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Nano Research 2022, 15(6): 5105-5113 https://doi.org/10.1007/s12274-022-4134-8
Research Article | Issue | Published: 15 March 2022

Rapid construction of highly-dispersed cobalt nanoclusters embedded in hollow cubic carbon walls as an effective polysulfide promoter in high-energy lithium-sulfur batteries

Show Author's Information Lin Sun1,2,  Yanxiu Liu1,  Kaiqiang Zhang2,  Feng Cheng1,  Ruiyu Jiang1,  Yangqing Liu1,  Jing Zhu1,  Zhong Jin2( ),  Huan Pang3( )
Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, China
MOE Key Laboratory of Mesoscopic Chemistry, MOE Key Laboratory of High Performance Polymer Materials and Technology, Jiangsu Key laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China
Keywords:
electrocatalysis, lithium-sulfur battery, shuttle effect, Co nanocluster, hollow carbon
Topics:
Energy
Cite this article:
Sun L, Liu Y, Zhang K, et al. Rapid construction of highly-dispersed cobalt nanoclusters embedded in hollow cubic carbon walls as an effective polysulfide promoter in high-energy lithium-sulfur batteries. Nano Research, 2022, 15(6): 5105-5113. https://doi.org/10.1007/s12274-022-4134-8
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Abstract Full text Electronic supplementary material About this article

The ultrahigh specific energy density and low cost of lithium-sulfur batteries are suitable for the next generation of energy storage. However, the shuttle issue and sluggish conversion kinetics of polysulfides remain unsolved. Confining metal nanoclusters with strong polarity in conductive porous carbon is an effective strategy for tackling such knotty issues. Herein, we design and synthesize hollow cubic carbon embedded with highly dispersed cobalt nanoclusters as an effective sulfur reservoir for lithium sulfur batteries. The large cavity structure and well-dispersed cobalt nanoclusters, with uniform sizes near 11 nm, enable the hosting structure to hold the high sulfur loading, 70% capacity retention after 500 cycles at 2 C with a high sulfur loading of 6.5 mg·cm−2, effective stress release, accelerated polysulfide conversion, superior rate performance, strong physical confinement and chemical absorption capability. Further density functional theoretical calculations demonstrate that the well-dispersed cobalt nanoclusters in the hosting structure play a critical electrocatalytic role in boosting the capability of absorbing and converting polysulfides.


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Electronic supplementary material
About this article

Rapid construction of highly-dispersed cobalt nanoclusters embedded in hollow cubic carbon walls as an effective polysulfide promoter in high-energy lithium-sulfur batteries

Show Author's information Lin Sun1,2, Yanxiu Liu1, Kaiqiang Zhang2, Feng Cheng1, Ruiyu Jiang1, Yangqing Liu1, Jing Zhu1, Zhong Jin2( ), Huan Pang3( )
Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, China
MOE Key Laboratory of Mesoscopic Chemistry, MOE Key Laboratory of High Performance Polymer Materials and Technology, Jiangsu Key laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China

Abstract

The ultrahigh specific energy density and low cost of lithium-sulfur batteries are suitable for the next generation of energy storage. However, the shuttle issue and sluggish conversion kinetics of polysulfides remain unsolved. Confining metal nanoclusters with strong polarity in conductive porous carbon is an effective strategy for tackling such knotty issues. Herein, we design and synthesize hollow cubic carbon embedded with highly dispersed cobalt nanoclusters as an effective sulfur reservoir for lithium sulfur batteries. The large cavity structure and well-dispersed cobalt nanoclusters, with uniform sizes near 11 nm, enable the hosting structure to hold the high sulfur loading, 70% capacity retention after 500 cycles at 2 C with a high sulfur loading of 6.5 mg·cm−2, effective stress release, accelerated polysulfide conversion, superior rate performance, strong physical confinement and chemical absorption capability. Further density functional theoretical calculations demonstrate that the well-dispersed cobalt nanoclusters in the hosting structure play a critical electrocatalytic role in boosting the capability of absorbing and converting polysulfides.

Keywords: electrocatalysis, lithium-sulfur battery, shuttle effect, Co nanocluster, hollow carbon

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Publication history
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Acknowledgements

Publication history

Received: 12 October 2021
Revised: 02 January 2022
Accepted: 03 January 2022
Published: 15 March 2022
Issue date: June 2022

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© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was supported by the National Key Research and Development Program of China (No. 2017YFA0208200), the Fundamental Research Funds for the Central Universities of China (No. 0205-14380219), the National Natural Science Foundation of China (Nos. 22109069, 22022505, 21872069, 21802119, and 21808195), the Natural Science Foundation of Jiangsu Province (Nos. BK20181056 and BK20180008), the Funding For School-Level Research Projects of Yancheng Institute of Technology (Nos. xjr2019006, and xjr2019055), the 2021 Suzhou Gusu Leading Talents of Science and Technology Innovation and Entrepreneurship in Wujiang District, the Open Fund of Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province and some enterprise projects (Nos. WJGTT-XT3, 19KJA540001, and JNHB-068).

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