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Nano Research 2022, 15(7): 5842-5847 https://doi.org/10.1007/s12274-022-4208-7
Research Article | Issue | Published: 10 March 2022

Highly dispersed Ag clusters for active and stable hydrogen peroxide production

Show Author's Information Mengmeng Jin1,2,§,  Wei Liu2,§,  Jiaqiang Sun3,  Xinzhong Wang1( ),  Shusheng Zhang4,  Jun Luo2( ),  Xijun Liu5( )
Information Technology Research Institute, Shenzhen Institute of Information Technology, Shenzhen 518172, China
Institute for New Energy Materials and Low-Carbon Technologies, Tianjin Key Lab for Photoelectric Materials & Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
College of Chemistry, Zhengzhou University, Zhengzhou 450000, China
MOE Key Laboratory of New Processing Technology for Non-Ferrous Metals and Materials, and Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, School of Resource, Environments and Materials, Guangxi University, Nanning 530004, China

§ Mengmeng Jin and Wei Liu contributed equally to this work.

Keywords:
oxygen reduction reaction, Ag nanoclusters, hydrogen peroxide synthesis, electrochemical route, energy-efficient
Topics:
Nanoclusters
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Jin M, Liu W, Sun J, et al. Highly dispersed Ag clusters for active and stable hydrogen peroxide production. Nano Research, 2022, 15(7): 5842-5847. https://doi.org/10.1007/s12274-022-4208-7
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Abstract Full text Electronic supplementary material About this article

The electrosynthesis of hydrogen peroxide (H2O2) from oxygen reduction reaction (ORR) via a two-electron pathway provides an appealing alternative to the energy-intensive anthraquinone route; however, the development of ORR with high selectivity and durability for H2O2 production is still challenging. Herein, we demonstrate an active and stable catalyst, composing of highly dispersed Ag nanoclusters on N-doped hollow carbon spheres (NC-Ag/NHCS), which can effectively reduce O2 molecules into H2O2 with a selectivity of 89%–91% in a potential range from 0.2 to 0.7 V (vs. reversible hydrogen electrode (RHE)) in acidic media. Strikingly, NC-Ag/NHCS achieve a mass activity of 27.1 A·g−1 and a yield rate of 408 mmol·gcat.−1·h−1 at 0.7 V, both of which are comparable with the best-reported results. Furthermore, NC-Ag/NHCS enable catalyzing H2O2 production with a stable current density over 48-h electrolysis and only about 9.8% loss in selectivity after 10,000 cycles. Theoretical analyses indicate that Ag nanoclusters can contribute more electrons to favor the protonation of adsorbed O2, thus leading to a high H2O2 selectivity. This work confirms the great potential of metal nanocluster-based materials for H2O2 electrosynthesis under ambient conditions.


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Abstract
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Electronic supplementary material
About this article

Highly dispersed Ag clusters for active and stable hydrogen peroxide production

Show Author's information Mengmeng Jin1,2,§, Wei Liu2,§, Jiaqiang Sun3, Xinzhong Wang1( ), Shusheng Zhang4, Jun Luo2( ), Xijun Liu5( )
Information Technology Research Institute, Shenzhen Institute of Information Technology, Shenzhen 518172, China
Institute for New Energy Materials and Low-Carbon Technologies, Tianjin Key Lab for Photoelectric Materials & Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
College of Chemistry, Zhengzhou University, Zhengzhou 450000, China
MOE Key Laboratory of New Processing Technology for Non-Ferrous Metals and Materials, and Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, School of Resource, Environments and Materials, Guangxi University, Nanning 530004, China

§ Mengmeng Jin and Wei Liu contributed equally to this work.

Abstract

The electrosynthesis of hydrogen peroxide (H2O2) from oxygen reduction reaction (ORR) via a two-electron pathway provides an appealing alternative to the energy-intensive anthraquinone route; however, the development of ORR with high selectivity and durability for H2O2 production is still challenging. Herein, we demonstrate an active and stable catalyst, composing of highly dispersed Ag nanoclusters on N-doped hollow carbon spheres (NC-Ag/NHCS), which can effectively reduce O2 molecules into H2O2 with a selectivity of 89%–91% in a potential range from 0.2 to 0.7 V (vs. reversible hydrogen electrode (RHE)) in acidic media. Strikingly, NC-Ag/NHCS achieve a mass activity of 27.1 A·g−1 and a yield rate of 408 mmol·gcat.−1·h−1 at 0.7 V, both of which are comparable with the best-reported results. Furthermore, NC-Ag/NHCS enable catalyzing H2O2 production with a stable current density over 48-h electrolysis and only about 9.8% loss in selectivity after 10,000 cycles. Theoretical analyses indicate that Ag nanoclusters can contribute more electrons to favor the protonation of adsorbed O2, thus leading to a high H2O2 selectivity. This work confirms the great potential of metal nanocluster-based materials for H2O2 electrosynthesis under ambient conditions.

Keywords: oxygen reduction reaction, Ag nanoclusters, hydrogen peroxide synthesis, electrochemical route, energy-efficient

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Publication history
Copyright
Acknowledgements

Publication history

Received: 27 December 2021
Revised: 29 January 2022
Accepted: 29 January 2022
Published: 10 March 2022
Issue date: July 2022

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (Nos. 22075211, 21601136, 51971157, 62005173, and 51621003), Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme (2016), Guangdong Third Generation Semiconductor Engineering Technology Development Center (No. 2020GCZX007), Science, Technology, and Innovation Commission of Shenzhen Municipality (No. RCBS20200714114818140), China Postdoctoral Science Foundation (No. 2019M663118), and School level scientific research project of Shenzhen Institute of information technology (No. PT2019E002).

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