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Nano Research 2022, 15(10): 8955-8961 https://doi.org/10.1007/s12274-022-4524-y
Research Article | Issue | Published: 10 June 2022

Degradation mechanism and stability improvement of formamidine-based perovskite solar cells under high humidity conditions

Show Author's Information Fengren Cao§,  Peng Zhang§,  Haoxuan Sun,  Meng Wang,  Liang Li( )
School of Physical Science and Technology, Center for Energy Conversion Materials & Physics (CECMP), Jiangsu Key Laboratory of Thin Films, Soochow University, Suzhou 215006, China

§ Fengren Cao and Peng Zhang contributed equally to this work.

Keywords:
solar cell, formamidine-based perovskite, moisture degradation, seed solution
Topics:
Perovskite solar cells
Cite this article:
Cao F, Zhang P, Sun H, et al. Degradation mechanism and stability improvement of formamidine-based perovskite solar cells under high humidity conditions. Nano Research, 2022, 15(10): 8955-8961. https://doi.org/10.1007/s12274-022-4524-y
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Abstract Full text Electronic supplementary material About this article

Formamidine (FA)-based perovskite solar cells (PSCs) are promising candidates for photoelectric conversion devices due to their excellent optoelectronic properties. However, the instability of perovskites, especially moisture instability, remains one of the biggest obstacles to the commercialization of perovskite devices. Therefore, it is very important to explore and target the effect of moisture on FA-based perovskites to prevent this effect and improve device stability. Herein, we studied the degradation process of commonly used FA-based perovskite films by X-ray diffraction and scanning electron microscopy characterization and analyzed the reasons for their humidity-induced degradation. Subsequently, we further adopted a strategy by adding methylammonium bromine powder into a PbI2 precursor solution to prepare a seed solution in a two-step preparation process to enhance the performance and stability of FA-based PSCs. Finally, the degradation rate of the obtained perovskite film was significantly slowed down under high humidity compared to that of perovskite films prepared by a two-step method without applying a seed solution. The corresponding device achieved a remarkable power conversion efficiency of 23.22%, and the efficiency of this device showed no attenuation after 900 h of exposure to air.


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About this article

Degradation mechanism and stability improvement of formamidine-based perovskite solar cells under high humidity conditions

Show Author's information Fengren Cao§, Peng Zhang§, Haoxuan Sun, Meng Wang, Liang Li( )
School of Physical Science and Technology, Center for Energy Conversion Materials & Physics (CECMP), Jiangsu Key Laboratory of Thin Films, Soochow University, Suzhou 215006, China

§ Fengren Cao and Peng Zhang contributed equally to this work.

Abstract

Formamidine (FA)-based perovskite solar cells (PSCs) are promising candidates for photoelectric conversion devices due to their excellent optoelectronic properties. However, the instability of perovskites, especially moisture instability, remains one of the biggest obstacles to the commercialization of perovskite devices. Therefore, it is very important to explore and target the effect of moisture on FA-based perovskites to prevent this effect and improve device stability. Herein, we studied the degradation process of commonly used FA-based perovskite films by X-ray diffraction and scanning electron microscopy characterization and analyzed the reasons for their humidity-induced degradation. Subsequently, we further adopted a strategy by adding methylammonium bromine powder into a PbI2 precursor solution to prepare a seed solution in a two-step preparation process to enhance the performance and stability of FA-based PSCs. Finally, the degradation rate of the obtained perovskite film was significantly slowed down under high humidity compared to that of perovskite films prepared by a two-step method without applying a seed solution. The corresponding device achieved a remarkable power conversion efficiency of 23.22%, and the efficiency of this device showed no attenuation after 900 h of exposure to air.

Keywords: solar cell, formamidine-based perovskite, moisture degradation, seed solution

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Publication history
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Acknowledgements

Publication history

Received: 12 April 2022
Revised: 30 April 2022
Accepted: 09 May 2022
Published: 10 June 2022
Issue date: October 2022

Copyright

© Tsinghua University Press 2022

Acknowledgements

The authors acknowledge the support from the National Natural Science Foundation of China (Nos. 52025028 and 52002258), the Ministry of Science and Technology of China (No. 2021YFA1500803), the Natural Science Foundation of Jiangsu Province (Nos. BK20200877 and BK20210728), “Shuangchuang” Program of Jiangsu Province, and the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions.

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