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Nano Research 2022, 15(4): 2961-2970 https://doi.org/10.1007/s12274-021-3918-6
Research Article | Issue | Published: 15 December 2021

Ultrastable MOF-based foams for versatile applications

Show Author's Information Qian Hu1,  Licong Xu1,6,  Kaixing Fu3,4,  Feichao Zhu1,  Taoyu Yang1,  Tao Yang5,  Jinming Luo3,  Minghua Wu1,  Deyou Yu1,2,6( )
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
Brook Byers Institute for Sustainable Systems, School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta 30332, USA
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China
Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Liberec 46117, Czech Republic
Zheijiang Sci-Tech University Tongxiang Research Institute, Tongxiang 345000, China
Keywords:
metal-organic framework, melamine foam, ultrastability, versatile applications, long-term use
Topics:
Organic frameworks
Cite this article:
Hu Q, Xu L, Fu K, et al. Ultrastable MOF-based foams for versatile applications. Nano Research, 2022, 15(4): 2961-2970. https://doi.org/10.1007/s12274-021-3918-6
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Abstract Full text Electronic supplementary material About this article

Metal-organic frameworks (MOFs) are attractive for promising applications but plagued by difficult recovery and deployment due to their intrinsic nano/micro powder nature. Although significant efforts have been made to develop separable solid matrixes for MOF supporting, the poor loading stability and durability of MOFs still challenge their engineering applications. Here, we present a facile and effective approach to fabricate MOF-based melamine foams (MFs) (denoted as MOFiths) with ultrahigh loading stability and operation stability, easy separation, and high-efficient performance for versatile robust applications. By adopting our approach, numbers of typical fragile MOFs characterized with wide ranges of particle size (from ~ nm to ~ μm) can be precisely incorporated into MFs with controllable loading ratios (up to ~ 1,600%). Particularly, the produced MOFiths show excellent capacities for the highly effective and durable water purifications and acetalization reactions. 100% of organic pollutants can be rapidly destructed within 10 min by MOFiths initiated Fenton or catalytic ozonation processes under five successive cycles while the maximum adsorption capacity of MOFiths toward Pb(II), Cd(II), and Cu(II) reaches to 422, 222, and 105 mg·g−1, respectively. This study provides a critical solution to substantially facilitate the engineering applications of MOFs for long-term use in practice.


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Abstract
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Electronic supplementary material
About this article

Ultrastable MOF-based foams for versatile applications

Show Author's information Qian Hu1, Licong Xu1,6, Kaixing Fu3,4, Feichao Zhu1, Taoyu Yang1, Tao Yang5, Jinming Luo3, Minghua Wu1, Deyou Yu1,2,6( )
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
Brook Byers Institute for Sustainable Systems, School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta 30332, USA
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China
Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Liberec 46117, Czech Republic
Zheijiang Sci-Tech University Tongxiang Research Institute, Tongxiang 345000, China

Abstract

Metal-organic frameworks (MOFs) are attractive for promising applications but plagued by difficult recovery and deployment due to their intrinsic nano/micro powder nature. Although significant efforts have been made to develop separable solid matrixes for MOF supporting, the poor loading stability and durability of MOFs still challenge their engineering applications. Here, we present a facile and effective approach to fabricate MOF-based melamine foams (MFs) (denoted as MOFiths) with ultrahigh loading stability and operation stability, easy separation, and high-efficient performance for versatile robust applications. By adopting our approach, numbers of typical fragile MOFs characterized with wide ranges of particle size (from ~ nm to ~ μm) can be precisely incorporated into MFs with controllable loading ratios (up to ~ 1,600%). Particularly, the produced MOFiths show excellent capacities for the highly effective and durable water purifications and acetalization reactions. 100% of organic pollutants can be rapidly destructed within 10 min by MOFiths initiated Fenton or catalytic ozonation processes under five successive cycles while the maximum adsorption capacity of MOFiths toward Pb(II), Cd(II), and Cu(II) reaches to 422, 222, and 105 mg·g−1, respectively. This study provides a critical solution to substantially facilitate the engineering applications of MOFs for long-term use in practice.

Keywords: metal-organic framework, melamine foam, ultrastability, versatile applications, long-term use

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Acknowledgements

Publication history

Received: 29 March 2021
Revised: 14 September 2021
Accepted: 30 September 2021
Published: 15 December 2021
Issue date: April 2022

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 22106141), the Key Research and Development Program of Zhejiang Province (No. 2018C03004), the Scientific Launching Funding of Zhejiang Sci-Tech University and the Postdoctoral Program (No. TYY202103) of Zhejiang Sci-Tech University Tongxiang Research Institute. The authors also acknowledge the support by the Brook Byers Institute for Sustainable Systems, Hightower Chair and the Georgia Research Alliance at the Georgia Institute of Technology. The views and ideas expressed herein are solely those of the authors’ and do not represent the ideas of the funding agencies in any form.

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