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Nano Research 2022, 15(5): 4008-4013 https://doi.org/10.1007/s12274-022-4174-0
Research Article | Issue | Published: 07 March 2022

FeP nanorod array: A high-efficiency catalyst for electroreduction of NO to NH3 under ambient conditions

Show Author's Information Jie Liang1,  Qiang Zhou2,  Ting Mou1,  Hongyu Chen1,  Luchao Yue1,  Yongsong Luo1,  Qian Liu3,  Mohamed S. Hamdy4,  Abdulmohsen Ali Alshehri5,  Feng Gong2( ),  Xuping Sun1( )
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 211189, China
Institute for Advanced Study, Chengdu University, Chengdu 610106, China
Catalysis Research Group (CRG), Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, 61413 Abha, Saudi Arabia
Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
Keywords:
density functional theory, electrocatalysis, NH3 synthesis , FeP nanoarray, NO reduction reaction
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Nanocatalysts
Cite this article:
Liang J, Zhou Q, Mou T, et al. FeP nanorod array: A high-efficiency catalyst for electroreduction of NO to NH3 under ambient conditions. Nano Research, 2022, 15(5): 4008-4013. https://doi.org/10.1007/s12274-022-4174-0
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Abstract Full text Electronic supplementary material About this article

Sustainable mitigation of the continuously rising concentration of NO contaminants is among the most urgent issues of this century. Ambient electrocatalytic conversion of NO into useful NH3 offers an attractive path toward achieving sustainable NO abatement and NH3 production simultaneously. However, its efficiency is challenged by the intense competition from hydrogen evolution reaction and relatively high energy barriers of NO activation. It is thus highly desirable to explore active electrocatalyst for NO reduction reaction and investigate the mechanisms on relevant surfaces. Herein, we introduce an FeP nanorod array on carbon cloth as a high-efficiency catalyst for NO electroreduction to NH3. In 0.2 M phosphate-buffered solution, this catalyst exhibits a low onset potential of −0.014 V. Moreover, it achieves a remarkable Faradaic efficiency of 88.49% and a large NH3 yield of 85.62 μmol·h−1·cm−2, with durability for stable NO conversion over 12 h of electrolysis. The catalytic mechanism on FeP is investigated further by theoretical calculations.


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Electronic supplementary material
About this article

FeP nanorod array: A high-efficiency catalyst for electroreduction of NO to NH3 under ambient conditions

Show Author's information Jie Liang1, Qiang Zhou2, Ting Mou1, Hongyu Chen1, Luchao Yue1, Yongsong Luo1, Qian Liu3, Mohamed S. Hamdy4, Abdulmohsen Ali Alshehri5, Feng Gong2( ), Xuping Sun1( )
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 211189, China
Institute for Advanced Study, Chengdu University, Chengdu 610106, China
Catalysis Research Group (CRG), Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, 61413 Abha, Saudi Arabia
Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

Abstract

Sustainable mitigation of the continuously rising concentration of NO contaminants is among the most urgent issues of this century. Ambient electrocatalytic conversion of NO into useful NH3 offers an attractive path toward achieving sustainable NO abatement and NH3 production simultaneously. However, its efficiency is challenged by the intense competition from hydrogen evolution reaction and relatively high energy barriers of NO activation. It is thus highly desirable to explore active electrocatalyst for NO reduction reaction and investigate the mechanisms on relevant surfaces. Herein, we introduce an FeP nanorod array on carbon cloth as a high-efficiency catalyst for NO electroreduction to NH3. In 0.2 M phosphate-buffered solution, this catalyst exhibits a low onset potential of −0.014 V. Moreover, it achieves a remarkable Faradaic efficiency of 88.49% and a large NH3 yield of 85.62 μmol·h−1·cm−2, with durability for stable NO conversion over 12 h of electrolysis. The catalytic mechanism on FeP is investigated further by theoretical calculations.

Keywords: density functional theory, electrocatalysis, NH3 synthesis , FeP nanoarray, NO reduction reaction

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Publication history
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Acknowledgements

Publication history

Received: 22 December 2021
Revised: 12 January 2022
Accepted: 13 January 2022
Published: 07 March 2022
Issue date: May 2022

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 52076045 and 22072015). The authors would also like to express their gratitude to Deanship of Scientific Research at King Khalid University, Abha, Saudi Arabia for funding this work through the Research Group Program under Grant No. RGP.1/70/42.

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