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Nano Research 2022, 15(5): 4747-4755 https://doi.org/10.1007/s12274-022-4159-z
Research Article | Issue | Published: 08 February 2022

Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances

Show Author's Information Yixin Han1,2,  Kunpeng Ruan1,2,  Junwei Gu1,2( )
Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518057, China
Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an 710072, China
Keywords:
Joule heating, thermal conductivity composite film, Janus structure, aramid nanofibers, electromagnetic interference shielding performance
Topics:
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Cite this article:
Han Y, Ruan K, Gu J. Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances. Nano Research, 2022, 15(5): 4747-4755. https://doi.org/10.1007/s12274-022-4159-z
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Abstract Full text Electronic supplementary material About this article

Highly thermal conductivity materials with excellent electromagnetic interference shielding and Joule heating performances are ideal for thermal management in the next generation of communication industry, artificial intelligence and wearable electronics. In this work, silver nanowires (AgNWs) are prepared using silver nitrate as the silver source and ethylene glycol as the solvent and reducing agent, and boron nitride (BN) is performed to prepare BN nanosheets (BNNS) with the help of isopropyl alcohol and ultrasonication-assisted peeling method, which are compounded with aramid nanofibers (ANF) prepared by chemical dissociation, respectively, and the (BNNS/ANF)-(AgNWs/ANF) thermal conductivity and electromagnetic interference shielding composite films with Janus structures are prepared by the “vacuum-assisted filtration and hot-pressing” method. Janus (BNNS/ANF)-(AgNWs/ANF) composite films exhibit “one side insulating, one side conducting” performance, the surface resistivity of the BNNS/ANF surface is 4.7 × 1013 Ω, while the conductivity of the AgNWs/ANF surface is 5,275 S/cm. And Janus (BNNS/ANF)-(AgNWs/ANF) composite film with thickness of 95 µm has a high in-plane thermal conductivity coefficient of 8.12 W/(m·K) and superior electromagnetic interference shielding effectiveness of 70 dB. The obtained composite film also has excellent tensile strength of 122.9 MPa and tensile modulus and 2.7 GPa. It also has good temperature-voltage response characteristics (high Joule heating temperature at low supply voltage (5 V, 215.0 °C), fast response time (10 s)), excellent electrical stability and reliability (stable and constant real-time relative resistance under up to 300 cycles and 1,500 s of tensile-bending fatigue work tests).


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About this article

Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances

Show Author's information Yixin Han1,2, Kunpeng Ruan1,2, Junwei Gu1,2( )
Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518057, China
Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an 710072, China

Abstract

Highly thermal conductivity materials with excellent electromagnetic interference shielding and Joule heating performances are ideal for thermal management in the next generation of communication industry, artificial intelligence and wearable electronics. In this work, silver nanowires (AgNWs) are prepared using silver nitrate as the silver source and ethylene glycol as the solvent and reducing agent, and boron nitride (BN) is performed to prepare BN nanosheets (BNNS) with the help of isopropyl alcohol and ultrasonication-assisted peeling method, which are compounded with aramid nanofibers (ANF) prepared by chemical dissociation, respectively, and the (BNNS/ANF)-(AgNWs/ANF) thermal conductivity and electromagnetic interference shielding composite films with Janus structures are prepared by the “vacuum-assisted filtration and hot-pressing” method. Janus (BNNS/ANF)-(AgNWs/ANF) composite films exhibit “one side insulating, one side conducting” performance, the surface resistivity of the BNNS/ANF surface is 4.7 × 1013 Ω, while the conductivity of the AgNWs/ANF surface is 5,275 S/cm. And Janus (BNNS/ANF)-(AgNWs/ANF) composite film with thickness of 95 µm has a high in-plane thermal conductivity coefficient of 8.12 W/(m·K) and superior electromagnetic interference shielding effectiveness of 70 dB. The obtained composite film also has excellent tensile strength of 122.9 MPa and tensile modulus and 2.7 GPa. It also has good temperature-voltage response characteristics (high Joule heating temperature at low supply voltage (5 V, 215.0 °C), fast response time (10 s)), excellent electrical stability and reliability (stable and constant real-time relative resistance under up to 300 cycles and 1,500 s of tensile-bending fatigue work tests).

Keywords: Joule heating, thermal conductivity composite film, Janus structure, aramid nanofibers, electromagnetic interference shielding performance

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Publication history
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Received: 06 January 2022
Revised: 11 January 2022
Accepted: 13 January 2022
Published: 08 February 2022
Issue date: May 2022

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