Xiang, Z.; Zhu, X. J.; Lu, W. Electrostatic self-assembly construction of 2D MoS2 wrapped hollow Fe3O4 nanoflowers@1D carbon tube hybrids for self-cleaning high-performance microwave absorbers. Carbon 2021, 177, 332–343.
Crossref Google Scholar
16

Pan, F.; Liu, Z. C.; Deng, B. W.; Dong, Y. Y.; Zhu, X. J.; Huang, C.; Lu, W. Lotus leaf-derived gradient hierarchical porous C/MoS2 morphology genetic composites with wideband and tunable electromagnetic absorption performance. Nano-Micro Lett. 2021, 13, 43.
Crossref Google Scholar
17

Wang, B. J.; Li, S. K.; Huang, F. Z.; Wang, S. P.; Zhang, H.; Liu, F. H.; Liu, Q. C. Construction of multiple electron transfer paths in 1D core-shell hetetrostructures with MXene as interlayer enabling efficient microwave absorption. Carbon 2022, 187, 56–66.
Crossref Google Scholar
18

Xu, X. Q.; Ran, F. T.; Fan, Z. M.; Cheng, Z. J.; Xie, Z. M.; Lv, T.; Liu, Y. Y. Microstructural engineering of flexible and broadband microwave absorption films with hierarchical superstructures derived from bimetallic metal-organic framework. Carbon 2021, 178, 320–331.
Crossref Google Scholar
19

Zhang, D. Q.; Wang, H. H.; Cheng, J. Y.; Han, C. Y.; Yang, X. Y.; Xu, J. Y.; Shan, G. G.; Zheng, G. P.; Cao, M. S. Conductive WS2-NS/CNTs hybrids based 3D ultra-thin mesh electromagnetic wave absorbers with excellent absorption performance. Appl. Surf. Sci. 2020, 528, 147052.
Crossref Google Scholar
20

Wu, J.; Chen, T.; Zhu, C. Y.; Du, J. J.; Huang, L. S.; Yan, J.; Cai, D. M.; Guan, C.; Pan, C. X. Rational construction of a WS2/CoS2 heterostructure electrocatalyst for efficient hydrogen evolution at all pH values. ACS Sustainable Chem. Eng. 2020, 8, 4474–4480.
Crossref Google Scholar
21

Guo, Y.; Wang, D. D.; Wang, J. W.; Tian, Y.; Liu, H.; Liu, C. T.; Shen, C. Y. Hierarchical HCF@NC/Co derived from hollow loofah fiber anchored with metal-organic frameworks for highly efficient microwave absorption. ACS Appl. Mater. Interfaces 2022, 14, 2038–2050.
Crossref Google Scholar
22

Ren, C. T.; Jia, X.; Zhang, W.; Hou, D.; Xia, Z. Q.; Huang, D. S.; Hu, J.; Chen, S. P.; Gao, S. L. Hierarchical porous integrated Co1−xS/CoFe2O4@rGO nanoflowers fabricated via temperature-controlled in situ calcining sulfurization of multivariate CoFe-MOF-74@rGO for high-performance supercapacitor. Adv. Funct. Mater. 2020, 30, 2004519.
Crossref Google Scholar
23

Zhou, X. F.; Yang, X. L.; Li, H. N.; Hedhili, M. N.; Huang, K. W.; Li, L. J.; Zhang, W. J. Symmetric synergy of hybrid CoS2-WS2 electrocatalysts for the hydrogen evolution reaction. J. Mater. Chem. A 2017, 5, 15552–15558.
Crossref Google Scholar
24

Ma, Z. L.; Xiang, X. L.; Shao, L.; Zhang, Y. L.; Gu, J. W. Multifunctional wearable silver nanowire decorated leather nanocomposites for joule heating, electromagnetic interference shielding and piezoresistive sensing. Angew. Chem., Int. Ed. 2022, 61, e202200705.
Crossref Google Scholar
25

Liu, P. B.; Zhu, C. Y.; Gao, S.; Guan, C.; Huang, Y.; He, W. J. N-doped porous carbon nanoplates embedded with CoS2 vertically anchored on carbon cloths for flexible and ultrahigh microwave absorption. Carbon 2020, 163, 348–359.
Crossref Google Scholar
26

