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Research Article | Open Access

There is life after coking for Ir nanocatalyst superlattices

Antonio J. Martínez-Galera1,2,( )Haojie Guo1Mariano D. Jiménez-Sánchez1Stefano Franchi3,Kevin C. Prince3José M. Gómez-Rodríguez1,2,4,
Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049, Spain
Instituto Nicolás Cabrera, Universidad Autónoma de Madrid, Madrid E-28049, Spain
Elettra-Sincrotrone Trieste S.C.p.A., in Area Science Park, Basovizza (Trieste) 34149, Italy
Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, Madrid E-28049, Spain
Present address: Departamento de Física de Materiales, Universidad Autónoma de Madrid, Madrid E-28049, Spain
Present address: Institute of Structure of Matter (ISM), National Research Council (CNR), Rome 00133, Italy
Deceased
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Graphical Abstract

Ordered networks of Ir nanocrystals, with a tunable narrow size distribution and good chemical and thermal stabilities, are proposed as a novel testbed to draw up a profile of the perfect catalyst in oxidation reactions.

Abstract

Achieving superior performance of nanoparticle systems is one of the biggest challenges in catalysis. Two major phenomena, occurring during the reactions, hinder the development of the full potential of nanoparticle catalysts: sintering and contamination with carbon containing species, sometimes called coking. Here, we demonstrate that Ir nanocrystals, arranged into periodic networks on hexagonal boron nitride (h-BN) supports, can be restored without sintering after contamination by persistent carbon. This restoration yields the complete removal of carbon from the nanocrystals, which keep their crystalline structure, allowing operation without degradation. These findings, together with the possibility of fine tuning the nanocrystals size, confer this nanoparticle system a great potential as a testbed to extract key information about catalysis-mediated oxidation reactions. For the case of the CO oxidation by O2, reaction of interest in environmental science and green energy production, the existence of chemical processes not observed before in other nanoparticle systems is demonstrated.

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Nano Research
Pages 6969-6976
Cite this article:
Martínez-Galera AJ, Guo H, Jiménez-Sánchez MD, et al. There is life after coking for Ir nanocatalyst superlattices. Nano Research, 2022, 15(8): 6969-6976. https://doi.org/10.1007/s12274-022-4300-z
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Received: 02 December 2021
Revised: 07 March 2022
Accepted: 07 March 2022
Published: 14 June 2022
© The Author(s) 2022

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