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Research Article

CO2 reduction with coin catalyst

Taishi Xiao1Can Tang1Hongbin Li1Tong Ye1Kun Ba1Peng Gong1Zhengzong Sun1,2( )
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China
School of Microelectronics and State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433, China
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Graphical Abstract

We successfully demonstrate the “third side of a coin” as an efficient CO2 reduction catalyst. A closed-loop lifecycle of formate/formic acid was developed, promising as an industry-compatible commodity chemical.

Abstract

Most organic commodity chemicals are derived from fossil carbon resources. The dependency is so immense that it is difficult to compensate for the accompanying carbon footprint with current technology and chemical infrastructure. To mitigate the future fossil fuel usage, it is crucial to explore alternative chemical pathways, which are both sustainable and suitable for large-scale productions. Here we demonstrate a closed-loop carbon-neutral chemical route, using standard coin catalyst, to produce high concentrated formate and formic acid. The catalyst’s Faradaic efficiency (FE) of formate is ~ 95.3% with great durability. The chemicals are not only synthesized but also purified and utilized in zero-carbon scenarios. We successfully harvested 45% formate salt and 86.2% formic acid, for applications like anti-freezing reagent and green liquid fuel to power the fuel-cell vehicles.

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Nano Research
Pages 3859-3865
Cite this article:
Xiao T, Tang C, Li H, et al. CO2 reduction with coin catalyst. Nano Research, 2022, 15(5): 3859-3865. https://doi.org/10.1007/s12274-021-3990-y
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Received: 29 September 2021
Revised: 06 November 2021
Accepted: 09 November 2021
Published: 06 December 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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