Wu, F.; Liu, Z. H.; Wang, J. Q.; Shah, T.; Liu, P.; Zhang, Q. Y.; Zhang, B. L. Template-free self-assembly of MXene and CoNi-bimetal MOF into intertwined one-dimensional heterostructure and its microwave absorbing properties. Chem. Eng. J. 2021, 422, 130591.
Crossref Google Scholar
27

Sun, L.; Shi, Z. C.; He, B. L.; Wang, H. L.; Liu, S.; Huang, M. H.; Shi, J.; Dastan, D.; Wang, H. Asymmetric trilayer all-polymer dielectric composites with simultaneous high efficiency and high energy density: A novel design targeting advanced energy storage capacitors. Adv. Funct. Mater. 2021, 31, 2100280.
Crossref Google Scholar
28

Sun, S. B.; Shi, Z. C.; Sun, L.; Liang, L.; Dastan, D.; He, B. L.; Wang, H. L.; Huang, M. H.; Fan, R. H. Achieving concurrent high energy density and efficiency in all-polymer layered paraelectric/ferroelectric composites via introducing a moderate layer. ACS Appl. Mater. Interfaces 2021, 13, 27522–27532.
Crossref Google Scholar
29

Wang, Z. H.; Yang, L. X.; Zhou, Y.; Xu, C.; Yan, M.; Wu, C. NiFe LDH/MXene derivatives interconnected with carbon fabric for flexible electromagnetic wave absorption. ACS Appl. Mater. Interfaces 2021, 13, 16713–16721.
Crossref Google Scholar
30

Wang, Y. P.; Zhong, W. X.; Zhang, S.; Zhang, X.; Zhu, C. L.; Zhang, X. L.; Zhang, X. T.; Chen, Y. J. Pearl necklace-like CoMn-based nanostructures derived from metal-organic frames for enhanced electromagnetic wave absorption. Carbon 2022, 188, 254–264.
Crossref Google Scholar
31

Song, S. W.; Zhang, A. T.; Chen, L.; Jia, Q.; Zhou, C. L.; Liu, J. Q.; Wang, X. X. A novel multi-cavity structured MOF derivative/porous graphene hybrid for high performance microwave absorption. Carbon 2021, 176, 279–289.
Crossref Google Scholar
32

Tan, R. Y.; Zhou, J. T.; Yao, Z. J.; Wei, B.; Zu, J. Q.; Lin, H. Y.; Li, Z. Ferrero Rocher® chocolates-like FeCo/C microspheres with adjustable electromagnetic properties for effective microwave absorption. J. Alloys Compd. 2021, 857, 157568.
Crossref Google Scholar
33

Guo, Y.; Wang, D. D.; Bai, T. T.; Liu, H.; Zheng, Y. J.; Liu, C. T.; Shen, C. Y. Electrostatic self-assembled NiFe2O4/Ti3C2Tx MXene nanocomposites for efficient electromagnetic wave absorption at ultralow loading level. Adv. Compos. Hybrid Mater. 2021, 4, 602–613.
Crossref Google Scholar
34

Wei, H. J.; Tian, Y.; Chen, Q.; Estevez, D.; Xu, P.; Peng, H. X.; Qin, F. X. Microwave absorption performance of 2D Iron-Quinoid MOF. Chem. Eng. J. 2021, 405, 126637.
Crossref Google Scholar
35

Zhao, B.; Deng, J. S.; Zhang, R.; Liang, L. Y.; Fan, B. B.; Bai, Z. Y.; Shao, G.; Park, C. B. Recent advances on the electromagnetic wave absorption properties of Ni based materials. Eng. Sci. 2018, 3, 5–40.
Crossref Google Scholar
36

Li, X.; Wang, Z. L.; Xiang, Z.; Zhu, X. J.; Dong, Y. Y.; Huang, C.; Cai, L.; Lu, W. Biconical prisms Ni@C composites derived from metal-organic frameworks with an enhanced electromagnetic wave absorption. Carbon 2021, 184, 115–126.
Crossref Google Scholar
37

