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Nano Research 2022, 15(8): 7227-7233 https://doi.org/10.1007/s12274-022-4477-1
Research Article | Issue | Published: 20 June 2022

Interface engineering of Zn meal anodes using electrochemically inert Al2O3 protective nanocoatings

Show Author's Information Rui Wang1,  Qiongfei Wu1,  Minjie Wu1,  Jiaxian Zheng1,  Jian Cui2,  Qi Kang3( ),  Zhengbing Qi2( ),  JiDong Ma2,  Zhoucheng Wang1,  Hanfeng Liang1( )
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Key Laboratory of Functional Materials and Applications of Fujian Province, School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361024, China
Department of Polymer Science and Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, Shanghai 200240, China
Keywords:
interface engineering, side reactions, aqueous Zn-ion batteries, Zn dendrites, Al2O3 protective nanocoatings
Topics:
Secondary batteries
Cite this article:
Wang R, Wu Q, Wu M, et al. Interface engineering of Zn meal anodes using electrochemically inert Al2O3 protective nanocoatings. Nano Research, 2022, 15(8): 7227-7233. https://doi.org/10.1007/s12274-022-4477-1
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Abstract Full text Electronic supplementary material About this article

Aqueous rechargeable Zn-ion batteries are regarded as a promising alternative to lithium-ion batteries owing to their high energy density, low cost, and high safety. However, their commercialization is severely restricted by the Zn dendrite formation and side reactions. Herein, we propose that these issues can be minimized by modifying the interfacial properties through introducing electrochemically inert Al2O3 nanocoatings on Zn meal anodes (Al2O3@Zn). The Al2O3 nanocoatings can effectively suppress both the dendrite growth and side reactions. As a result, the Al2O3@Zn symmetric cells show excellent electrochemical performance with a long lifespan of more than 4,000 h at 1 mA·cm−2 and 1 mAh·cm−2. Meanwhile, the assembled Al2O3@Zn//V2O5 full cells can deliver a high capacity (236.2 mAh·g−1) and long lifespan with a capacity retention of 76.11% after 1,000 cycles at 4 A·g−1.


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Abstract
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Electronic supplementary material
About this article

Interface engineering of Zn meal anodes using electrochemically inert Al2O3 protective nanocoatings

Show Author's information Rui Wang1, Qiongfei Wu1, Minjie Wu1, Jiaxian Zheng1, Jian Cui2, Qi Kang3( ), Zhengbing Qi2( ), JiDong Ma2, Zhoucheng Wang1, Hanfeng Liang1( )
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Key Laboratory of Functional Materials and Applications of Fujian Province, School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361024, China
Department of Polymer Science and Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, Shanghai 200240, China

Abstract

Aqueous rechargeable Zn-ion batteries are regarded as a promising alternative to lithium-ion batteries owing to their high energy density, low cost, and high safety. However, their commercialization is severely restricted by the Zn dendrite formation and side reactions. Herein, we propose that these issues can be minimized by modifying the interfacial properties through introducing electrochemically inert Al2O3 nanocoatings on Zn meal anodes (Al2O3@Zn). The Al2O3 nanocoatings can effectively suppress both the dendrite growth and side reactions. As a result, the Al2O3@Zn symmetric cells show excellent electrochemical performance with a long lifespan of more than 4,000 h at 1 mA·cm−2 and 1 mAh·cm−2. Meanwhile, the assembled Al2O3@Zn//V2O5 full cells can deliver a high capacity (236.2 mAh·g−1) and long lifespan with a capacity retention of 76.11% after 1,000 cycles at 4 A·g−1.

Keywords: interface engineering, side reactions, aqueous Zn-ion batteries, Zn dendrites, Al2O3 protective nanocoatings

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Publication history
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Acknowledgements

Publication history

Received: 13 April 2022
Revised: 26 April 2022
Accepted: 27 April 2022
Published: 20 June 2022
Issue date: August 2022

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 51601163, 22001081, and 22075236), the National Key Research and Development Program of China (No. 2017YFE0198100), the Natural Science Foundation of Fujian Province (No. 2021J011211), Xiamen Municipal Bureau of Science and Technology (No. 3502Z20206070), and Xiamen University.

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