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Nano Research 2022, 15(4): 2919-2927 https://doi.org/10.1007/s12274-021-3903-0
Research Article | Issue | Published: 23 October 2021

Sub-2 nm ultra-thin Bi2O2CO3 nanosheets with abundant Bi-O structures toward formic acid electrosynthesis over a wide potential window

Show Author's Information Yuhong Wang1,2,§,  Bin Wang3,§,  Wenjun Jiang1( ),  Zailun Liu1,  Jiangwei Zhang3,4( ),  Lizhen Gao2( ),  Wei Yao1( )
Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology, 104 Youyi Road, Beijing 100094, China
College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Dalian National Laboratory for Clean Energy & State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS), Dalian 116023, China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (CAS), Fuzhou 350002, China

§ Yuhong Wang and Bin Wang contributed equally to this work.

Keywords:
CO2 reduction , Bi2O2CO3 nanosheets , Bi-O structures, X-ray absorption fine structure, wide potential window
Topics:
Electrocatalysis
Cite this article:
Wang Y, Wang B, Jiang W, et al. Sub-2 nm ultra-thin Bi2O2CO3 nanosheets with abundant Bi-O structures toward formic acid electrosynthesis over a wide potential window. Nano Research, 2022, 15(4): 2919-2927. https://doi.org/10.1007/s12274-021-3903-0
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Abstract Full text Electronic supplementary material About this article

The electrocatalytic reduction of CO2 to HCOOH (ERC-HCOOH) is one of the most feasible ways to alleviate energy crisis and solve environmental problems. Nevertheless, it remains a challenge for ERC-HCOOH to maintain excellent activity and selectivity in a wide potential window. Herein, ultra-thin flower-like Bi2O2CO3 nanosheets (NSs) with abundant Bi-O structures were in situ synthesized on carbon paper via topological transformation and post-processing. Faraday efficiency of HCOOH (FEHCOOH) reached 90% in a wide potential window (−1.5 to −1.8 V vs. Ag/AgCl). Significantly, excellent FEHCOOH (90%) and current density (47 mA·cm−2) were achieved at −1.8 V vs. Ag/AgCl. The X-ray absorption fine structure (XAFS) combined with density functional theory (DFT) calculation demonstrated that the excellent performance of Bi2O2CO3 NS was attributed to the abundant Bi-O structures, which was conducive to enhancing the adsorption of CO2* and OCHO* intermediates and can effectively inhibit hydrogen evolution. The excellent performance of Bi2O2CO3 NS over a wide potential window could provide new insights for the efficient electrocatalytic conversion of CO2.


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About this article

Sub-2 nm ultra-thin Bi2O2CO3 nanosheets with abundant Bi-O structures toward formic acid electrosynthesis over a wide potential window

Show Author's information Yuhong Wang1,2,§, Bin Wang3,§, Wenjun Jiang1( ), Zailun Liu1, Jiangwei Zhang3,4( ), Lizhen Gao2( ), Wei Yao1( )
Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology, 104 Youyi Road, Beijing 100094, China
College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Dalian National Laboratory for Clean Energy & State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS), Dalian 116023, China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (CAS), Fuzhou 350002, China

§ Yuhong Wang and Bin Wang contributed equally to this work.

Abstract

The electrocatalytic reduction of CO2 to HCOOH (ERC-HCOOH) is one of the most feasible ways to alleviate energy crisis and solve environmental problems. Nevertheless, it remains a challenge for ERC-HCOOH to maintain excellent activity and selectivity in a wide potential window. Herein, ultra-thin flower-like Bi2O2CO3 nanosheets (NSs) with abundant Bi-O structures were in situ synthesized on carbon paper via topological transformation and post-processing. Faraday efficiency of HCOOH (FEHCOOH) reached 90% in a wide potential window (−1.5 to −1.8 V vs. Ag/AgCl). Significantly, excellent FEHCOOH (90%) and current density (47 mA·cm−2) were achieved at −1.8 V vs. Ag/AgCl. The X-ray absorption fine structure (XAFS) combined with density functional theory (DFT) calculation demonstrated that the excellent performance of Bi2O2CO3 NS was attributed to the abundant Bi-O structures, which was conducive to enhancing the adsorption of CO2* and OCHO* intermediates and can effectively inhibit hydrogen evolution. The excellent performance of Bi2O2CO3 NS over a wide potential window could provide new insights for the efficient electrocatalytic conversion of CO2.

Keywords: CO2 reduction , Bi2O2CO3 nanosheets , Bi-O structures, X-ray absorption fine structure, wide potential window

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Publication history
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Acknowledgements

Publication history

Received: 25 August 2021
Revised: 16 September 2021
Accepted: 22 September 2021
Published: 23 October 2021
Issue date: April 2022

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 22002185 and 21701168), Beijing Natural Science Foundation (No. 2204100), the National Key Research and Development Program of China (Nos. 2020YFA0710304 and 2020YFA0406101), Civil Aerospace Technology Research Project (No. B0108), Dalian high level talent innovation project (No. 2019RQ063), and Open project Foundation of State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (No. 20200021). We gratefully acknowledge 1W2B beamline of Beijing Synchrotron Radiation Facility (BSRF) Beijing, China, for providing the beam time.

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