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Research Article

Nanosheet-coated synthetic wood with enhanced flame-retardancy by vacuum-assisted sonocoating technique

Zhi-Yuan Ma1,§Xiao-Feng Pan1,§Ze-Lai Xu2Zhi-Long Yu1Bing Qin1Yi-Chen Yin1Yu-Cheng Gao1Shu-Hong Yu1 ( )
Department of Chemistry, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, University of Science and Technology of China, Hefei 230026, China
Department of Modern Mechanics, University of Science and Technology of China, Hefei 230027, China

§ Zhi-Yuan Ma and Xiao-Feng Pan contributed equally to this work.

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Abstract

Compared to natural woods, synthetic woods have superior mechanical stability, thermal insulation, and flame retardancy owing to their hierarchically cellular microstructures and intrinsic advantages of the thermosetting matrix. Increasing the long-time fire resistance is very important to the practical application. In this study, we present a novel coating strategy by a vacuum-assisted sonication technique (sonocoating) with a rectorite nanosheet dispersion to create a uniform nanocoating on the channel walls of synthetic wood. Owing to ultrasonic energy and vacuum pressure, the nanosheet dispersion can penetrate deep down to form a layered nanocoating on the channel surface. The coated synthetic woods can withstand fire (400–600 °C) for more than 10 min with 62% mass retainment, surpassing uncoated synthetic woods and natural woods. Therefore, as a lightweight and strong composite with enhanced flame-retardant performance, the coated synthetic woods have huge potential applications in safe and energy-efficient buildings.

Graphical Abstract

A vacuum-assisted sonocoating approach has been proposed to modify the artificial wood with a rectorite nano-coating on every internal channel wall. The nanosheets can go much deeper into the channels with the help of vacuum and sonication, which promote the infiltration of nanosheets solution into the channels. The nanosheet coating enables the formation of a thick ash layer and a char layer to endure the fire erosion for at least 10 min without any structural collapse.

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Nano Research
Pages 9440-9446

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Cite this article:
Ma Z-Y, Pan X-F, Xu Z-L, et al. Nanosheet-coated synthetic wood with enhanced flame-retardancy by vacuum-assisted sonocoating technique. Nano Research, 2022, 15(10): 9440-9446. https://doi.org/10.1007/s12274-022-4407-2
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Received: 20 March 2022
Revised: 05 April 2022
Accepted: 06 April 2022
Published: 26 July 2022
© Tsinghua University Press 2022