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Nano Research 2022, 15(7): 6208-6212 https://doi.org/10.1007/s12274-022-4307-5
Research Article | Issue | Published: 10 May 2022

Rational designed isostructural MOF for the charge–discharge behavior study of super capacitors

Show Author's Information Hong Chen,  Xiao-Fei Liu,  Hai-Yang Li,  Peng Peng( ),  Shuang-Quan Zang( )
Green Catalysis Center and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
Keywords:
rational design, Eu-metal-organic framework (Eu-MOF), super capacitor, controllable charge–discharge behavior
Topics:
Energy
Cite this article:
Chen H, Liu X-F, Li H-Y, et al. Rational designed isostructural MOF for the charge–discharge behavior study of super capacitors. Nano Research, 2022, 15(7): 6208-6212. https://doi.org/10.1007/s12274-022-4307-5
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Abstract Full text Electronic supplementary material About this article

In recent years, the rapid charge–discharge property of super capacitors based on metal-organic frameworks (MOFs) has seen excellent applications in energy storage equipment. However, the purposeful design of high-performance electrodes for MOF-derived super capacitors is still an urgent problem that needs to be solved. Herein, we rationally design and prepare three MOFs with the same crystal configuration and controllable functional groups. Through the combination of rigorous experiment and calculation, we have verified the effects of the specific surface area of the electrode material as well as the binding energy between the electrode material and the electrolyte ions on the performance of the super capacitor. This work not only extends the application of MOFs, but also provides a model-material platform for the study of charge–discharge behavior of MOF-based super capacitors, creating a way of thinking for the selection and design of MOF materials for energy storage applications.


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About this article

Rational designed isostructural MOF for the charge–discharge behavior study of super capacitors

Show Author's information Hong Chen, Xiao-Fei Liu, Hai-Yang Li, Peng Peng( ), Shuang-Quan Zang( )
Green Catalysis Center and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Abstract

In recent years, the rapid charge–discharge property of super capacitors based on metal-organic frameworks (MOFs) has seen excellent applications in energy storage equipment. However, the purposeful design of high-performance electrodes for MOF-derived super capacitors is still an urgent problem that needs to be solved. Herein, we rationally design and prepare three MOFs with the same crystal configuration and controllable functional groups. Through the combination of rigorous experiment and calculation, we have verified the effects of the specific surface area of the electrode material as well as the binding energy between the electrode material and the electrolyte ions on the performance of the super capacitor. This work not only extends the application of MOFs, but also provides a model-material platform for the study of charge–discharge behavior of MOF-based super capacitors, creating a way of thinking for the selection and design of MOF materials for energy storage applications.

Keywords: rational design, Eu-metal-organic framework (Eu-MOF), super capacitor, controllable charge–discharge behavior

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Publication history
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Acknowledgements

Publication history

Received: 04 January 2022
Revised: 01 March 2022
Accepted: 08 March 2022
Published: 10 May 2022
Issue date: July 2022

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 22005273 and 21825106).

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