Graphical Abstract

Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
The plastic pollution has become one of the top environmental concerns. Substantial effort has been devoted into recycling waste plastic materials in a facile and economical way. In this work, we have successfully recycled a common type of plastic waste, i.e., polystyrene (PS), into value-added functional materials through a cost-effective and facile dip-coating method. The resulted mixture of waste PS and SiO2, referred to as PS/SiO2, coated textile material is superhydrophobic and superoleophilic, showing an excellent resistance towards corrosive solutions (acid, alkaline, and saline), high temperature treatment, and mechanical abrasion. As a proof-of-concept application, the PS/SiO2-coated textile is used to selectively separate oil/water mixtures through either absorption or filtration method. It also exhibits a surface self-cleaning property, which may be used as fabrics for dust-preventing cloths. Our work offers a new strategy to treat the waste for preparation of novel low-cost superhydrophobic materials for various applications.
Brahney, J.; Hallerud, M.; Heim, E.; Hahnenberger, M.; Sukumaran, S. Plastic rain in protected areas of the United States. Science 2020, 368, 1257–1260.
Yang, J.; Yang, Y.; Wu, W. M.; Zhao, J.; Jiang, L. Evidence of polyethylene biodegradation by bacterial strains from the guts of plastic-eating waxworms. Environ. Sci. Technol. 2014, 48, 13776–13784.
Cox, K. D.; Covernton, G. A.; Davies, H. L.; Dower, J. F.; Juanes, F.; Dudas, S. E. Human consumption of microplastics. Environ. Sci. Technol. 2019, 53, 7068–7074.
Barboza, L. G. A.; Vethaak, A. D.; Lavorante, B. R. B. O.; Lundebye, A. K.; Guilhermino, L. Marine microplastic debris: An emerging issue for food security, food safety and human health. Mar. Pollut. Bull. 2018, 133, 336–348.
Fonseca, W. S.; Meng, X. H.; Deng, D. Trash to treasure: Transforming waste polystyrene cups into negative electrode materials for sodium ion batteries. ACS Sustainable Chem. Eng. 2015, 3, 2153–2159.
Hong, M.; Chen, E. Y. X. Towards truly sustainable polymers: A metal-free recyclable polyester from biorenewable non-strained γ-Butyrolactone. Angew. Chem., Int. Ed. 2016, 55, 4188–4193.
Hong, M.; Chen, E. Y. X. Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone. Nat. Chem. 2016, 8, 42–49.
Yang, Y.; Yang, J.; Wu, W. M.; Zhao, J.; Song, Y. L.; Gao, L. C.; Yang, R. F.; Jiang, L. Biodegradation and mineralization of polystyrene by plastic-eating mealworms: Part 1. Chemical and physical characterization and isotopic tests. Environ. Sci. Technol. 2015, 49, 12080–12086.
Ma, Q. L.; Yu, Y. F.; Sindoro, M.; Fane, A. G.; Wang, R.; Zhang, H. Carbon-based functional materials derived from waste for water remediation and energy storage. Adv. Mater. 2017, 29, 1605361.
Gu, J. H.; Fan, H. W.; Li, C. X.; Caro, J.; Meng, H. Robust superhydrophobic/superoleophilic wrinkled microspherical MOF@rGO composites for efficient oil-water separation. Angew. Chem., Int. Ed. 2019, 58, 5297–5301.
Maurer, J. A.; Miller, M. J.; Bartolucci, S. F. Self-cleaning superhydrophobic nanocomposite surfaces generated by laser pulse heating. J. Colloid Interf. Sci. 2018, 524, 204–208.
Xiang, T. F.; Han, Y.; Guo, Z. Q.; Wang, R.; Zheng, S. L.; Li, S.; Li, C.; Dai, X. M. Fabrication of inherent anticorrosion superhydrophobic surfaces on metals. ACS Sustainable Chem. Eng. 2018, 6, 5598–5606.
Wang, L.; Gong, Q. H.; Zhan, S. H.; Jiang, L.; Zheng, Y. M. Robust anti-icing performance of a flexible superhydrophobic surface. Adv. Mater. 2016, 28, 7729–7735.
Shin, C.; Chase, G. G. Nanofibers from recycle waste expanded polystyrene using natural solvent. Polym. Bull. 2005, 55, 209–215.
Yu, C. M.; Lin, W. Y.; Jiang, J. E.; Jing, Z. X.; Hong, P. Z.; Li, Y. Preparation of a porous superhydrophobic foam from waste plastic and its application for oil spill cleanup. RSC Adv. 2019, 9, 37759–37767.
Edwards, H. G. M.; Farwell, D. W.; Williams, A. C. FT-Raman spectrum of cotton: A polymeric biomolecular analysis. Spectrochim. Acta Part A:Mol. Spectrosc. 1994, 50, 807–811.
Rygula, A.; Jekiel, K.; Szostak-Kot, J.; Wrobel, T. P.; Baranska, M. Application of FT-Raman spectroscopy for in situ detection of microorganisms on the surface of textiles. J. Environ. Monit. 2011, 13, 2983–2987.
Sears, W. M.; Hunt, J. L.; Stevens, J. R. Raman scattering from polymerizing styrene. II. Intensity changes as a function of conversion. J. Chem. Phys. 1981, 75, 1599–1602.
Mazilu, M.; De Luca, A. C.; Riches, A.; Herrington, C. S.; Dholakia, K. Optimal algorithm for fluorescence suppression of modulated Raman spectroscopy. Opt. Express 2010, 18, 11382–11395.
Feng, L.; Li, S.; Li, Y.; Li, H.; Zhang, L.; Zhai, J.; Song, Y.; Liu, B.; Jiang, L.; Zhu, D. Super-hydrophobic surfaces: From natural to artificial. Adv. Mater. 2002, 14, 1857–1860.
Ma, Q. L.; Cheng, H. F.; Fane, A. G.; Wang, R.; Zhang, H. Recent development of advanced materials with special wettability for selective oil/water separation. Small 2016, 12, 2186–2202.
Verho, T.; Bower, C.; Andrew, P.; Franssila, S.; Ikkala, O.; Ras, R. H. A. Mechanically durable superhydrophobic surfaces. Adv. Mater. 2011, 23, 673–678.
Chen, B.; Ma, Q. L.; Tan, C. L.; Lim, T. T.; Huang, L.; Zhang, H. Carbon-based sorbents with three-dimensional architectures for water remediation. Small 2015, 11, 3319–3336.
Wang, Z. X.; Ji, S. Q.; He, F.; Cao, M. Y.; Peng, S. Q.; Li, Y. X. One-step transformation of highly hydrophobic membranes into superhydrophilic and underwater superoleophobic ones for high-efficiency separation of oil-in-water emulsions. J. Mater. Chem. A 2018, 6, 3391–3396.
Wang, Z. X.; Yang, H. C.; He, F.; Peng, S. Q.; Li, Y. X.; Shao, L.; Darling, S. B. Mussel-inspired surface engineering for water-remediation materials. Matter 2019, 1, 115–155.
Jiang, L.; Zhao, Y.; Zhai, J. A lotus-leaf-like superhydrophobic surface: A porous microsphere/nanofiber composite film prepared by electrohydrodynamics. Angew. Chem., Int. Ed. 2004, 43, 4338–4341.