Bai, T. T.; Guo, Y.; Liu, H.; Song, G.; Zhang, D. B.; Wang, Y. M.; Mi, L. W.; Guo, Z. H.; Liu, C. T.; Shen, C. Y. Achieving enhanced electromagnetic shielding and absorption capacity of cellulose-derived carbon aerogels via tuning the carbonization temperature. J. Mater. Chem. C 2020, 8, 5191–5201.
Crossref Google Scholar
38

Liang, X. H.; Wang, G. H.; Gu, W. H.; Ji, G. B. Prussian blue analogue derived carbon-based composites toward lightweight microwave absorption. Carbon 2021, 177, 97–106.
Crossref Google Scholar
39

Qu, X. H.; Zhou, Y. L.; Li, X. Y.; Javid, M.; Huang, F. R.; Zhang, X. F.; Dong, X. L.; Zhang, Z. D. Nitrogen-doped graphene layer-encapsulated NiFe bimetallic nanoparticles synthesized by an arc discharge method for a highly efficient microwave absorber. Inorg. Chem. Front. 2020, 7, 1148–1160.
Crossref Google Scholar
40

Peng, C. L.; Zhang, Y. N.; Zhang, B. S. MOF-derived jujube pit shaped C/Co composites with hierarchical structure for electromagnetic absorption. J. Alloys Compd. 2020, 826, 154203.
Crossref Google Scholar
41

Huang, W. H.; Zhang, X. X.; Zhao, Y. N.; Zhang, J.; Liu, P. B. Hollow N-doped carbon polyhedra embedded Co and Mo2C nanoparticles for high-efficiency and wideband microwave absorption. Carbon 2020, 167, 19–30.
Crossref Google Scholar
42

Yan, J.; Huang, Y.; Zhang, Z.; Liu, X. D. Novel 3D microsheets contain cobalt particles and numerous interlaced carbon nanotubes for high-performance electromagnetic wave absorption. J. Alloys Compd. 2019, 785, 1206–1214.
Crossref Google Scholar
43

Liu, L. L.; Wang, L.; Li, Q. Q.; Yu, X. F.; Shi, X. F.; Ding, J. J.; You, W. B.; Yang, L. T.; Zhang, Y. H.; Che, R. C. High-performance microwave absorption of MOF-derived core−shell Co@N-doped carbon anchored on reduced graphene oxide. ChemNanoMat 2019, 5, 558–565.
Crossref Google Scholar
44

Li, N.; Huang, G. W.; Xiao, H. M.; Feng, Q. P.; Fu, S. Y. Investigations on structure-dependent microwave absorption performance of nano-Fe3O4 coated carbon-based absorbers. Carbon 2019, 144, 216–227.
Crossref Google Scholar
45

Quan, B.; Xu, G. Y.; Yi, H.; Yang, Z. H.; Xiang, J. X.; Chen, Y. T.; Ji, G. B. Enhanced electromagnetic wave response of nickel nanoparticles encapsulated in nanoporous carbon. J. Alloys Compd. 2018, 769, 961–968.
Crossref Google Scholar
46

Liao, Q.; He, M.; Zhou, Y. M.; Nie, S. X.; Wang, Y. J.; Wang, B. B.; Yang, X. M.; Bu, X. H.; Wang, R. L. Rational construction of Ti3C2Tx/Co-MOF-derived laminated Co/TiO2-C hybrids for enhanced electromagnetic wave absorption. Langmuir 2018, 34, 15854–15863.
Crossref Google Scholar
Nano Research
Volume 15 Issue 8,
August 2022
Pages 6841-6850
DOI: 10.1007/s12274-022-4533-x
Cite this article:
Guo Y, Liu H, Wang D, et al. Engineering hierarchical heterostructure material based on metal-organic frameworks and cotton fiber for high-efficient microwave absorber. Nano Research, 2022, 15(8): 6841-6850. https://doi.org/10.1007/s12274-022-4533-x
Topics:
Carbon composites
Part of a topical collection:
EM Wave Functional Materials

1073

Views

84

Crossref

82

Web of Science

88

Scopus

3

CSCD

Altmetrics
Received: 24 April 2022
Revised: 11 May 2022
Accepted: 14 May 2022
Published: 03 June 2022
© Tsinghua University Press 2022
Return